教授 曹剑瑜

Email: jycao@cczu.edu.cn; jyucao@hotmail.com

教育经历:
2006/09 – 2009/07,中科院上海微系统与信息技术研究所,材料物理与化学,博士
2001/09 – 2004/07,南京师范大学化学与环境科学学院,物理化学,硕士

工作经历：
2009/07 – 至今,常州大学石油化工学院,讲师(2006) 副教授(2011) 教授(2017) 博士生导师(2018)
2019/01 – 2019/12,澳大利亚昆士兰大学生物工程与纳米技术研究所,访问****
2013/08 – 2014/08,美国特拉华(Delaware)大学化学工程与分子工程系,访问****

荣誉与获奖：
江苏省高校“青蓝工程”中青年学术带头人(2019)
常州市自然科学论文三等奖(2019)
国家公派出国留学基金(2018)
常州市自然科学论文三等奖(2015)
江苏省高校“青蓝工程”中青年骨干教师(2014)
江苏省教育厅公派留学基金(2013)
常州市自然科学论文二等奖(2011)
江苏省企业博士人才项目(2011)
中国石油和化学工业协会(CPCIA)科技进步奖三等奖(2010)
常州市“831高层次创新创业人才培养工程”首批中青年骨干人才(2009)
中国科学院所长奖(2009)

社会兼职（社会兼职填是否担任过专业杂志编委、专业委员会委员、专业协会会员等）
中国化学会会员。

研究方向:
有机液流电池
纳米电催化

科研项目:
[1]国家自然科学基金面上项目(**): 基于氧化还原活性共价有机框架聚合物的水系全有机二次电池设计(2020-2023), 66万, 主持, 在研.
[2]国家自然科学基金面上项目(**): 基于醌类衍生物电化学的全有机水系液流电池高电位电解质研究(2016-2019), 66万, 主持, 结题.
[3]国家自然科学基金青年基金项目(**):直接甲醇燃料电池石墨烯基扩散层电极及传质机理研究(2012-2014), 主持, 结题.
[4]江苏省自然科学基金项目(BK**):石墨烯负载金属氢氧化物/石墨烯不对称电化学电容器研究(2013-2014), 主持, 结题.
[5]江苏省企业博士集聚计划项目(2011Z0062)：直接甲醇燃料电池膜电极的有序结构设计与性能研究(2011-2013), 主持, 结题.
[6]江苏省太阳能电池材料与技术重点实验室开放课题(201106): 有序碳基复合储能材料的制备及其电极动力学机理研究(2012-2013), 主持, 结题.

