2013-09-12
张扣林,博士,教授,硕士生导师。
专业:无机化学
研究方向:配合物型功能材料
电话:13056348001
传真:0154-7975244
电子信箱: klzhang@yzu.edu.cn
教育经历:
1988, 9-1992, 7: 徐州师范大学化学系 化学教育专业
1992, 9-1995, 7: 南京大学化学化工学院 无机化学 专业 硕士
1999, 3-2002, 1: 南京大学化学化工学院 无机化学 专业 博士
2004, 1-2004, 7: 台 湾 淡江大学化学系 博士后
工作经历:
1995.11 - 至今,扬州大学 化学化工学院 工作 教授, 化学化工学院
现任扬州大学化学化工学院 无机化学教研室主任
研究领域和兴趣:
主要从事功能性配合物的设计、合成及性能的研究。
主要有三个方向:
1. 配合物型分子基磁性材料的设计、合成、结构及性质研究。主要目标为系统研究磁性与结构的关系,为能够定向设计并合成出具有特定功能的配合物型磁性材料打下坚实的基础。
2. 配合物型荧光材料的设计、合成、结构及性质的研究。主要目标为从分子设计的角度设计并合成出具有较好荧光性质的配合物,系统研究这些配合物的荧光性质与结构的关系,为能够定向设计并合成出较好荧光性能配合物型荧光材料打下基础。
3. 配合物型吸附材料的制备。主要目标为从分子设计的角度设计并合成出具有较好吸附性能的框架配位聚合物(MOF),通过研究吸附性能与结构的关系,为能定向设计并合成配合物型吸附材料打下基础。
获奖情况
2002年 扬州大学 优秀青年骨干教师
2001年 南京大学 研究生光华奖学金
科研成果
Selected Publications:
1、 K. -L. Zhang, Y.-J. Shi, S. Gao, Y. -D. Dai, X.-Z. You, Synthesis and characterization of a new iron(III) oxide cluster containing two different discrete [Fe3O] units: [Fe3O(O2CCH=CH---CH3)6(H2O)3][Fe3O(O2CCH=CH---CH3)7(H2O)2] (HO2CCH=CH---CH3)4(OH)(H2O). Inorg. Chem. Commum., 7 (2004) 584-587.
2、 K. -L. Zhang, Z. Wang, H. Huang, X.-Z. You, Synthesis, crystal structure and magnetic properties of a novel dinuclear cobalt(II) complex based on the mixed N- and O-donor ligands: [Co2(pyrazine)(fumarato)2(H2O)8]•7H2O. J. of Mol. Struct., 693 (2004) 193-197.
3、 K. -L. Zhang, Y. Xu, J. G. Lin, X.-Z. You, {[Cu(mal)(bipy)]•2H2O}n: a new one-dimensional ladder-like copper(II) complex based on the mixed N- and O-donor ligands with intrachain ferromagnetic interactions. J. of Mol. Struct., 1-3 (2004) 63-67.
4、 K. -L. Zhang, J. G. Lin, Y.-Q. Wang, W.-L. Xu,
a) Aquabis(2-nitrobenzoato-kO)(1,10-phenanthroline-k2N,N)zinc(II) Acta Cryst., 2004 C60 m454-456.
5、 K. -L. Zhang, Y. Xu, X.-Z. You, Synthesis, crystal and molecular structure and magnetic properties of an extended two-dimensional fumarato-bridged polymeric cobalt(II) complex [Co(l-fumarato)(c-methylpyridine)2(H2O)2]. Transition Met. Chem., 30 (2005) 376-379.
6、 K. -L. Zhang, H.-W. Kuai, G. –W. Diao,Synthesis, characterization and crystal structure of a novel coordination compound based on the mixed N- and O- donor ligands exhibiting the metal ion-bridged ligand–ligand interaction: [Zn(2,2’-bipy)(Phmal)(H2O)].2H2O. J. of Mol. Struct., 779/1-3 (2005) 11-15
7、 K. -L. Zhang, H.-W. Kuai, W.-L. Liu,G. –W. Diao, Self assembly of a novel mixed-ligand hydrogen bonding three dimensional supramolecular network [Co(Phmal)(Him)4] J. of Mol. Struct., 831 (2007) 114–118
8、 K. -L. Zhang, N. Qiao, H.-Y. Gao, F. Zhou, M. Zhang,. Self assembly of two novel three-dimensional supramolecular networks with blue photoluminescence Polyhedron, 26 (2007) 2461-2469.
9、 K. -L. Zhang, H.-Y. Gao, Z - C. Pan, W. Liang, G. –W. Diao, Preparation and characterization of two three-dimensionalmetal–organic photoluminescent supramolecular networks Polyhedron, 26 (2007) 5177-5184.
10、 K. -L. Zhang, H.-Y. Gao, N. Qiao, F. Zhou, G. –W. Diao, Preparation and characterization of two novel three-dimensional supramolecular networks with blue photoluminescence Inorg. Chim. Acta, 361 (2008) 153-160.
11、 K. -L. Zhang, F. Zhou, L.-M. Yuan, G-W Diao, S. W. Ng, Synthesis and characterization of a novel photoluminescent three-dimensional metal–organic framework Inorg. Chim. Acta, 362 (2009) 2510–2514
12、 K. -L. Zhang, W. Liang, Y. Chang, L.-M. Yuan, S. W. Ng, Syntheses, characterization and luminescent properties of two lead(II) fumarate metal-organic frameworks Polyhedron, 28 (2009) 647-652.
13、 K. -L. Zhang, Y. Chang, C. T. Hou, R. Wu, G. W. Diao, S. W. Ng, Effect of N-donor auxiliary ligands on the engineering of crystalline architectures of a series of lead(II) complexes with 5-amino-2,4,6-triiodoisophthalic acid CrystEngComm 12 (2010) 1194–1204.
14、 K. -L. Zhang, Z. -C. Pan, W. Liang, W.-L Liu, S. W. Ng, Synthesis and characterization of an energetic three-dimensional metal-organic framework with blue photoluminescence Materials Letter 63 (2009) 2136-2138.
15、 Y. Xu,J.-Q. Xu, K. -L. Zhang, X. Z. You, Keggin unit supported transition metal complexes: hydrothermal synthesis and ?characterization of [Ni(2,2’-bipy)3]1.5[PW12O40Ni(2,2’-bipy)2(H2O)] 0.5H2O?0.5H2O and [Co(1,10’-phen)3]1.5[PMo12O40Co(1,10’-phen)2(H2O)] Chem. Commum., (2000) 153-154.
16、 K. -L. Zhang,Y. Chang, J.-B. Zhang, L.-M. Yuan, Y. Deng, G.-W. Diao, S. W. Ng Synthesis, crystal structures and characterization of four coordination polymers based on 5-amino-2,4,6-triiodoisophthalic acid J. Solid. State Chem (2011) accepted.
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