■ 个人简介


宋溪明，男，工学博士，教授，博士生导师，“绿色合成与先进材料制备化学”辽宁省重点实验室主任，化学一级学科博士点学科带头人；中国化学会无机化学学科委员会委员，辽宁省化学会理事长。

学习经历：辽宁大学化学系本科（1982.01）和硕士研究生（1987.07）、日本九州大学工学研究院合成化学系博士研究生（1991.09）毕业。

工作经历：辽宁大学化学系助教（1982.01-1987.11）；日本花王基础科学研究所博士后研究员（1991.10-1993.07）;辽宁大学化学系副教授（1993.07-1996.08）；辽宁大学化学院教授（1996.08-今，其间1997年7月至1998年9月：辽宁大学化学院常务副院长；1998年9月至2009年8月：辽宁大学化学院院长；2002年10月至2003年10月：日本奈良先端科学技术大学院大学物质创成科学研究院访问教授；2015年7月至2016年1月：日本九州大学工学研究院教授）。

联系方式：地址：沈阳市皇姑区崇山中路66号辽宁大学化学院，邮编110036；电话：（O）；E-mail: xmsong@lnu.edu.cn。

■ 研究领域 界面科学与软物质

■ 研究方向 微纳米复合与组装化学

随着材料科学技术的不断发展，单功能纳米材料已经不能满足应用的需要，将多种功能性组分运用简易的方法复合或组装以获得微纳米复合物或组装体被认为是解决问题、满足需求的有效途径。微纳米复合物和组装体的性质，不是各个组分性能的简单加和，而是在保持各个组分材料某些特性基础上，具有组分间协同作用所产生的综合性能。由于微纳米复合物和组装体各组分间的协同效应，充分弥补了单一材料的缺点，展现多功能的同时，能够产生单一组分材料所不具备的新性能，开创了材料设计的新局面。

■ 研究概述 基于化学、特别是胶体与界面化学理论和合成制备技术，通过微纳米尺度上的复合与组装，构筑新型固体或软物质体系，研究其结构与性能间关系，展现体系组分各自功能的同时，实现不同组分和结构的协同效应表达，开拓其应用。





■ 研究内容






近期发表论文

1.Shuyao Wu, Jinyu Hao, Shaojun Yang, Ying Sun, Yulu Wang, Wei Zhang, Hui Mao, Xi-Ming Song*, Layer-by-layer self-assembly film of PEI-reduced graphene oxide composites and cholesterol oxidase for ultrasensitive cholesterol biosensing, Sensors & Actuators: B. Chemical 2019, 298, 126856.

2.Zhi-Jia Sun, Hao Ge*, Shuai Zhu, Xiao-Man Cao, Xin Guo, Zhong-Hai Xiu, Zi-Hang Huang, Hui Li, Tianyi Ma*, Xi-Ming Song*,Versatile Template-Free Construction of Hollow Nanostructured CeO2 Induced by Functionalized Carbon Materials, Journal of Materials Chemistry A, 2019, 7, 12008-12017.

3.Xiuping Tang, Yu Hou, Qing Bo Meng*, Guolin Zhang, Fuxin Liang, Xi-Ming Song*, Heteropoly acids-functionalized Janus particles as catalytic emulsifier for heterogeneous acylation in flow ionic liquid-in-oil Pickering emulsion, Colloids and Surfaces A, 2019, 570, 191–198.

4.Yu Zhang, Weining Sun, Bingzhi Qian, Yanming Wang, Baoxin Wang, Shuo Li, Daliang Liu, Daming Feng, Tianyi Ma*, Xi-Ming Song*, Room-temperature photocatalytic methanol fuel cell based on onedimensionsemiconductor photoanode: Intrinsic mechanism ofphotogenerated charge separation, Electrochimica Acta, 2019, 318, 413-421.

5.Dayin Sun, Yan Si, Xi-Ming Song, Fuxin Liang* and Zhenzhong Yang*, Bi-continuous emulsion using Janus particles, Chem. Commun., 2019, DOI: 10.1039/c9cc01191a

6.Yu Hou, Guolin Zhang, Xiuping Tang, Yan Si, Ximing Song, Fuxin Liang* and Zhenzhong Yang*, Janus Nanosheets Synchronously Strengthen and Toughen Polymer Blends, Macromolecules, 2019, DOI: 10.1021/acs.macromol.9b00598

7.Dan Yu, Shintaro Morisada, Hidetaka Kawakita, Keisuke Ohto*, Katsutoshi Inoue, Ximing Song and Guolin Zhang, Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves, Processes, 2019, 7, 412 (DOI:10.3390/pr**).