研究论文
1.Binbin Wang, Yang Zhang, Ye Zhu, Yong-Miao Shen, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹剑瑜)*, Juan Xu*, Redox-active poly(6-(1H-pyrrol-1-yl)quinoxaline) as a novel organic anode material for aqueous hybrid flow batteries, Journal of Power Sources, 2020, 451, 227788. https://doi.org/10.1016/j.jpowsour.2020.227788.
2.Yang Zhang, Wenjie Liu, Zheng Wang, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu*, Jianyu Cao(曹剑瑜)*, Tetrapyridophenazine/graphene composites for aqueous hybrid flow battery anodes with long cycle life, Carbon,2020, 161, 309-315.https://doi.org/10.1016/j.carbon.2020.01.092.
3. Xiaolin Li, Yongsheng Zhou, Yingying Du, Juan Xu*, Wenchang Wang, Zhidong Chen*,Jianyu Cao(曹剑瑜)*, PtCu nanoframes as ultra-high performance electrocatalysts for methanol oxidation, International Journal of Hydrogen Energy, 2019, 44, 18050-18057. https://doi.org/10.1016/j.ijhydene.2019.05.072.
4. Jianyu Cao(曹剑瑜), Fanfan Ding, Hongping Chen, Hongning Wang, Wenchang Wang, Zhidong Chen*, Juan Xu*, A new redox-active conjugated polymer containing anthraquinone pendants as anode material for aqueous all-organic hybrid-flow battery, Journal of Power Sources, 2019, 423, 316-322.https://doi.org/10.1016/j.jpowsour.2019.03.098.
5. Juan Xu, Huada Cao, Chaoying Ni, Yan Wang,Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Design and synthesis of sandwich-like CoNi₂S₄@C@NiCo-LDH microspheres for supercapacitors, Journal of Solid State Electrochemistry, 2019, 23, 1513-1522.https://doi.org/10.1007/s10008-019-04246-0.
6.Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors, Journal of Applied Electrochemistry, 2019, 1-12. https://doi.org/10.1007/s10800-019-01352-9.
7. Mingming Dong, Hongping Chen, Juan Xu*, Zhidong Chen* and Jianyu Cao(曹剑瑜)*, Synthesis of Cu-decorated PtTe nanotubes with high electrocatalytic activity for oxygen reduction,Journal of Alloys and Compounds, 2019, 770, 76-81. https://doi.org/10.1016/j.jallcom.2018.08.052
8. Jianyu Cao(曹剑瑜), Meng Tao, Hongping Chen, Juan Xu*, Zhidong Chen*, A highly reversible anthraquinone-based anolyte for alkaline aqueous redox flow batteries, Journal of Power Sources, 2018, 386, 40-46. https://doi.org/10.1016/j.jpowsour.2018.03.041
9. Jianyu Cao(曹剑瑜), Yingying Du, Mingming Dong, Zhidong Chen*, Juan Xu*, Template-free synthesis of chain-like PtCu nanowires and their superior performance for oxygen reduction and methanol oxidation reaction, Journal of Alloys and Compounds, 2018, 747, 124-130. https://doi.org/10.1016/j.jallcom.2018.03.025
10. Jianyu Cao(曹剑瑜), Xiaodi Jia, Mengwei Guo, Yingying Du, Juan Xu* and Zhidong Chen*, Fe–N co-decorated hierarchically porous graphene as a highly efficient electrocatalyst for the oxygen reduction reaction, Sustainable Energy & Fuels, 2, 169-174, DOI: 10.1039/c7se00458c (2018).
11. Jianyu Cao(曹剑瑜), Zhentao Zhu, Juan Xu*, Meng Tao and Zhidong Chen*, Nitrogen-doped porous graphene as a highly efficient cathodic electrocatalyst for aqueous organic redox flow battery application, Journal of Materials Chemistry A, 2017, 5, 7944–7951, DOI: 10.1039/c7ta00873b.
12. Jianyu Cao(曹剑瑜), Yue Hu, Lijuan Chen, Juan Xu*, Zhidong Chen*, Nitrogen-doped carbon quantum dot/graphene hybrid nanocomposite as an efficient catalyst support for the oxygen reduction reaction,International Journal of Hydrogen Energy, 2017, 42, 2931-2942, http://dx.doi.org/10.1016/j.ijhydene.2017.01.029.
13. Juan Xu, Chaojie Ma, Jianyu Cao(曹剑瑜)*and Zhidong Chen*, Facile synthesis of core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides as high-performance electrode materials for supercapacitors, Dalton Transactions, 2017, 46, 3276–3283, DOI: 10.1039/c6dt04759a.
14. Juan Xu, Kexing Hou, Zhengwei Ju, Chaojie Ma, Wenchang Wang, Cheng Wang, Jianyu Cao(曹剑瑜)*and Zhidong Chen*, Synthesis and Electrochemical Properties of Carbon Dots/Manganese Dioxide (CQDs/MnO₂) Nanoflowers for Supercapacitor Applications, Journal of The Electrochemical Society, 2017, 164(2), A430-A437, DOI: 10.1149/2.**jes.
15. Jianyu Cao(曹剑瑜), Zhentao Zhu, Weifang Zhao, Juan Xu* and Zhidong Chen*, Facile Synthesis of Carbon-Supported Ultrasmall Ag@Pd Core-Shell Nanocrystals with Superior Electrocatalytic Activity for Direct Formic Acid Fuel Cell Application, Chinese Journal of Chemistry, 2016, 34, 1086-1092, DOI: 10.1002/cjoc..
16. J. Xu, Y. Xue, J. Cao(曹剑瑜),*G. Wang, Y. Li, W. Wang and Z. Chen*, Carbon quantum dots/nickel oxide (CQDs/NiO) nanorods with high capacitance for supercapacitors, RSC Advances, 2016, 6, 5541–5546, DOI: 10.1039/c5ra24192h.
