张维萍
院系：化工学院
办公电话：**(B栋323室)
电子信箱：wpzhang@dlut.edu.cn
更新时间：2015-9-1
其他专业：应用化学物理化学



个人简介
1994年获得大连理工大学 应用化学学士学位；1997年获得大连理工大学 有机化学硕士学位；
2000年获得中国科学院大连化学物理研究所 物理化学博士学位；
2000年至2004年 先后在苏黎世瑞士联邦理工学院 (ETH, Zurich)和加拿大国家研究理事会（National Research Council of Canada in Ottawa）进行博士后研究；
2004年至2010年中国科学院大连化学物理研究所 催化基础国家重点实验室
先后任副研究员、研究员、博士生导师、创新特区研究组组长
2011年至今 大连理工大学化工与环境生命学部 化工学院 精细化工国家重点实验室 教授 博士生导师


社会兼职
担任国际学术期刊Journal of the American Chemical Society, Journal of Physical Chemistry B/C, Journal of Catalysis, Applied Catalysis B, Chemistry-A European Journal, Microporous and Mesoporous Materials等和国内核心期刊《物理化学学报》、《化学学报》、《化工学报》等的审稿人

研究领域（研究课题）
研究领域：多孔功能材料、能源催化与原位核磁共振新方法

已主持5项国家自然科学基金项目、1项中国科学院“百人计划”择优资助项目和1项与德国BASF公司的国际合作项目；参加2项科技部“973”计划子课题研究
1. 原位固体核磁共振研究有序多级孔炭材料的结构及CO2 吸附分离机理，国家自然科学基金面上项目，2014.1-2017.12
2．原位磁共振研究新型层状扩孔分子筛的结构及对选择性催化反应的调控机理，国家自然科学基金面上项目，2012.1-2015.12
3. 用于基础化学制品生产中的分子筛类催化剂的修饰及应用(INCOE项目), 德国BASF公司国际合作项目, 2012.1-2016.12
4. 原位磁共振与功能催化材料，辽宁省高等学校杰出青年学者成长计划资助项目，2012.1-2015.12
5.离子液体中磷铝分子筛合成过程和晶化机理的原位固体核磁共振研究，国家自然科学基金面上项目，2009.1-2011.12
6．原位连续流动的超极化129Xe核磁共振技术及其在材料和多相催化研究中的应用，国家自然科学基金面上项目，2006.1-2008.12
7. 原位固体核磁共振与纳米催化，中国科学院“百人计划”择优资助项目，2006.1-2008.12
8．原位固体核磁共振研究过渡金属修饰的分子筛体系及催化烯烃歧化反应机理，国家自然科学基金青年基金项目，2005.1-2007.12
9. 原位核磁共振研究离子液体导向制备多孔催化材料的合成机理，催化基础国家重点实验室自主研究课题，2008.6-2010.6
10．新结构高性能多孔催化材料创制的基础研究 之 第六子课题-催化材料的原位动态谱学表征 科技部“973”计划，2004.12-2008.11
11．新结构高性能多孔催化材料的基础研究之第七子课题-催化剂和催化体系的构效关系和动态表征科技部“973”计划，2009.01-2013.08


硕博研究方向
1）纳米功能材料与能源环境催化

2）原位核磁共振结合密度泛函理论研究功能材料合成机理与催化反应机理



出版著作和论文
已在国内外核心期刊包括Chem. Soc. Rev.; JACS; Angew. Chem.; Chem.-Eur. J.; J. Phys. Chem.; PCCP; J. Catal.; Chem. Commun.; Anal. Chem.; J. Mol. Catal.;等发表SCI收录学术论文80余篇，其中作为第一作者和通讯作者发表论文60余篇，在第14届国际催化大会(Korea, 2008)、第16届国际分子筛大会（Italy, 2010）等国际和国内会议上口头报告12余次，已授权和申请中国专利4项、与德国BASF公司合作的国际专利（PCT）5项，合作撰写专著中3章。2011年受英国皇家化学会“Chemical Society Reviews”杂志邀请撰写有关原位核磁共振研究催化方面的综述。

