职务：
联系电话：
办公地址： 化学楼C403
电子邮箱： wangxiaoliang@nju.edu.cn
http://hysz.nju.edu.cn/wangxl/
课题组主页：





个人简介


王晓亮，2002年和2009年分别获得南京大学化学系本科学位和高分子系博士学位。2007年9月至2008年9月国家公派，在美国麻省大学（University of Massachusetts, Amherst）H Henning Winter教授课题组从事流变学研究工作。2008年12月到2011年6月，在南京大学高分子系和物理系从事博后研究工作。2011年7月到2013年4月，在南京大学高分子系从事副研究员工作。2013年5月迄今，任南京大学高分子系副教授。






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工作经历




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研究方向


1、以流变学和核磁共振为基础的多尺度表征技术
........高分子具有复杂的聚集态结构及独特的物理化学性能，对其结构与性能之间关系的研究是我们认识高分子本质的基础，对开发新型高分子材料及发展高分子物理理论具有重要意义。从合成高分子样品到高分子的加工成型，人们对高分子的理解和认识包含了从微观的化学键、链间弱相互作用及链段分子运动到宏观性能等多尺度的过程。为了获得对高分子在这些不同尺度下结构与性能的深入理解，各种实验表征技术已经被广泛地应用到高分子材料的研究中。而在众多表征手段中，核磁共振波谱学和流变学这两种独特技术的检测范围都有着显著的多尺度特征，并且两者对应的检测特征尺度互为补充，因此两者的有机结合将成为人们认识高分子本质和理解高分子结构设计到加工成型的新桥梁。
........本课题组尝试将多尺度的固体NMR检测技术和流变学技术有机的结合起来，在高分子物理理论指导下来理解高分子及其复合材料的结构和动力学，进而揭示高分子复杂聚集态结构的形成和演化机理及不同层次结构与宏观性能间的关系，为新型高分子材料的设计与制备提供理论依据，并从新材料研究所呈现的实验新现象中进一步发展高分子物理理论。

2、高性能高分子复合材料的合成及其独特性能的微观机理
........高性能高分子复合材料是当前高分子领域的研究热点之一，不论是超强超韧的材料，还是有特殊响应性的材料，在很多情况下，他们的独特性能都是多尺度上不同相互作用协同的结果。比如有机粘土和液体橡胶的复合物凝胶体系就包含着界面上的有机-无机相互作用（0.5-1nm）、靠近界面的强链段吸附作用（1-10 nm）、以及在更大一些的尺度上（>10 nm）的弱链段吸附作用。分别对应着空间尺度的还有从十几微秒到秒量级的时间尺度的不均匀性。我们试图通过这些时间与空间的多尺度性信息，揭示不同高分子复合物体系独特性能的根源。




学术成果


2019年

1. Wang, X.L, Chain proximity of polystyrene in bulk polymer, polymer blend and nanocomposites.In NMR Methods for Characterization of Synthetic and Natural Polymers, Miyoshi, P. S. a. T., Ed. THE ROYAL SOCIETY OF CHEMISTRY: 2019; pp 241-260. (book)

2.Wang, J. C.; Yang, S. N.; Ding, P. T.; Cao, X. Y.; Zhang, Y.; Cao, S. T.; Zhang, K. K.; Kong, S. X.; Zhou, Y. L.; Wang, X. L.*; Li, D. C.*; Kong, D. S.*, Omnidirectional Printing of Soft Elastomer for Liquid-State Stretchable Electronics.ACS Appl. Mater. Interfaces2019, 11 (20), 18590-18598.
3.Lu, H. Y.; Wan, Y. X.; Wang, T. Y.; Jin, R.; Ding, P. T.; Wang, R.; Wang, Y.; Teng, C.; Li, L. L.; Wang, X. L.*; Zhou, D. S.*; Xue, G., A high performance SnO2/C nanocomposite cathode for aluminum-ion batteries.J. Mater. Chem. A2019, 7 (12), 7213-7220

2017年

1. Stabilization of Poly (methyl methacrylate) Nanofibers with Core-Shell Structures Confined in AAO Templates by the Balance between Geometric Curvature, Interfacial Interactions and Cooling Rate.
Zhang, C.; Li, L. L.; Wang, X. L.*; Xue, G.Macromolecules,2017，50,1599-1609

2.Zhang, C.; Sha, Y.; Zhang, Y.; Cai, T.; Li, L. L.; Zhou, D. S.; Wang, X. L.*; Xue, G., Nanostructures and Dynamics of Isochorically Confined Amorphous Drug Mediated by Cooling Rate, Interfacial, and Intermolecular Interactions. J. Phys. Chem. B 2017, 121 (47): 10704-10716.