8.Dan Xue, Qing Bo Meng, and Xi-Ming Song*, Fabrication of Ternary Hybrid Colloids via In-Situ Polymerization at the Interface of Oil/Water Emulsion, Macromol. Chem. Phys. 2019, 220, ** (DOI: 10.1002/macp.).

9. Hui Mao, Zhenqian Cao, Xi Guo, Dayin Sun, Daliang Liu, Shuyao Wu, Yu Zhang, and Xi-Ming Song*, Ultrathin NiS/Ni(OH)2 Nanosheets Filled within Ammonium Polyacrylate-Functionalized Polypyrrole Nanotubes as an Unique Nanoconfined System for Nonenzymatic Glucose Sensors, ACS Appl. Mater. Interfaces, 2019, 11, 10153?10162.

10. Dan Xue, Qing Bo Meng, and Xi-Ming Song*, Magnetic-Responsive Janus Nanosheets with Catalytic Properties, ACS Appl. Mater. Interfaces2019, 11, 10967?10974.

11. Yuxuan Zhang, Saisai Gai, Zhonghui Wang, Shuang Wang, An Sui and Xi-Ming Song*，Poly(arylene ether)s with aromatic azo-coupled cobalt phthalocyanines in the side chain: synthesis, characterization and nonlinear optical and optical limiting properties，RSC Adv., 2019, 9, 9253–9259.

12. Qinzhen Fan, Gang Bai, Qing Liu, Ying Sun, Wei Yuan, Shuyao Wu, Xi-Ming Song*, De-Zhi Zhao.The Ultrasound Thermal Cracking for the Tar-sand Bitumen. Ultrasonics sonochemistry 2019, 50, 354-362.

13. Gang Bai, Qinzhen Fan, Xi-Ming Song* Preparation and characterization of pavement materials with phase-change temperature modulation Journal of Thermal Analysis and Calorimetry, DOI: org/10.1007/s10973-018-7862-y

14.Hui Mao, Zhenqian Cao, Xi Guo, Meihong Liu, Dayin Sun, Zhijia Sun, Hao Ge, Yu Zhang, Xi-Ming Song*, Enhanced electrocatalytic performance for the oxidation of methanol by hierarchical NiS/Ni(OH)2@polypyrrole/graphene oxide nanosheets,Applied Surface Science, 2019, 471, 355–367.

15.Xi-Ming Song, Chunxue Yuan, Yanming Wang, Baoxin Wang, Hui Mao, Shuyao Wu, Yu Zhang*, ZnO/CuO photoelectrode with n-p heterogeneous structure for photoelectrocatalytic oxidation of formaldehyde, Applied Surface Science, 2018, 455, 181–186

16.Zhenqian Cao, Hui Mao*, Xi Guo, Dayin Sun, Zhijia Sun, Baoxin Wang, Yu Zhang, Xi-Ming Song*, Hierarchical Ni(OH)2/polypyrrole/graphene oxide nanosheets as excellent electrocatalysts for the oxidation of urea, ACS Sustainable Chemistry & Engineering, 2018, 6(11): 15570-15581.

17.Hui Mao, Chunguang Ji, Meihong Liu, Zhenqian Cao, Dayin Sun, Zhiqiang Xing, Xia Chen, Yu Zhang, Xi-Ming Song*, Enhanced catalytic activity of Ag nanoparticles supported on polyacrylamide/polypyrrole/graphene oxide nanosheets for the reduction of 4-nitrophenol, Applied Surface Science, 2018, 434, 522–533.

18.Qing Bo Meng, Peng Yang, Tianyang Feng, Xuyang Ji, Qian Zhang, Daliang Liu, Shuyao Wu, Fuxin Liang*, Zhaoliang Zheng, and Xi-Ming Song*, Phosphomolybdic Acid-Responsive Pickering Emulsions Stabilized by Ionic Liquid Functionalized Janus Nanosheets, Journal of colloid and interface science, 2017, 507, 74-82.