17. Juan Xu, Chao Yang, Yufei Xue, Cheng Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Facile synthesis of novel metal-organic nickel hydroxide nanorods for high performance supercapacitor, Electrochimica Acta2016,211, 595–602, http://dx.doi.org/10.1016/j.electacta.2016.06.090.
18. Juan Xu, Zhengwei Ju, Jianyu Cao(曹剑瑜)*, Wenchang Wang, Cheng Wang, Zhidong Chen*, Microwave synthesis of nitrogen-doped mesoporous carbon/nickelcobalt hydroxide microspheres for high-performance supercapacitors, Journal of Alloys and Compounds, 2016, 689, 489-499, http://dx.doi.org/10.1016/j.jallcom.2016.08.006.
19. Juan Xu, Guoxin Wang, Jianyu Cao(曹剑瑜)*, Yufei Xue, Yang Li, Wenchang Wang, Zhidong Chen*, Supercapacitor performances of rich nitrogen-doped mesoporous graphene fabricated by a facile template-free copyrolysis process, Ionics, 2016, 22, 1177–1184, DOI 10.1007/s11581-015-1624-7.
20. Jianyu Cao(曹剑瑜), Mengwei Guo, Jinyan Wu, Juan Xu, Wenchang Wang, Zhidong Chen*, Carbon-supported Ag@Pt core-shell nanoparticles with enhanced electrochemical activity for methanol oxidation and oxygen reduction reaction, Journal of Power Sources, 2015, 277, 155-160, http://dx.doi.org/10.1016/j.jpowsour.2014.12.017.
21. Jianyu Cao(曹剑瑜), Xiaojuan Yin, Liangduo Wang, Mengwei Guo, Juan Xu, Zhidong Chen*, Enhanced electrocatalytic activity of platinum nanoparticles supported on nitrogen-modified mesoporous carbons for methanol electrooxidation, International Journal of Hydrogen Energy, 2015, 40, 2971-2978, http://dx.doi.org/10.1016/j.ijhydene.2015.01.014.
22. Juan Xu, Xicheng Wei, Jianyu Cao(曹剑瑜)*, Yuanzhu Dong, Guoxin Wang, Yufei Xue, Wenchang Wang, Zhidong Chen*, Facile synthesis and electrochemical performances of binder-free flexible graphene/acetylene black sandwich film, Electrochimica Acta, 2015, 152, 391–397, http://dx.doi.org/10.1016/j.electacta.2014.11.201.
23. Juan Xu, Yang Li, Jianyu Cao(曹剑瑜)*, Rongrong Meng, Wenchang Wang and Zhidong Chen*, Preparation of graphene-supported highly dispersed nickel nanoparticles for the improved generation of hydrogen from ball-milled LiBH4, Catalysis Science & Technology, 2015, 5, 1821–1828, DOI: 10.1039/c4cy01276c.
24. Jianyu Cao(曹剑瑜), Hui Zhuang, Mengwei Guo, Hongning Wang, Juan Xu* and Zhidong Chen*, Facile preparation of mesoporous graphenes by the sacrificial template approach for direct methanol fuel cell application, Journal of Materials Chemistry A, 2014, 2, 19914–19919, DOI: 10.1039/c4ta05100a.
25. Jianyu Cao(曹剑瑜)*, Liangduo Wang, Lingzheng Song, Juan Xu, Hongning Wang, Zhidong Chen, Qinghong Huang, Hui Yang*, Novel cathodal diffusion layer with mesoporous carbon for the passive direct methanol fuel cell,Electrochimica Acta, 2014, 118, 163–168, http://dx.doi.org/10.1016/j.electacta.2013.11.140.
26. Jianyu Cao(曹剑瑜), Zhuanxia Chen, Juan Xu, Wenchang Wang, Zhidong Chena*, Mesoporous carbon synthesized from dual colloidal silica/block copolymer template approach as the support of platinum nanoparticles for direct methanol fuel cells, Electrochimica Acta, 2013, 88, 184–192, http://dx.doi.org/10.1016/j.electacta.2012.10.030.
27. Jianyu Cao(曹剑瑜), Lingzheng Song, Jiali Tang, Juan Xu, Wenchang Wang, Zhidong Chena*, Enhanced activity of Pd nanoparticles supported on Vulcan XC72R carbon pretreated via a modified Hummers method for formic acid electrooxidation, Applied Surface Science, 2013, 274, 138–143, http://dx.doi.org/10.1016/j.apsusc.2013.02.133.
28. Jianyu Cao(曹剑瑜), Jiali Tang, Lingzheng Song, Juan Xu, Wenchang Wang, Zhidong Chen*, Functionalization of activated carbon with EDTA and its effect on electrocatalytic performance of carbon supported Pd catalysts, Acta Phys. -Chim. Sin., 2013, 29(1), 144-150, doi: 10.3866/PKU.WHXB.
29. Jianyu Cao(曹剑瑜)*, Juan Xu, Zhidong Chen, Wenchang Wang, Qinghong Huang, Zhiqing Zou, A silicon-based micro direct methanol fuel cell stack with a serial flow path design, International Journal of Energy Research, 2013, 37, 370–376, DOI: 10.1002/er.1936.
30. Zhidong Chen, Zhuanxia Chen, Juan Xu, Wenchang Wang, Jianyu Cao(曹剑瑜)*, Highly dispersed Pt nanoparticles supported on mesoporous carbon and its electrocatalytic performance for ethylene glycol oxidation, Acta Chimica Sinica, 2012, 70(3), 241-246.
31. Jianyu Cao(曹剑瑜), Mei Chen, Ji Chen, Shenjun Wang, Zhiqing Zou, Zhilin Li, Daniel L. Akins* and Hui Yang*, Double microporous layer cathode for membrane electrode assembly of passive direct methanol fuel cells, International Journal of Hydrogen Energy, 2010, 35, 4622-4629, doi:10.1016/j.ijhydene.2010.02.012.