主要期刊论文：

1)Structural Stability and Lewis Acidity of Tetravalent Ti, Sn, or Zr-linked Interlayer-expanded Zeolite COE-4: A DFT Study
Haichao Li, Juan Wang, Danhong Zhou, Dongxu Tian, Chuan Shi, Ulrich Müller, Mathias Feyen, Hermann Gies, Feng-Shou Xiao, Dirk De Vos, Toshiyuki Yokoi, Xinhe Bao, Weiping Zhang*
Microporous and Mesoporous Materials, 218: 160-166, (2015)

2)Al2O3 Nanosheets Rich in Pentacoordinate Al3+ Ions Stabilize Pt-Sn Clusters for Propane Dehydrogenation
Lei Shi, Gao-Ming Deng, Wen-Cui Li, Shu Miao, Qing-Nan Wang, Wei-Ping Zhang, An-Hui Lu*
Angew. Chem. Int. Ed., in press, (2015)

3)呋喃类平台化合物催化转化成可再生化学品和燃料
赵蓉蓉，张玉玲，张维萍*
《分子催化》，28（5）：485-495，（2014）

4)“Enhancement of Low-temperature Activity over Cu-exchanged Zeolite Beta from Organotemplate-free Synthesis for the Selective Catalytic Reduction of NOx with NH3 in Exhaust Gas Streams”
Li Xu, Chuan Shi*, Zhaoshun Zhang, Hermann Gies, Feng-Shou Xiao, Dirk De Vos, Toshiyuki Yokoi, Xinhe Bao, Mathias Feyen, Stefan Maurer, Bilge Yilmaz, Ulrich Müller*, Weiping Zhang*
Microporous and Mesoporous Materials, 200: 304-310, (2014)
Invited for the 60th birthday issue of Prof. Thomas Bein

5)“Framework Stability and Bronsted Acidity of Isomorphously Substituted Interlayer-expanded Zeolite COE-4: A Density Functional Theory Study”
Haichao Li, Danhong Zhou, Dongxu Tian, Chuan Shi, Ulrich Müller, Mathias Feyen, Bilge Yilmaz, Hermann Gies, Feng-Shou Xiao, Dirk De Vos, Toshiyuki Yokoi, Takashi Tatsumi, Xinhe Bao, Weiping Zhang*
ChemPhysChem, 15: 1700-1707, (2014)

6)“Density functional theory investigations into the structure and spectroscopic properties of the Ti4+ species in Ti-MWW zeolite”
Danhong Zhou*, Huijuan Zhang, Jiajia Zhang, Xiuming Sun, Haichao Li, Ning He, Weiping Zhang
Microporous and Mesoporous Materials, 195: 216-226, (2014)

7)"Insights into the Topotactic Conversion Process from Layered Silicate RUB-36 to FER-type Zeolite by Layer Reassembly"
Zhenchao Zhao, Weiping Zhang*, Pengju Ren, Xiuwen Han, Ulrich Müller, Bilge Yilmaz, Mathias Feyen, Hermann Gies Feng-Shou Xiao, Dirk De Vos, Takashi Tatsumi, Xinhe Bao*
Chemistry of Materials, 25(6): 840-847, (2013)

8)"Multinuclear Solid-state NMR Studies on the Formation Mechanism of Aluminophosphate Molecular Sieves in Ionic Liquids"
Renshun Xu, Weiping Zhang*, Jun Xu, Zhijian Tian, Feng Deng, Xiuwen Han, Xinhe Bao*
Journal of Physical Chemistry C, 117(11): 5848-5854, (2013)