19.Shaojun Yang, Daliang Liu, Qing Bo Meng, Shuyao Wu* and Xi-Ming Song*, Reduced graphene oxide-supported methylene blue nanocomposite as a glucose oxidase-mimetic for electrochemical glucose sensing, RSC Advances, 2018, 8, 32565

20.Yuchun Jiang, Manna Li, Daliang Liu, Xi-Ming Song, Xiaohong Chang* Mixed m-azido-Schiff-base cyclometallated Pd (II) complexes as a template for novel palladacycles bearing bridging carbodiimido, tetrazolato ligands, and tetrazole-thiolato linkers. Journal of Organometallic Chemistry2018, 871: 103-110

21. Hao Ge, Luxia Cui, Zhijia Sun, Denghu Wang, Shengnan Nie, Shuai Zhu, Bryan Matthews, Gang Wu*, Xi-Ming Song* and Tian-Yi Ma* Unique Li4Ti5O12/TiO2 multilayer arrays with advanced surface lithium storage capability. Journal of Materials Chemistry A, 2018, 6, 22053-22061

22.Ying Sun, Wei Zhang*, Tian-Yi Ma, Yu Zhang, Hisashi Shimakoshi, Yoshio Hisaeda and Xi-Ming Song. Enhanced photocatalytic activity of a B₁₂-based catalyst co-photosensitized by TiO₂ and Ru(II) towards dechlorination. RSC Advances, 2018, 8, 662-670

23.Yuxuan Zhang, Shuang Wang, Zhonghui Wang, Saisai Gai, Xi-Ming Song* Preparation and performance of crosslinked poly(arylene ether)s containing azobenzene chromophores Designed Monomers and Polymers, 2017, 1: 496-504

24.Yu Zhang, Ying Li, Weining Sun, Chunxue Yuan, Baoxin Wang, Wei Zhang, and Xi-Ming Song*，Fe2O3/BiOI-Based Photoanode with n-p Heterogeneous Structure for Photoelectric Conversion. Langmuir2017, 33,12065-12071

25. Wei Yuan, Run-Hui Ding, Hao Ge, Pei-Liang Zhu, Shan-Shan Ma, Bing Zhang, Xi-Ming Song*. Solid-phase extraction of d -glucaric acid from aqueous solution, Separation and Purification Technology, 2017, 175, 352-357

26. Yu Zhang, Fuyuan Qi, Ying Li, Xin Zhou, Hongfeng Sun, Wei Zhang, Daliang Liu, Xi-Ming Song*, Graphene oxide quantum dot-sensitized porous titanium dioxide microsphere: Visible-light-driven photocatalyst based on energy band Engineering, Journal of Colloid and Interface Science, 2017, 498, 105-111

27. Xi-Ming Song, Xin Zhou, Chunxue Yuan, Yu Zhang?, Qiang Tong, Ying Li, Luxia Cui, Daliang Liu, Wei Zhang, One-dimensional Fe₂O₃/TiO₂photoelectrode and investigation of its photoelectric properties in photoelectrochemical cell, Applied Surface Science, 2017, 397, 112–118

28. Dan Xue, Ximing Song, Fuxin Liang*, Ultrathin Janus nanodiscs, RSC Advances, 2017,7, 25450-25454

29. Ying Sun, Wei Zhang*, Jian Tong, Yu Zhang, Shuyao Wu, Daliang Liu, Hisashi Shimakoshi, Yoshio Hisaeda, Xi-Ming Song*, Significant enhancement of visible light photocatalytic activity of the hybrid B₁₂-PIL/rGO in the presence of Ru(bpy)₃ ²⁺ for DDT dehalogenation, RSC Advances, 2017, 7, 19197–19204

30. Hui Mao, Meihong Liu, Zhenqian Cao, Chunguang Ji, Ying Sun, Daliang Liu, Shuyao Wu, Yu Zhang, Xi-Ming Song*, Poly(4-vinylphenylboronic acid) functionalized polypyrrole/graphene oxide nanosheets for simultaneous electrochemical determination of catechol and hydroquinone, Applied Surface Science, 2017, 420, 594–605