授权专利
[1]曹剑瑜,吴金燕,许娟,郭梦薇,王文昌,陈智栋, 一种碳载Co核-Pt壳纳米粒子催化剂及其制备方法(授权),中国发明专利,CN 1.0(2015)
[2]曹剑瑜,王进,许娟,展亮亮,陈智栋,一种锂离子电池负极材料及其制备方法(授权), 中国发明专利,CN7.4(2014)
[3]曹剑瑜,周慧,陈智栋,许娟,王文昌, 一种磷酸铁锂-碳-二氧化硅复合材料及其制备方法(授权), 中国发明专利,7.3(2014)
[4]许娟,魏曦晨,曹剑瑜,陈智栋,王文昌,高导电性柔性石墨烯膜电极的制备方法(授权), 中国发明专利,8.X(2015)
[5]许娟,居正伟,陈智栋,曹剑瑜,一种超级电容器用镍钴双氢氧化物/含氮碳纳米角复合材料及其制备方法(授权), 中国发明专利,3.6(2018)
[6]许娟,赵明学,曹剑瑜,陈智栋,王文昌,一种有机电解液体系不对称电化学电容器及其制备方法(授权), 中国发明专利,2.5(2015)
[7]许娟,邬纯晶,曹剑瑜,陈智栋,王文昌,一种含氮碳量子点/石墨相氮化碳复合光催化剂的制备方法(授权), 中国发明专利,2.3(2019)
[8]许娟,曹剑瑜,陈智栋,王文昌,一种基于金属有机配合物液流正极的水系单液流电池及其制备方法(授权), 中国发明专利,1.3(2019)