9)“Rational synthesis of Beta zeolite with improved quality by decreasing crystallization temperature in organotemplate-free route”
Zhang, Haiyan; Xie, Bin; Meng, Xiangju; Mueller, Ulrich; Yilmaz, Bilge; Feyen, Mathias;Maurer, Stefan; Gies, Hermann; Tatsumi, Takashi; Bao, Xinhe; Zhang, Weiping; De Vos, Dirk; Xiao, Feng-Shou*
Microporous and Mesoporous Materials, 180: 123-129, (2013)

10)“A new catalyst platform: zeolite Beta from template-free synthesis”
*Yilmaz, Bilge; Mueller, Ulrich; Feyen, Mathias; Maurer, Stefan; Zhang, Haiyan; Meng, Xiangju; Xiao, Feng-Shou; Bao, Xinhe; Zhang, Weiping; Imai, Hiroyuki; Yokoi, Toshiyuki; Tatsumi, Takashi; Gies, Hermann; De Baerdemaeker, Trees; De Vos, Dirk
Catalysis Science & Technology, 3(10): 2580-2586, (2013)

11)“Catalytic applications of OSDA-free Beta Zeolite”
De Baerdemaeker, Trees; Yilmaz, Bilge; Mueller, Ulrich; Feyen, Mathias; Xiao, Feng-Shou; Zhang, Weiping; Tatsumi, Takashi; Gies, Hermann; Bao, Xinhe; *De Vos, Dirk
Journal of Catalysis, 308: 73-81, (2013)

12)"Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ionic liquid system"
Zhenchao Zhao, Weiping Zhang*, Renshun Xu, Xiuwen Han, Zhijian Tian, Xinhe Bao*
Dalton Transactions, 41(3): 990-994, (2012)

13)“In situ Solid-state NMR for Heterogeneous Catalysis : a Joint Experimental and Theoretical Approach”
Weiping Zhang*, Shutao Xu, Xiuwen Han, Xinhe Bao*
Chemical Society Reviews, Invited Critical Review Article, 41(1): 192-210, (2012)

14)“Al-RUB-41: a Shape-selective Zeolite Catalyst from a Layered Silicate”
Bilge Yilmaz*, Ulrich Muller, Bart Tijsebaert, Dirk De Vos, Bin Xie, Feng-Shou Xiao, Hermann Gies, Weiping Zhang, Xinhe Bao, Hiroyuki Imai, Takashi Tatsumi
Chemical Communications, 47: 1812-1814, (2011)

15)“Shape-selective Synthesis of Methylamines over the RRO Zeolite Al-RUB-41”
Bart Tijsebaert, Bilge Yilmaz,Ulrich Mueller, Hermann Gies, Weiping Zhang, Xinhe Bao, Feng-Shou Xiao, Takashi Tatsumi, Dirk De Vos*
Journal of Catalysis, 278(2): 246-252, (2011)

16)“Interlayer Expansion of the Layered Zeolite Precursor RUB-39: A Universal Method To Synthesize Functionalized Microporous Silicates”
Hermann Gies*, Ulrich Mller, Bilge Yilmaz, Takashi Tatsumi, Bin Xie, Feng-Shou Xiao, Xinhe Bao, Weiping Zhang, Dirk De Vos
Chemistry of Materials, 23(10), 2545-2554, (2011)

17)“Cooperative Structure-Directing Effect in the Synthesis of Aluminophosphate Molecular Sieves in Ionic Liquids”
Renshun Xu, Xiaochao Shi, Weiping Zhang*, Yunpeng Xu, Zhijian Tian, Xiaobing Lu, Xiuwen Han, Xinhe Bao*
Physical Chemistry Chemical Physics, 12(10): 2443-2449, (2010)

18)“Ionothermal Synthesis of the First Aluminophosphate Molecular Sieve with 20-Ring Pore Openings, DNL-1”
Ying Wei, Zhijian Tian*, Hermann Gies, Renshun Xu, Huaijun Ma, Renyan Pei, Weiping Zhang, Yunpeng Xu, Lei Wang, Keda Li, Bingchun Wang, Guodong Wen, Liwu Lin
Angew. Chem. Int. Ed., 49(31): 5367-5370 (2010) (Inner Cover Article)