31. Hui Mao, Haifeng Zhang, Wei Jiang, Jiachen Liang, Ying Sun, Yu Zhang, Qiuhua Wu, Guolin Zhang, Xi-Ming Song*, Poly(ionic liquid) functionalized polypyrrole nanotubes supported gold nanoparticles: An efficient electrochemical sensor to detect epinephrine, Materials Science and Engineering C, 2017, 75, 495-520

32. Qinzhen Fan, Gang Bai, Shuyao Wu, Wei Yuan and Xi-Ming Song* The chemical structure and the kinetics research of oil-wet oil sand from Kazakhstan during pyrolysis process. Journal Petroleum Science and Technology 2017, 35(14):1495-1501

33. Yun Qiao, Keishiro Tahara, Qian Zhang*, Xi-Ming Song*, Jun-ichi Kikuchi*, Cerasomes: Soft Interface for Redox Enzyme Electrochemical Signal Transmission,Chemistry-A European Journal, 2016, 22, 1340 -1348

34. Wei Zhang, Guoqin Li, Xiaoying Fei, Yu Zhang, Jian Tong, Xi-Ming Song*, Significant photoelectric conversion properties of multilayer films formed by a cationic zinc phthalocyanine complex and graphene oxide, RSC Advances, 2016, 6, 67017–67024

35. Hao Ge, Luxia Cui, Bing Zhang, Tianyi Ma* and Xi-Ming Song*, Ag quantum dots promoted Li₄Ti₅O₁₂/TiO₂nanosheets with ultrahigh reversible capacity and super rate performance for power lithium-ion batteries, Journal of Materials Chemistry A, 2016, 4, 16886-16895

36. Hao Ge,Tingting Hao,Hannah Osgood,Bing Zhang,Li Chen,Luxia Cui,Xi-Ming Song*,Ogechi Ogoke, andGang Wu*, Advanced mesoporous spinel Li₄Ti₅O₁₂/rGO composites with increased surface lithium storage capability for high-power lithium-ion batteries, ACS Applied Material & Interfaces, 2016, 8, 9162-9169

37. Hao Ge,Tingting Hao, Bing Zhang,Li Chen,Luxia Cui,Xi-Ming Song*, Nanoparticles-constructed spinel Li₄Ti₅O₁₂with extra surface lithium storage capability towards advanced lithium-ion batteries, Electrochimica Acta, 2016, 211, 119-125

38. Shuyao Wu, Yuxiang Wang, Hui Mao, Chong Wang, Lixin Xia, Yu Zhang, Hao Ge, Xi-Ming Song*, Direct electrochemistry of cholesterol oxidase and biosensing of cholesterol based on PSS/polymeric ionic liquid-graphene nanocomposite, RSC Advances, 2016, 6, 59487-59496

39. Shuyao Wu, Jiali Chen, Daliang Liu, Qian Zhuang, Qi Pei, Lixin Xia, Qian Zhang*, Jun-ichi Kikuchi, Yoshio Hisaeda, Xi-Ming Song*, A biocompatible cerasome based platform for direct electrochemistry of cholesterol oxidase and cholesterol sensing, RSC Advances, 2016, 6, 70781-70790

40. Daliang Liu, Qian Zhuang, Ling Zhang, Hui Zhang, Shuyao Wu, Jun-ichi Kikuchi, Zhengbo Han, Qian Zhang*, Xi-Ming Song*, Self-assembly of novel fluorescent quantum dot-cerasome hybrid for bioelectrochemistry, Talanta, 2016, 154, 31-37

41. Hui Mao, Chunguang Ji, Meihong Liu, Ying Sun, Daliang Liu, Shuyao Wu, Yu Zhang, Xi-Ming Song*, Hydrophilic polymers/polypyrrole/graphene oxide nanosheets with different performence in electrocatalytic application to simultaneous determination of dopamine and ascorbic acid, RSC Advances, 2016, 6, 111632-111639

42. Hui Mao, Jiachen Liang, Chunguang Ji, Haifeng Zhang, Qi Pei, Yuyang Zhang, Yu Zhang, Yoshio Hisaeda, Xi-Ming Song*, Poly(zwitterionic liquids) functionalized polypyrrole/graphene oxide nanosheets for electrochemically detecting dopamine at low concentration, Materials Science and Engineering C, 2016, 65, 143-150

