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西华师范大学化学化工学院导师教师师资介绍简介-敬林海

本站小编 Free考研考试/2021-10-03


男,1977年02月生,四川南部人,博士,教授
联系方式
地址:四川省南充市师大路1号 西华师范大学化学化工学院
邮编:637009
e-mail:jlhhxg@cwnu.edu.cn
教育背景
1995.9-2000.7 四川师范学院化学系学习,获理学学士学位;
1999.9-2002.7 西华师范大学化学系攻读硕士学位,获理学硕士学位;
2007.9-2010.7 四川大学化学学院攻读博士学位,获理学博士学位
工作经历
2002.7-至今西华师范大学化学化工学院工作
讲授课程
《有机化学》、《有机化学实验》、《近代有机合成》及《有机合成和反应机理》等课程
研究兴趣
1.不对称催化;
2.光催化反应。
科研项目
1.3-(1-砜基烷基)氮杂吲哚和氮杂吲唑类化合物在不对称合成中的应用研究(国家自然科学基金主持);
2.过渡金属催化的水相中三氮唑类化合物的“一锅法”合成及其在医药合成中的应用(省教育厅重点项目主持);
3.手性色氨酸衍生物的不对称合成及其在医药合成中的应用(南充市科技局 主持);
4.相转移催化的不对称有机反应研究(博士启动基金主持)。
专利与专著
《有机物制备》科学出版社
学术论文
已发表研究论文30余篇,其中SCI收录20篇
1.Highly Enantioselective Michael Addition of Malononitrile to Vinylogous Imine Intermediates Generated in situ from Arylsulfonyl Indoles,Chem. Eur. J.,2010, 16(36),10955;(第一作者)
2.Lithium pipecolinate as a facile and efficient ligand for copper-catalyzed hydroxylation of aryl halides in water,Chem. Commun.,2010,46(26),4767;(第一作者)
3.Asymmetric cyanohydrin formation from aldehydes catalyzed by manganese Schiff base complexes,Tetrahedron: Asymmetry,2010,21(2),187.(第二作者)
4.Organocatalytic Asymmetric Vinylogous Michael Addition of Dicyanoolefins to Imine Intermediates Generated in situ from Arenesulfonylalkylindoles,Adv. Synth. Catal.,2012,354, 2965;(通讯作者)
5.Organocatalytic Asymmetric Michael Addition of Oxazolones to Arylsulfonyl Indoles: Facile Access to syn-Configured α,β-Disubstituted Tryptophan Derivatives,Eur. J. Org. Chem.,2013, 456;(通讯作者)
6.Organocatalytic asymmetric Michael addition of 2-naphthols to alkylideneindolenines generated in situ from arenesulfonylalkylindoles,Tetrahedron Lett.,2013,54, 3675;(通讯作者)
7.Enantioselective Michael Addition of 1,3-Diketones to Arenesulfonylalkylindoles: A Flexible Gateway to Optically Active 3-sec-Alkyl-Substituted Indoles Containing a Pyrazole Skeleton,Synthesis,2013, 2832;(通讯作者)
8.Organocatalytic asymmetric synthesis of 3(2H)-furanones with adjacent quaternary and tertiary stereocenters,Tetrahedron Lett.,2013,54, 6363;(通讯作者)
9. Enantioselective Michael addition of 3(2H)-furanones to α,β-unsaturated aldehydes catalyzed by a diphenylprolinol silyl ether,Tetrahedron Lett.,2014,55, 209;(通讯作者)
10.Regioselective asymmetric stereoablative O-alkylation of α-nitrophosphonates via o-azaxylylene intermediates generated in situ from 3-bromooxindoles,RSC adv.,2014,4, 11605;(通讯作者)
11.3-(1-Arylsulfonylalkyl)-7-azaindoles as precursors of vinylogous imine intermediates for hetero-Michael addition reactions.Tetrahedron,2015,71, 4039;(通讯作者)
12. Facile synthesis of 3-sec-alkyl substituted 7-azaindoles by Michael addition of carbon nucleophiles to vinylogous imine intermediates generated in situ from 3-(1-arylsulfonylalkyl)-7-azaindoles.Tetrahedron Lett.,2015,56, 1764;(通讯作者)
13.Organocatalytic asymmetric Michael addition of benzofuran-2(3H)-ones to alkylideneindolenines generated in situ from arenesulfonylalkylindoles.Tetrahedron Lett.,2015,56, 2867;(通讯作者)
14. Organocatalytic asymmetric synthesis of trans-configured trispirooxindoles through a cascade Michael-cyclization reaction.Tetrahedron Lett.2016,57, 2857;(通讯作者)

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