博士 硕士生导师
单位：成都理工大学材料与化学化工学院 应用化学系
电话：+86-**
传真：+86-
邮箱：xiaoyuhaoscu@outlook.com
基本情况：
　　郝小余，男，1989年12月生，河南南阳人，博士研究生。2012年6月毕业于四川大学化学学院，获得“应用化学”学士学位。师从四川大学化学学院冯小明教授，攻读博士学位，主要研究方向为手性路易斯酸配合物（手性双氮氧-金属配合物）催化的环加成反应研究，并于2017年6月毕业，获得“有机化学”理学博士学位。2018年5月—2020年12月在瑞士日内瓦大学生物与化学学院从事博士后科学研究，主要研究超分子与材料化学中常见的相互作用“阴离子-π”在有机合成中的应用。入选成都理工大学“珠峰引才计划”C2类人才项目，2021年2月起，于本校材料与化学化工学院任教。主要从事有机化学领域教学与研究工作，主要研究方向为有机合成与催化、药物活性化合物的合成、“阴离子-π”等分子间弱相互作用在有机合成中的应用等。近年来，作为项目负责人主持成都理工大学校级科研启动基金1项。迄今在Journal of the American Chemical Society、Angewandte Chemie, International Edition、ACS Catalysis、Organic Letters、Organic Chemistry Frontiers等国际顶级期刊上发表SCI检索论文13篇，其中第一作者4篇。
讲授课程：
本科生课程：有机波谱分析

研究领域：
研究方向：有机合成与催化、药物活性化合物的合成、“阴离子-π”等分子间弱相互作用在有机合成中的应用
主要学术论文：
[1]Miguel Paraja#, Xiaoyu Hao#, Stefan Matile*, “Polyether Natural Product Inspired Cascade Cyclizations Autocatalyzed on π-Acidic Aromatic Surfaces” Angew. Chem. Int. Ed. (2020) 59, 15093-15097.. (SCI, IF = 12.257)
[2]Xiaoyu Hao, Lili Lin, Fei Tan, Chengkai Yin, Xiaohua Liu, and Xiaoming Feng*, “Ligand Control of Diastereodivergency in Asymmetric Inverse Demand Diels-Alder Reaction”, ACS Catal. (2015), 5, 6052-6056. (SCI, IF = 12.221)
[3]Xiaoyu Hao, Xiaohua Liu, Wei Li, Fei Tan, Yangyang Chu, Xiaohu Zhao, Lili Lin, and Xiaoming Feng*, “Chiral Lewis Acid Catalyzed Asymmetric Cycloaddition of Disubstituted Ketenes for the Synthesis of β-Lactones and δ-Lactones”, Organic Letters, (2014), 16, 134?137. (SCI, IF = 6.555)
[4]Xiaoyu Hao, Lili Lin, Fei Tan, Shulin Ge, Xiaohua Liu, and Xiaoming Feng*, “Asymmetric synthesis of chromans via the Friedel–Crafts alkylation–hemiketalization catalysed by an N,N’-dioxide scandium(III) complex” Org. Chem. Front. (2017) 1647-1650. (SCI, IF = 5.076)
[5]Xiang Zhang, Xiaoyu Hao, Le Liu, Anh-Tuan Pham, Javier Lo?pez-Andarias, Antonio Frontera, Naomi Sakai, and Stefan Matile*, “Primary Anion?π Catalysis and Autocatalysis”, J. Am. Chem. Soc. (2018) 140, 17867-17871. (SCI, IF = 14.695)
[6]Yangyang Chu, Xiaoyu Hao, Lili Lin, Weiliang Chen, Wei Li, Fei Tan, Xiaohua Liu, and Xiaoming Feng*, “Chiral N,N’-Dioxide–Scandium(III)-Catalyzed Asymmetric Epoxidation of 2-Arylidene-1,3-diketones with Hydrogen Peroxide” Adv. Synth. Catal. (2014) 356, 2214-2218. (SCI, IF = 5.451)
[7]Wei Li, Xiaohua Liu, Xiaoyu Hao, Xiaolei Hu, Yangyang Chu, Weidi Cao, Song Qin, Changwei Hu, Lili Lin, and Xiaoming Feng*, “New Electrophilic Addition of α-Diazoesters with Ketones for Enantioselective C–N Bond Formation” J. Am. Chem. Soc. (2011) 133, 15268–15271. (SCI, IF = 14.695)
[8]Wei Li, Xiaohua Liu, Xiaoyu Hao, Yunfei Cai, Lili Lin, and Xiaoming Feng,* “A Catalytic Asymmetric Ring-Expansion Reaction of Isatins and α-Alkyl-α-Diazoesters: Highly Efficient Synthesis of Functionalized 2-Quinolone Derivatives” Angew. Chem. Int. Ed. (2012) 51, 8644-8647. (SCI, IF = 12.257)
[9]Wei Li, Xiaohua Liu, Fei Tan, Xiaoyu Hao, Jianfeng Zheng, Lili Lin, and Xiaoming Feng,* “Catalytic Asymmetric Homologation of α-Ketoesters with α-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers” Angew. Chem. Int. Ed. (2013) 52, 10883-10886. (SCI, IF = 12.257)
[10]Wei Li, Fei Tan, Xiaoyu Hao, GangWang, Yu Tang, Xiaohua Liu, Lili Lin, and Xiaoming Feng*, “Catalytic Asymmetric Intramolecular Homologation of Ketones with α-Diazoesters: Synthesis of Cyclic α-Aryl/Alkyl β-Ketoesters” Angew. Chem. Int. Ed. (2015) 54, 1608-1611. (SCI, IF = 12.257)
[11]Jiannan Zhao, Bing Fang, Weiwei Luo, Xiaoyu Hao, Xiaohua Liu, Lili Lin, and Xiaoming Feng,* “Enantioselective Construction of Vicinal Tetrasubstituted Stereocenters by the Mannich Reaction of Silyl Ketene Imines with Isatin-Derived Ketimines” Angew. Chem. Int. Ed. (2015) 54, 241-244. (SCI, IF = 12.257)
[12]Fei Tan, Xiaohua Liu*, Xiaoyu Hao, Yu Tang, Lili Lin, and Xiaoming Feng*, “Asymmetric Catalytic Insertion of α-Diazo Carbonyl Compounds into O–H Bonds of Carboxylic Acids” ACS Catal. (2016) 6, 6930–6934. (SCI, IF = 12.221)
[13]Yangbin Liu, Haipeng Hu, Lili Lin, Xiaoyu Hao, Xiaohua Liu, and Xiaoming Feng*, “Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement” Chem. Commun. (2016), 52, 11963-11966. (SCI, IF = 6.164)