43. Hui Mao, Chao Wen, Shuyao Wu, Daliang Liu, Yu Zhang, Xi-Ming Song*, Mechanism of the formation and growth of fine particles clustered polymer microspheres by simple one-step polymerization in aqueous alcohol system, Applied Surface Science, 2016, 363, 395-405

44. Yu Zhang, Ting Feng, Xin Zhou, Qi Pei, Tingting Hao, Wei Zhang, Shuyao Wu, Hui Mao, Xi-Ming Song*, Facile preparation of one dimension ZnO/chalcogenide semiconductor heterostructure for efficient photoelectrochemical water splitting, Journal of Alloys and Compounds, 2016, 685, 581-586

45. Xuyang Ji, Qian Zhang, Xiaozhong Qu, Qian Wang, Xi-Ming Song*, Fuxin Liang*, Zhenzhong Yang, Poly(ionic liquid) Janus nanosheets towards dye degradation, RSC Advances, 2015, 5, 21877-21880

46. Ziguang Zhao, Fuxin Liang*, Guolin Zhang, Xuyang Ji, Qian Wang, Xiaozhong Qu,Ximing Song, Zhenzhong Yang*, Dually Responsive Janus Composite Nanosheets, Macromolecules, 2015, 48, 3598?3603

47. Hao Ge, Li Chen, Wei Yuan, Yu Zhang, Qingzhen Fan, Hannah Osgood, Daniel Matera, Xi-Ming Song*, Gang Wu, Unique mesoporous spinel Li₄Ti₅O₁₂nanosheets as anode materials for lithium-ion batteries, Journal of Power Source, 2015, 297, 436-441

48. Hao Ge, Ying Song, Hua Song, Hui Tian, Xi-Ming Song*, Ning Li, Daliang Liu, Shuyao Wu, Xicheng Shi, Advanced charge performance of pristine Li₄Ti₅O₁₂spinel for power lithium-ion battery, Ceramics International,2015, 41, 3869-3874

49. Hao Ge, Hui Tian, Hua Song, Daliang Liu, Shuyao Wu, Xicheng Shi, XiaoQiang Gao, Li Lv, Xi-Ming Song*, Study on the energy band structure and photoelectrochemical performances of spinel Li₄Ti₅O₁₂,Materials Research Bulletin, 2015, 61, 459-462

50. Hui Mao, Yang Song, Dongmei Qian, Daliang Liu, Shuyao Wu, Yu Zhang, Yoshio Hisaeda,Xi-Ming Song*, One-step preparation of flower-like poly (styrene-co-zwitterionic ionic liquid) microspheres with hierarchical, RSC Advances, 2015, 5, 91654-91664

51. Hui Mao, Haifeng Zhang, Jiachen Liang, Daliang Liu, Shuyao Wu, Yu Zhang, Yuyang Zhang, Qiuhua Wu, Guolin Zhang, Xi-Ming Song*, Preparation of poly(ionic liquids)-functionalized polypyrrole nanotubes and their electrocatalytic application to simultaneously determinate dopamine and ascorbic acid, Journal of Materials Chemistry B, 2015, 3, 5310–5317

52. Hui Mao, Jiachen Liang, HaifengZhang, Qi Pei, Daliang Liu, Shuyao Wu, Yu Zhang, Xi-Ming Song*, Poly(ionic liquids) functionalized polypyrrole/graphene oxide nanosheets for electrochemical sensor to detect dopamine in the presence of ascorbic acid, Biosensors and Bioelectronics, 2015, 70, 289–298

53. Hui Mao, Naiqi Gong, Qian Zhang, Daliang Liu, Chao Wen, Ying Li, Qiong Wu, Francis Verpoort, Xi-Ming Song*, Novel K-birnessite hierarchical hollow microspheres prepared from imidazolium groups modified surface of polystyrene microspheres, Materials Research Bulletin, 2015, 67, 102–110

54. Yu Zhang, Qi Pei, Jiachen Liang, Ting Feng, Xin Zhou, Hui Mao, Wei Zhang, Yoshio Hisaeda, Xi-Ming Song*, Mesoporous TiO₂-Based Photoanode Sensitized by BiOI and Investigation of Its Photovoltaic Behavior, Langmuir, 2015, 31, 10279-10284

