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南昌航空大学环境与化学工程学院导师教师师资介绍简介-宋仁杰
本站小编 Free考研考试/2021-05-05
职称称号:副教授
行政职务:科技处副处长
电子邮件:srj0731@hnu.edu.cn
研究方向: 有机合成方法学和环境有机化学
教育背景:
2006年9月-2011年6月 湖南师范大学,化学化工学院,硕博连读,有机化学专业,导师李金恒教授
2002年9月-2006年6月 湖南师范大学,化学化工学院,化学工程与工艺专业
工作履历:
2016年1月-至今 南昌航空大学,环境与化学工程学院,副教授
2013年11月-2016年1月 湖南大学,化学化工学院,助理研究员
2014年4月-2015年3月 兰州大学访问****,合作导师涂永强院士
2011年7月-2013年11月 湖南大学,化学化工学院,博士后,有机化学专业,导师郭灿诚教授和李金恒教授
研究领域:有机合成方法学和环境有机化学
科研项目:
主持基金情况:
(1)国家自然科学基金面上项目“水体中汞离子在含氮杂环功能有机吸附剂的强化富集去除研究(**)”、2019/01-2022/12、60万元、在研。
(2)国家自然科学基金地区项目“硅烷参与的烯烃双官能团化反应研究(**)”、2018/01-2021/12、38万元、在研。
(3)江西省自然科学青年基金项目“以苯并呋喃类化合物的合成为导向的碳-氢官能团化反应研究(20181BAB213002)”、2018/01-2019/12、6万元、在研。
(4)江西省科技厅重点项目“以具有生理活性杂环骨架合成为导向的烯烃双官能团化反应研究(20171ACB21032)”、2017/01-2019/12、20万元、在研。
(5)江西省****基金项目(20171BCB23055)、2017/01-2019/12、15万元、在研。
(6)江西省教育厅项目“廉价过渡金属催化烯烃双官能团化反应研究(GJJ160725)”、2017/01-2018/12、2万元、在研。
(7)湖南省自然科学基金项目“铜或铁催化烯烃双官能团化反应研究(2016JJ3033)”、2016/01-2018/12、5万元、在研。
(8)国家自然科学青年科学基金项目“铜或铁催化醛参与的炔烃氧化官能团化反应研究(**)”、2015/01-2017/12、25万元、结题。
(9)湖南省科技厅重点研发计划项目“以甾体药物合成为导向的烯烃双官能团化反应研究(2015JC3052)”、2015/01-2016/12、5万元、结题。
(10)中央高校基本科研业务费湖南大学青年教师成长计划资助2014/01-2018/12、10万元、在研。
(11)湖南省科技厅项目“以昆虫激素的合成为导向的醛脱羰基加成反应研究(2013RS4026)”、2013/01-2014/12、3万元、结题。
(12)中国博士后基金“过渡金属催化α-氨基羰基化合物α-C-H氧化反应研究”(2012M511716)、2012/06-2013/06、5万元、结题。
(13)湖南省研究生创新基金“基于C-H活化的串联反应合成抗肿瘤靶向药物吲哚-2-酮类化合物的研究”(CX2009B104)、2009/03-2011/03、1万元、结题。
学术成果:
共发表SCI论文116篇,其中以通迅作者或第一作者(含共同第一作者)发表论文59篇,参与撰写专著《Copper-mediated cross-coupling reactions》第11章,《Fe-, Ag-Catalyzed Synthesis of Heterocycles in Transition-metal Catalyzed Heterocycle Synthesis via C-H Activation》第7章。
(一)论文发表:
1.Ying-Xia Dong, Yang Li, Chang-Cheng Gu, Shuai-Shuai Jiang, Ren-Jie Song* , and Jin-Heng Li*, Copper-Catalyzed Three-Components Intermolecular Alkylesterification of Styrenes with Toluenes and Peroxyesters or Acids, Org. Lett., 2018, DOI: 10.1021/acs.orglett.8b03330. (通讯作者)
2.Rongkui Su, Yang Li, Man-Yi Min, Xuan-Hui Ouyang,* Ren-Jie Song* and Jin-Heng Li*, Copper-catalyzed oxidative intermolecular 1,2-alkylarylation of styrenes with ethers and indoles, Chem. Commun, 2018, DOI:10.1039/c8cc08274j. (通讯作者)
3.Xuan-Hui Ouyang, Yang Li, Ren-Jie Song* , and Jin-Heng Li*, Alkylamination of Styrenes with Alkyl N-Hydroxyphthalimide Esters and Amines by B(C6H5)3-Facilitated Photoredox Catalysis, Org. Lett. 2018, 20, 6659-6662. (通讯作者)
4.Xin Yong, Ya-Fei Han, Yang Li,* Ren-Jie Song* and Jin-Heng Li*, Alkylarylation of styrenes via direct C(sp3)-Br/C(sp2)-H functionalization mediated by photoredox and copper cooperative catalysis, Chem. Commun., 2018, 54, 12816-12819. (通讯作者)
5.Xuan-Hui Ouyang, Fang-Lin Tan, Ren-Jie Song*, Wei Deng, and Jin-Heng Li*, Palladium-Catalyzed Oxidative [2 + 2 + 1] Annulation of 1,7-Diynes with H2O: Entry to Furo[3,4-c]quinolin-4(5H)-ones, Org. Lett., 2018, 20, 6765-6768. (通讯作者)