3.Luo, S. C.; Wei, L.; Jiang, J.; Sha, Y.; Xue, G.; Wang, X. L.*; Zhou, D. S.*, Phase Separation Dynamics of a Poly(Vinyl Methyl Ether)/Polystyrene (PVME/PS) Blend Studied by Ultrafast Differential Scanning Calorimetry. J. Polym. Sci. Pt. B-Polym. Phys. 2017, 55 (18): 1357-1364.
4.Li, X.; Zhang, C.; Sha, Y.; Li, L. L.; Zhou, D. S.; Zhang, Z. X.; Xue, G.*; Wang, X. L.*, Cold flow of three-dimensional confined polymer systems. Polymer 2017, 111: 67-72
5. Wan, Y. X.; Xu, X. Q.; Liu, J. W.; Sha, Y.; Chen, Y. J.; Li, L. L.; Xue, G.; Wang, X. L.*; Zhou, D. S.*, A Cold-Flow Process for Fabricating a High-Volumetric-Energy-Density Anode for Lithium-Ion Batteries. Adv. Mater. Technol. 2017, 2 (1): 5.

6. How Thermal Stress Alters the Confinement of Polymers Vitrificated in Nanopores.
Teng, C.; Li, L.; Wang, Y.; Wang, R.; Chen, W.; Wang, X.*; Xue, G.The Journal of Chemical Physics,2017Accepted

2016年
1. Temperature dependent intercalation and self-exfoliation of clay/polymesssr nanocomposite.
Momani, B.; Sen, M.; Endoh, M.; Wang, X. L.; Koga, T.; Winter, H. H.Polymer2016,93204-212

2015年
1. Hydrogenation induced deviation of temperature and concentration dependences of polymer-solvent interactions in poly(vinyl chloride) and a new eco-friendly plasticizer.
Liu Y, Zhang R, Wang X*, Sun P, Chen W, Shen J, Xue, G.Eur. Phys. J. Plus2015,130(6), 1-11.

2. Effect of geometric curvature on vitrification behavior for polymer nanotubes confined in anodic aluminum oxide templates.
Jiao Chen, Linling Li, Dongshan Zhou, Xiaoliang Wang*, and Gi Xue*Physical Review E,2015, 92, 032306.

3.Effects of residual surfactant on the glass transition behavior of polystyrene/gold nanocomposites.
Lili Zhu, Xiaoliang Wang,* Qiang Gu, Rongchun Zhang, Tianxiong Ju, Yong Wang, Pingchuan Sun, and Gi Xue*.Polymer,2015, 77, 14-20.

4. Effect of PEO molecular weight on the miscibility and dynamics in epoxy/PEO blends.
Shoudong Lu, Rongchun Zhang, Xiaoliang Wang, Pingchuan Sun, Weifeng Lv, Qingjie Liu and Ninghong Jia.Eur. Phys. J. E,2015, 38, 118.

2014年
1. Critical Effect of Segmental Dynamics in Polybutadiene/Clay Nanocomposites Characterized by Solid State H-1 NMR Spectroscopy.
Gao Y, Zhang RC, Lv WF, Liu QJ,Wang XL*, Sun PC, Winter HH, and Xue G.J. Phys. Chem. C, 2014, 118, 5606-5614. （Abstract）

2. Complex microstructures of ABC triblock copolymer thin films directed by polymer brushes based on self-consistent field theory.
Zhibin Jiang, Chang Xu, Yu dong Qiu,Xiaoliang Wang*, Dongshan Zhou and Gi Xue.Nanoscale Research Letters2014,9:359

3. Investigation on the Mechanism of the Synthesis of Gold(I) Thiolate Complexes by NMR.
Yu CH, Zhu LL, Zhang RC,Wang XL*, Guo CC, Sun PC, and Xue G*.J. Phys. Chem. C, 2014, 118, 10434-10440. （Abstract）

4. The strong interaction between poly(vinyl chloride) and a new eco-friendly plasticizer: A combined experiment and calculation study.
Liu Y, Zhang RC,Wang XL*, Sun PC, Chen W, Shen JY, and Xue G*.Polymer, 2014, 55, 2831-2840. （Abstract）