19)“DFT Studies on the Reaction Mechanism of Cross-metathesis of Ethylene and 2-Butylene to Propylene over Heterogeneous Mo/HBeta Catalyst”
Xin Li, Jing Guan, Anmin Zheng, Danhong Zhou, Xiuwen Han, Weiping Zhang*, Xinhe Bao*
Journal of Molecular Catalysis A, 330: 99-106, (2010)

20)“Enhanced in situ Continuous-flow MAS NMR for Reaction Kinetics in the Nanocages”
Shutao Xu, Weiping Zhang*, Xianchun Liu, Xiuwen Han, Xinhe Bao*
J. Am. Chem. Soc., 131(38): 13722-13727, (2009)

21)“Investigation of the Physicochemical Changes Preceding Zeolite Nucleation in a Sodium-rich Aluminosilicate Gel”
Lama Itani, Yong Liu, Weiping Zhang*, Krassimir Bozhilov, Luc Delmotte, Valentin Valtchev*
J. Am. Chem. Soc., 131(29): 10127-10139, (2009)

22)“New Insights into the Role of Amines in the Synthesis of Molecular Sieves in Ionic Liquids”
Renshun Xu, Weiping Zhang*, Jing Guan, Yunpeng Xu, Lei Wang, Huaijun Ma, Zhijian Tian, Xiuwen Han, Liwu Lin, Xinhe Bao*
Chemistry-A European Journal, 15(21): 5348-5354, (2009)

23)“Insights into the Deactivation Mechanism of Heterogeneous Mo/HBeta-Al2O3 Catalysts for Olefin Metathesis”
Xiujie Li, Weiping Zhang*, Xin Li, Shenglin Liu, Huijuan Huang, Xiuwen Han, Longya Xu, Xinhe Bao*
Journal of Physical Chemistry C, 113(19): 8228-8233, (2009)

24)“Structure, Activity and Stability of Triphenyl Phosphine modified Rh/SBA-15 Catalyst for Hydroformylation of Propene: A High-resolution Solid-state NMR Study”
Xijie Lan, Weiping Zhang*, Li Yan, Yunjie Ding, Xiuwen Han, Liwu Lin, Xinhe Bao*
Journal of Physical Chemistry C, 113(16): 6589-6595, (2009)

25)“The Formation Mechanism of Mo-methylidene Species over Mo/HBeta Catalysts for Heterogeneous Olefin Metathesis: A DFT Study”
Jing Guan, Gang Yang, Danhong Zhou, Weiping Zhang, Xianchun Liu, Xiuwen Han, Xinhe Bao*
Journal of Molecular Catalysis A, 300(1-2): 41-47, (2009)

26)“Direct Observation of the Mesopores in ZSM-5 Zeolites with Hierarchical Porous Structures by Laser-hyperpolarized 129Xe NMR”
Yong Liu, Weiping Zhang*, Zhicheng Liu, Shutao Xu, Yangdong Wang, Zaiku Xie, Xiuwen Han, Xinhe Bao*
Journal of Physical Chemistry C, 112(39): 15375-15381, (2008)

27)“Effect of Water on the Ionothermal Synthesis of Molecular Sieves”
Huaijun Ma, Zhijian Tian,* Renshun Xu, Bingchun Wang, Ying Wei, Lei Wang, Yunpeng Xu, Weiping Zhang, Liwu Lin
J. Am. Chem. Soc., 130(26): 8120-8121, (2008)

28)“Probing the Porosity of co-crystallized MCM-49/ZSM-35 Zeolites by Hyperpolarized 129Xe NMR”
Yong Liu, Weiping Zhang*, Sujuan Xie, Longya Xu, Xiuwen Han, Xinhe Bao*
Journal of Physical Chemistry B, 112(4): 1226-1231, (2008)