6.Xuan-Hui Ouyang, Ming Hu, Ren-Jie Song*, and Jin-Heng Li*, Oxidative three-component 1,2-alkylarylation of alkenes with alkyl nitriles and N-heteroarenes, Chem. Commun., 2018,54, 12345-12348. (通讯作者)
7.Li-Jun Wu, Ren-Jie Song*, Shenglian Luo, Jin-Heng Li*, Palladium-Catalyzed Reductive [5+1] Cycloaddition of 3-Acetoxy-1,4-enynes with CO: Access to Phenols Enabled by Hydrosilanes, Angew.Chem.Int.Ed, 2018, 57, 13308-1331. (通讯作者)
8.Xuan-Hui Ouyang, Ren-Jie Song*, Jin-Heng Li*, Developments in the Chemistry of α-Carbonyl Alkyl Bromides, Chem.Asian J, 2018, 13, 2316-2332. (通讯作者)
9.Jie Lin, Ren-Jie Song*, Ming Hu, Jin-Heng Li*, Recent Advances in the Intermolecular Oxidative Difunctionalization of Alkenes, Chem. Rec. 2018, 18, 1-13. (通讯作者)
10.Xuan-Hui Ouyang, Chao Hu, Ren-Jie Song*, and Jin-Heng Li*, [4 + 2] Annulation Cascades of 2-Bromo-1-arylpropan-1-ones with Terminal Alkynes Involving C-Br/C-H Functionalization, Org. Lett. 2018, 20, 4659-4662. (通讯作者)
11.Yu Liu, Ren-Jie Song*, Shenglian Luo and Jin-Heng Li*, Visible-Light-Promoted Tandem Annulation of N?(o?Ethynylaryl)acrylamides with CH2Cl2, Org. Lett. 2018, 20, 212-215. (通讯作者)
12.Li-Jun Wu, Yuan Yang, Ren-Jie Song*, Jiang-Xi Yu, Jin-Heng Li* and De-Liang He*, An access to 1,3-azasiline-fused quinolinones via oxidative heteroannulation involving silyl C(sp3)-H functionalization, Chem. Commun. 54, 1367-1370. (通讯作者)
13.Yuan Yang, Ren-Jie Song*, Yang Li, Xuan-Hui Ouyang, Jin-Heng Li* and De-Liang He*, Oxidative radical divergent Si-incorporation: facile access to Si-containing heterocycle, Chem. Commun. 2018, 54, 1441-1444. (通讯作者)
14.Gao-Hui Pan, Ren-Jie Song* and Jin-Heng Li*, Radical-mediated synthesis of γ-lactones by copper-catalyzed intermolecular carboesterification of alkenes with α-carbonyl alkyl bromides and H2O, Org. Chem. Front. 2018, 5, 179-183.(通讯作者)
15.Gao-Hui Pan, Ren-Jie Song*, Ye-Xiang Xie, Shenglian Luo, Jin-Heng Li*, Synthesis of Amino Esters by Copper-Catalyzed Intermolecular 1,2-Aminoalkylation of Alkenes with Amines and α-Bromoalkyl Esters, Synthesis 2018, 50, 1651–1660(通讯作者)
16.Yuan Yang, Ren-Jie Song*, Xuan-Hui Ouyang, Cheng-Yong Wang, Jin-Heng Li* and Shenglian Luo*, Iron-Catalyzed Intermolecular 1,2-Difunctionalization of Styrenes and Conjugated Alkenes with Silanes and Nucleophiles, Angew. Chem. Int. Ed. 2017, 56, 7916-7919. (通讯作者)
17.Yu Liu, Ren-Jie Song* and Jin-Heng Li*, Palladium-catalyzed dearomatizative [2+2+1] carboannulation of 1,7-enynes with aryl diazonium salts and H2O: facile synthesis of spirocyclohexadienone-fused cyclopenta[c]quinolin-4(5H)-ones, Chem. Commun. 2017, 53, 8600-8603. (通讯作者)