5. Diffusion Behavior of Polystyrene/Poly(2,6-dimethyl-1,4-phenylene oxide) (PS/PPO) Nanoparticles Mixture: Diffusion Mechanism for Liquid PS and Glassy PPO.
Li LL,Wang XL, Zhou DS, Teng C, Sun Q, and Xue G*.Macromolecules, 2014, 47, 2131-2139. （Abstract）

2013年
1. Confinement-Induced Deviation of Chain Mobility and Glass Transition Temperature for Polystyrene/Au Nanoparticles.
Zhu LL,Wang XL, Gu Q, Chen W, Sun PC, and Xue G*.Macromolecules, 2013, 46, 2292-2297. （Abstract）

2. Characterization of the Mobility and Reactivity of Water Molecules on TiO2 Nanoparticles by H-1 Solid-State Nuclear Magnetic Resonance.
Zhu LL, Gu Q, Sun PC, Chen W,Wang XL*, and Xue G*.ACS Appl. Mater. Interfaces, 2013, 5, 10352-10356. （Abstract）

2012年前
1. Tracking the interdiffusion of polymers at a molecular level by H-1 dipolar filter solid-state NMR under fast magic angle spinning.
Gu Q,Wang XL, Sun PC*, Zhou DS*, and Xue G*.Soft Matter, 2011, 7, 691-697. （Abstract）

2. Late-State Ripening Dynamics of a Polymer/Clay Nanocomposite.
Wang XL, Sun PC*, Xue G*, and Winter HH*.Macromolecules, 2010, 43, 1901-1906. （Abstract）

3. Enhanced Exfoliation of Organoclay in Partially End-Functionalized Non-Polar Polymer.
Wang XL, Tao FF, Xue G*, Zhu JJ, Chen TH, Sun PC*, Winter HH*, and Shi AC.Macromol. Mater. Eng., 2009, 294, 190-195. （Abstract）

4. Probing the contraction and association of polystyrene chains in semidilute solution by non-radiative energy transfer.
Tao FF,Wang XL, Che B, Zhou DS, Chen W, Xue G*, Zou DW, and Tie ZX.Macromol. Rapid Commun., 2008, 29, 160-164. （Abstract）

5. Room temperature spontaneous exfoliation of organo-clay in liquid polybutadiene: Effect of polymer end-groups and the alkyl tail number of organic modifier.
Zhu JJ,Wang XL, Tao FF, Xue G*, Chen TH*, Sun PC*, Jin QH, and Ding DT.Polymer, 2007, 48, 7590-7597. （Abstract）

6. Probing chain interpenetration in polymer glasses by H-1 dipolar filter solid-state NMR under fast magic angle spinning.
Wang XL, Tao FF, Sun PC*, Zhou DS, Wang ZQ, Gu Q, Hu JL, and Xue G*.Macromolecules, 2007, 40, 4736-4739. （Abstract）

7. Characterization of polymer compatibility by H-1 dipolar filter solid-state NMR under fast magic angle spinning.
Wang XL, Gu Q, Sun Q, Zhou DS, Sun PC*, and Xue G*.Macromolecules, 2007, 40, 9018-9025. （Abstract）

8. Probing chain entanglement, interpenetration and proximity in polymer glasses by H-1 solid state NMR.
Gu Q,Wang XL, Tao FF, Sun PC, and Xue G.Acta Polym. Sin., 2007, 945-951. （Abstract）


9. Unusual rheological behavior of liquid polybutadiene rubber/clay nanocomposite gels: The role of polymer-clay interaction, clay exfoliation, and clay orientation and disorientation.
Wang XL, Gao Y, Mao KM, Xue G*, Chen TH, Zhu JJ, Li BH, Sun PC*, Jin QH, Ding DT, and Shi AC.Macromolecules, 2006, 39, 6653-6660. （Abstract）

10. Entropic contribution to the interaction parameter chi in the polymer/oligomer system: A lattice cluster theory consideration.
Zhou DS,Wang XL, Che B, Li L, Chen JL, and Xue G.Chin. J. Polym. Sci., 2005, 23, 159-163. （Abstract）

11. Crystallization and relaxation behavior of partially disentangled poly(vinyl chloride) prepared from large molecule solvent dioctyl phthalate.
Sun Q, Zhou DS,Wang XL, and Xue G.Macromolecules, 2002, 35, 7089-7092. （Abstract）





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