29)“Olefin Metathesis over Heterogeneous Catalysts: the Interaction between Mo species and HBeta-Al2O3 Composite Support”
Xiujie Li, Weiping Zhang*, Shenglin Liu, Longya Xu, Xiuwen Han and Xinhe Bao*
Journal of Physical Chemistry C, 112(15): 5955-5960, (2008)

30)"Formation of Mo-carbene Active Sites in Mo/Beta Zeolite Catalysts with Different Olefins: Theoretical Exploration of Possible Reaction Pathways and Substituent Effects”
Jing Guan, Gang Yang, Danhong Zhou, Weiping Zhang, Xianchun Liu, Xiuwen Han, Xinhe Bao*
Catalysis Communications, 9: 2213-2216, (2008)

31)“The Role of Alumina in the Supported Mo/HBeta-Al2O3 Catalyst for Olefin Metathesis: A High-resolution Solid-state NMR and Electron Microscopy Study”
Xiujie Li, Weiping Zhang*, Shenglin Liu, Xiuwen Han, Longya Xu, Xinhe Bao*
Journal of Catalysis, 250(1): 55-66, (2007)

32)“Synthesis, Characterization and Catalytic Performance of Ti-Containing Mesoporous Molecular Sieves Assembled from Titanosilicate Precursors”
Changzi Jin, Gang Li,* Xiangsheng Wang, Lixia Zhao, Liping Liu, Haiou Liu, Yong Liu, Weiping Zhang, Xiuwen Han, Xinhe Bao
Chemistry of Materials, 19(7): 1664 – 1670, (2007)

33)“Study on Conformation Interconversion of 3-Alkyl-4-acetyl-3,4-dihydro-2H-1,4- benzoxazines from Dynamic NMR Experiments and ab Initio Density Functional Calculations”
Gang Yang, Xiuwen Han, Weiping Zhang, Xiumei Liu, Pengyu Yang, Yonggui Zhou, Xinhe Bao*
Journal of Physical Chemistry B, 109: 18690-18698, (2005)

34)"Distribution of Gallium Nanocrystals in Ga/MCM-41 Mesocomposites by Continuous-Flow Hyperpolarized 129Xe NMR Spectroscopy"
Weiping Zhang*, Christopher I. Ratcliffe, Igor L. Moudrakovski, Chung-Yuan Mou, John A. Ripmeester
Analytical Chemistry, 77(10): 3379-3382, (2005)

35)“Characterization of the Location and Interfacial States of Gallium in Gallium/MCM-41 Composites”
Weiping Zhang, Christopher I. Ratcliffe,* Igor L.Moudrakovski, John S. Tse, Chung-Yuan Mou, John A. Ripmeester
Microporous and Mesoporous Materials, 79(1-3): 195-203, (2005)

36)"A High-Resolution MAS NMR Study of the Structure of Fluorinated NiW/?-Al2O3 Hydrotreating Catalysts"
Weiping Zhang, Mingyong Sun, Roel Prins*
Journal of Physical Chemistry B, 107(40): 10977-10982, (2003)

37)"MAS NMR, TPR and TEM Studies of the Interaction of NiMo with Alumina and Silica-Alumina Supports"
Lianglong Qu, Weiping Zhang, Patricia Kooyman, Roel Prins*
Journal of Catalysis, 215(1): 7-13, (2003)

38)"Characterization of the Acid Sites in Dealuminated Nanosized HZSM-5 Zeolite with Probe Molecule Trimethylphosphine"
Weiping Zhang,* Xiuwen Han, Xiumei Liu, Xinhe Bao*
Journal of Molecular Catalysis A: Chemical, 194(1-2): 107-113, (2003)