18.Fang-Lin Tan,+ Ming Hu,+ Ren-Jie Song* and Jin-Heng Li*, Metal-Free Annulation Cascades of 1,7-Enynes Using Di-tertbutyl Peroxide as the Methyl Source towards the Synthesis of Polyheterocyclic Scaffolds, Adv. Synth. Catal. 2017, 359, 3602-3610. (通讯作者)
19.Li-Jun Wu,+ Fang-Lin Tan,+ Meng Li, Ren-Jie Song* and Jin-Heng Li*, Fe-Catalyzed oxidative spirocyclization of N-arylpropiolamides with silanes and TBHP involving the formation of C-Si bonds, Org. Chem. Front. 2017, 4, 350-353. (通讯作者)
20.Meng Li, Ren-Jie Song* and Jin-Heng Li*, Nickel-Promoted Oxidative ipso-Annulation of N-(p-Methoxyaryl)propiolamides with α-Carbonyl Alkyl Bromides, Chin. J. Chem. 2017, 35, 299-302. (通讯作者)
21.Ren-Jie Song* and Ye-Xiang Xie, Recent Advances in Oxidative ipso-Annulation of N-Arylpropiolamides, Chin. J. Chem. 2017, 35, 280-288. (通讯作者)
22.Chao Hu+, Ren-Jie Song+, Ming Hu, Yuan Yang, Jin-Heng Li*, Shenglian Luo*, [5+2] Cycloaddition of 2-(2-Aminoethyl)oxiranes with Alkynes via Epoxide Ring-Opening: A Facile Access to Azepines, Angew. Chem. Int. Ed. 2016, 55(35), 10423-10426.(共同第一作者)
23.Xuan-Hui Ouyang+, Ren-Jie Song+, Ming Hu, Yuan Yang, and Jin-Heng Li*, Silver-Mediated Intermolecular 1,2-Alkylarylation of Styrenes with α-Carbonyl Alkyl Bromides and Indoles, Angew. Chem. Int. Ed. 2016, 55, 3187-3191. (+共同第一作者)
24.Yang Li, Gao-Hui Pan, Ming Hu, Bang Liu, Ren-Jie Song*, Jin-Heng Li*, Intermolecular oxidative decarbonylative [2+2+2] carbocyclization of N-(2-ethynylaryl)acrylamideswith tertiary and secondary alkyl aldehydesinvolving C(sp3)-H functionalization, Chem. Sci. 2016, 7, 7050-7054.(通讯作者)
25.Fang-Lin Tan, Ren-Jie Song*, Ming Hu, Jin-Heng Li*, Metal-Free Oxidative 1,2-Arylmethylation Cascades of N-(Arylsulfonyl)acrylamides Using Peroxides as the Methyl Resource, Org. Lett. 2016, 18(13), 3198-3201.(通讯作者)
26.Guo-Bo Deng, Hai-Bing Li, Xu-Heng Yang, Ren-Jie Song*, Ming Hu, Jin-Heng Li*, Dehydrogenative [2 + 2 + 1] Heteroannulation Using a Methyl Group as a One-Carbon Unit: Access to Pyrazolo[3,4?c]quinolines, Org. Lett. 2016, 18(9), 2012-2015.(通讯作者)
27.Xuan-Hui Ouyang, Ren-Jie Song*, Bang Liu and Jin-Heng Li, Synthesis of 3-alkyl spiro[4,5]trienones by copper-catalyzed oxidative ipso-annulation of activated alkynes with unactivated alkanes, Chem. Commun. 2016, 52, 2573-2576. (通讯作者)
28.Ming Hu, Ren-Jie Song,* Xuan-Hui Ouyang, Fang-Lin Tan, Wen-Ting Wei, and Jin-Heng Li*, Copper-catalyzed oxidative [2+2+1] annulation of 1,n-enynes with a-carbonyl alkyl bromides through C–Br/C–H functionalization, Chem. Commun., 2016, 52, 3328-3331. (通讯作者)
29.Xuan-Hui Ouyang, Ren-Jie Song*, Bang Liu, Jin-Heng Li*, Metal-Free Oxidative Decarbonylative Hydroalkylation of Alkynes with Secondary and Tertiary Alkyl Aldehydes, Adv. Synth. Catal. 2016, 358(12), 1903-1909.(通讯作者)