55. Yu Zhang, Yù Zhang, Qi Pei, Ting Feng, Hui Mao, Wei Zhang, Shuyao Wu, Daliang Liu, Hongyu Wang, Xi-Ming Song*, Ionic liquid-modified metal sulfides/graphene oxide nanocomposites for photoelectric conversion, Applied Surface Science, 2015, 346, 194-200

56. Xuyang Ji, Qian Zhang, Fuxin Liang, Qinan Chen, Xiaozhong Qu, Chengliang Zhang, Qian Wang, Jiaoli Li, Ximing Song* and Zhenzhong Yang*, Ionic liquid functionalized Janus nanosheets, Chemical Communication, 2014, 50, 5706-5709

57. Yu Zhang, Shen Lin, Wei Zhang, Yù Zhang, Fuyuan Qi, Shuyao Wu, Qi Pei, Ting Feng, Xi-Ming Song*, Mesoporous titanium oxide microspheres for high-efficient cadmium sulfide quantum dot-sensitized solar cell and investigation of its photovoltaic behavior, Electrochimica Acta, 2014, 150, 167-172

58. Hao Ge, Hui Tian, Ming-Xia Li, Ting-Ting Hao, Ying Song, Fu-Yuan Qi, Qin-Zhen Fan, Xi-Ming Song*, Influence of reaction conditions on the reduction efficiency of the surface function groups of graphene oxide reduced by hydrazine hydrate, Journal of Liaoning University (Natural Sciences Edition), 2014, 41, 243-250

59. Hao Ge, Hui Tian, Yangen Zhou, Shuyao Wu, Daliang Liu, Xianzhi Fu, Xi-Ming Song*, Influence of Surface States on the Evaluation of the Flat Band Potential of TiO₂, ACS Applied Material & Interfaces, 2014, 6, 2401-2406

60. Hao Ge, Tingting Hao, Hui Tian, Ying Song, Hua Song, Daliang Liu, Shuyao Wu, Xi-Ming Song*. Hydrolysis-assisted synthesis of spherical spinel Li₄Ti₅O₁₂with advanced electrochemical performances for power lithium-ions battery, Ceramics International, 2014, 40, 14529-14532.

61. Hao Ge, Li Chen, Shen Lin, Xicheng Shi, Xi-Ming Song*, Advanced electrochemical performances of Li₄Ti₅O₁₂/Ag prepared by a facile synthesis route, Ionics, 2014, 20, 1189-1192

62. Yu Zhang, Shen Lin, Wei Zhang, Hao Ge, Gen Li, Yù Zhang, Fu-Yuan Qi, Xi-Ming Song*, Synthesis of a tailored SrTiO₃–TiO₂microspherical photocatalyst and its photogenerated charge properties, RSC Advances, 2014, 4, 3226–3232

63. Qian Zhang, Shu-Yao Wu, Ling Zhang, Hui Mao, Da-Liang Liu, Yang Liu, Xiang-Qun Zeng Xi-Ming Song*, Jing-Hong Li, Biocompatible phospholipid modified graphene nanocomposite for direct electrochemistry of redox enzyme, Acta Chimica Sinica, 2014, 72, 388-394

64. Wei Zhang, Hisashi Shimakoshi,Noriyuki Houfuku,Ximing Song, Yoshio Hisaeda, A polymerized ionic liquid-supported B₁₂ catalyst with a ruthenium trisbipyridine photosensitizer for photocatalytic dechlorination in ionic liquids, Dalton Transactions, 2014, 43, 13972-13978

65. Wei Zhang, Huicong Bai, Yu Zhang, Ying Sun, Shen Lin, Jian Liu, Qi Yang, Xi-Ming Song*, Enhanced photovoltaic effect of ruthenium complex-modified graphene oxide with P-type conductivity, Materials Chemistry and Physics, 2014, 147, 1140-1145

66. Qinzhen Fan, Gang Bai, Jiwei Yu, Shuyao Wu, Ximing Song*, Improvement of FCC gasoline aromatization for olefins reduction with modified nano-scale HZSM-5, Petroleum Science and Technology, 2014, 32, 2829-2836

67. Yun Qiao, Keishiro Tahara, Qian Zhang, Xi-Ming Song, Yoshio Hisaeda, Jun-ichi Kikuchi，Construction of molecular communication interface formed from cerasome and hydrophobic vitamin B₁₂ on glassy carbon electrode, Chemstry Letter, 2014, 43, 684–686