39)"Multinuclear MAS NMR Identification of Fluorine Species on the Surface of Fluorinated gama-Alumina"
Weiping Zhang, Mingyong Sun, Roel Prins*
Journal of Physical Chemistry B, 106(45): 11805-11809, (2002)

40)"Investigation of the Microporous Structure and Non-framework Aluminum Distribution in Dealuminated Nanosized HZSM-5 Zeolite by 129Xe NMR Spectroscopy"
Weiping Zhang,* Xiuwen Han, Xianchun Liu, Hao Lei, Xiumei Liu, Xinhe Bao*
Microporous and Mesoporous Materials, 53(1): 145-152, (2002)

41)"The Stability of Nanosized HZSM-5 Zeolite: A High-resolution Solid-state NMR Study"
Weiping Zhang, Xiuwen Han, Xiumei Liu, Xinhe Bao*
Microporous and Mesoporous Materials, 50(1): 13-23, (2001)

42)"Xenon Probe for Detecting the Microporous Structure of Nanosized HZSM-5 Zeolite”
Weiping Zhang*, Xiuwen Han, Xianchun Liu, Hao Lei, Xinhe Bao*
Chemical Communications, (3): 293-294, (2001)

43)"Applications of In Situ NMR in Catalytic Processes of Organic Reactions"
Xiuwen Han, Zhimin Yan, Weiping Zhang, Xinhe Bao*
Current Organic Chemistry, 5(10): 1017-1037, (2001)

44)"In-situ 1H MAS NMR Spectroscopic Observation of Proton Species on A Mo-modified HZSM-5 Zeolite Catalyst for the Dehydromatization of Methane"
Ding Ma, Yuying Shu, Weiping Zhang, Xiuwen Han, Yide Xu, Xinhe Bao*
Angewandte Chemie International Edition, 39(6): 2928-2931, (2000)

45)"Perfluorotributyl amine as a Probe Molecule for Distinguishing Internal and External Acidic Sites in Zeolites by High-resolution 1H MAS NMR Spectroscopy"
Weiping Zhang, Ding Ma, Xianchun Liu, Xiumei Liu, Xinhe Bao*
Chemical Communications, (12): 1091-1092, (1999)

46)"Methane Dehydro-aromatization over Mo/HZSM-5 in the Absence of Oxygen: A Multinuclear Solid-state NMR Study of the Interaction between Supported Mo Species and HZSM-5 Zeolite with Different Crystal Sizes"
Weiping Zhang, Ding Ma, Xiuwen Han, Xiumei Liu, Xinhe Bao,* Xinwen Guo, Xiangsheng Wang
Journal of Catalysis, 188(2): 393-402, (1999)

47)"A High-resolution Solid-state NMR Study on Nano-structured HZSM-5 Zeolite"
Weiping Zhang, Xinhe Bao,* Xinwen Guo, Xiangsheng Wang
Catalysis Letters, 60(1,2): 89-94, (1999)

发表著作章节：

1)韩秀文，张维萍，包信和，“第9章核磁共振方法”，《固体催化剂研究方法》，辛勤主编，北京：科学出版社，2004年，p.433-464.

2)韩秀文，张维萍，包信和，“第8章核磁共振方法”，《现代催化研究方法》，辛勤、罗孟飞主编，北京：科学出版社，2009年，p.347-380.

3)冯兆池，张维萍，“催化材料的原位动态谱学表征”，《新结构高性能多孔催化材料》，谢在库主编，北京：中国石化出版社，2010年，p.340-412.


工作成果（奖励、专利等）
1）2012年入选辽宁省高等学校杰出青年学者成长计划
2) 2007年入选辽宁省百千万人才工程千人层次
3) 2005年入选中国科学院“百人计划”并获择优支持
4) 2002年加拿大政府实验室Visiting Fellowship
5) 2000年中国科学院院长奖学金优秀奖


在读学生人数
9人

毕业学生人数
指导2人硕士研究生已毕业，合作指导5人博士研究生已毕业