30.Yang Li, Bang Liu, Ren-Jie Song*, Qiu-An Wang*, Jin-Heng Li*, Visible Light-Initiated C(sp3)-Br/C(sp3)-H Functionalization of a-Carbonyl Alkyl Bromides through Hydride Radical Shift, Adv. Synth. Catal. 2016, 358(8), 1219-1228.(通讯作者)
31.Meng Li, Ji Yang, Xuan-Hui Ouyang, Yuan Yang, Ming Hu, Ren-Jie Song*, Jin-Heng Li*, 1,2-Alkylarylation of Styrenes with a?Carbonyl Alkyl Bromides and Indoles Using Visible-Light Catalysis, J. Org. Chem. 2016, 81(16), 7148-7154.(通讯作者)
32.Ren-Jie Song, Jia-Dong Xia, Jiang-Xi Yu*, Jin-Heng Li*, Redox-triggered hydroarylation of o-(hydroxyalkyl)arylalkynes with arylsulfonyl chlorides using visible light catalysis, Science China Chemistry, 2016, 59(2), 184-189.(第一作者)
33.Xuan-Hui Ouyang, Ren-Jie Song,* Yu Liu, Ming Hu, and Jin-Heng Li*, Copper-Catalyzed Radical [2 + 2 + 1] Annulation of Benzene-Linked 1,n?Enynes with Azide: Fused Pyrroline Compounds, Org. Lett. 2015, 17, 6038-6041. (通讯作者).
34.Bang Liu, Ren-Jie Song*, Xuan-Hui Ouyang, Yang Li, Ming Hu, and Jin-Heng Li*, Palladium-catalyzed oxidative 6-exo-trig cyclization of 1,6-enynes: facile synthesis of bicyclo [4.1.0] heptan-5-ones, Chem. Commun. 2015, 51(64), 12819-12822. (通讯作者).
35.Xuan-Hui Ouyang, Ren-Jie Song*, Cheng-Yong Wang, Yuan Yang, and Jin-Heng Li*, Metal-free carbonyl C(sp2)-H oxidative alkynylation of aldehydes using hypervalent iodine reagents leading to ynones, Chem. Commun. 2015, 51(77), 14497-14500. (通讯作者).
36.Ren-Jie Song, Yong-Qiang Tu*, Dao-Yong Zhu, Fu-Min Zhang and Shao-Hua Wang, A nickel-mediated oxidative α-C(sp3)–H functionalization of amides with allylic alcohols terminated by radical 1,2-aryl migration, Chem. Commun. 2015, 51, 749-752. (第一作者)
37.Xu-Heng Yang, Xuan-Hui Ouyang, Wen-Ting Wei, Ren-Jie Song*, and Jin-Heng Li*, Nitrative Spirocyclization Mediated by TEMPO: Synthesis of Nitrated Spirocycles from N-Arylpropiolamides, tert-Butyl Nitrite and Water, Adv. Synth. Catal. 2015, 357(6), 1161-1166. (通讯作者).
38.Xu-Heng Yang, Ren-Jie Song*, and Jin-Heng Li*, Metal-Free [4+2] Annulation of Arylalkynes with tert-Butyl Nitrite through C(sp2)-H Oxidation to Assemble Benzo[e][1,2]oxazin-4-ones, Adv. Synth. Catal. 2015, 357, 3849-3856. (通讯作者).
39.Yang Li, Bang Liu, Xuan-Hui Ouyang, Ren-Jie Song*, and Jin-Heng Li*, Alkylation/1,2-aryl migration of α-aryl allylic alcohols with α-carbonyl alkyl bromides using visible-light photoredox catalysis, Org. Chem. Front. 2015, 2(11), 1457-1467. (通讯作者).
40.Peng-Cheng Qian, Yu Liu, Ren-Jie Song*, Jian-Nan Xiang, and Jin-Heng Li*, Copper-Catalyzed Oxidative ipso-Cyclization of N-(p-Methoxyaryl)propiolamides with Disulfides and Water Leading to 3-(Arylthio)-1-azaspiro[4.5]deca-3,6,9-triene-2,8-diones, Synlett 2015, 26(9), 1213-1216. (通讯作者).
41.Ren-Jie Song, Yu Liu, Ye-Xiang Xie, and Jin-Heng Li*, Difunctionalization of Acrylamides through C-H Oxidative Radical Coupling: New Approaches to Oxindoles, Synthesis 2015, 47(9), 1195-1209. (第一作者)
42.Xuan-Hui Ouyang, Ren-Jie Song*, Yang Li, Bang Liu, Jin-Heng Li*. Metal-Free Oxidative Ipso-Carboacylation of Alkynes: Synthesis of 3-Acylspiro[4,5]trienones from N-Arylpropiolamides and Aldehydes. J. Org. Chem. 2014, 79(10), 4582-4589 (通讯作者).
43.Xuan-Hui Ouyang, Ren-Jie Song*, Jin-Heng Li*. Iron-Catalyzed Oxidative 1,2-Carboacylation of Activated Alkenes with Alcohols: A Tandem Route to 3-(2-Oxoethyl)indolin-2-ones. Eur. J. Org. Chem. 2014, 16, 3395-3401 (通讯作者).
44.Mao-Mei Zhang, Jun Gong, Ren-Jie Song*, and Jin-Heng Li*, Synthesis of Internal Alkynes by Pd(PPh3)4/TMEDA-Catalyzed Kumada Cross-Coupling of Alkynyl Halides with Grignard Reagents, Eur. J. Org. Chem.2014, (30), 6769-6773. (通讯作者).
45.Jian-Hong Fan, Ming-Bo Zhou, Yu Liu, Wen-Ting Wei, Xuan-Hui Ouyang, Ren-Jie Song*, Jin-Heng, Li*, Iron-Catalyzed Oxidative Arylmethylation of Activated Alkenes Using a Peroxide as the Methyl Source, Synlett 2014, 25, 657-660 (通讯作者).
46.Ye-Xiang Xie, Ren-Jie Song*, Yu Liu, Zhi-Qiang Wang, Jian-Nan Xiang* and Jin-Heng Li*, Base-Mediated Synthesis of 1-Aryl-4-(phenylsulfonyl)- butan-1-ones from 1,2-Bis(phenylsulfonyl)ethane and Ketones, Synthesis 2014, 46(2), 203–211 (通讯作者).
47.Ming-Bo Zhou, Ren-Jie Song,* Xuan-Hui Ouyang, Yu Liu, Wen-Ting Wei, Guo-Bo Deng, and Jin-Heng Li*, Metal-Free Oxidative Tandem Coupling of Activated Alkenes with Carbonyl C(sp2)-H Bonds and Aryl C(sp2)-H Bonds Using TBHP, Chem. Sci. 2013, 4, 2690-2694 (通讯作者).
48.Ye-Xiang Xie, Ren-Jie Song*, Yu Liu, Yan-Yun, Liu, Jian-Nan Xiang, and Jin-Heng Li*, Copper-Catalyzed α-Aminoxylation of Ketones with 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO), Adv. Synth. Catal. 2013, 355(17), 3387-3390 (通讯作者).
49.Ye-Xiang Xie, Ren-Jie Song,* Xu-Heng Yang, Jian-Nan Xiang, and Jin-Heng Li*, Copper-Catalyzed Amidation of Acids Using Formylamides as the Amine Resources, Eur. J. Org. Chem. 2013, 25, 5737-5742 (通讯作者).
50.Ji-Cheng Wu+, Ren-Jie Song+, Zhi-Qiang Wang, Xiao-Cheng Huang, Ye-Xiang Xie, and Jin-Heng Li*, Copper-Catalyzed C-H Oxidation/Cross-Coupling of α-Amino Carbonyl Compounds, Angew. Chem. Int. Ed. 51(14), 3453-3457, 2012. (+共同第一作者)
51.Ren-Jie Song, Ji-Cheng Wu, Yu Liu, Guo-Bo Deng, Cui-Yan Wu, Wen-Ting Wei, and Jin-Heng Li*, Copper-Catalyzed Oxidative Cyanation of Aryl Halides with Nitriles Involving a Carbon-Carbon Cleavage, Synlett 2012, 23(17), 2491-2496. (第一作者)
52.Ren-Jie Song, Yan-Yun Liu, Ji-Cheng Wu, Ye-Xiang Xie,* Guo-Bo Deng, Xu-Heng Yang, Yu Liu, Jin-Heng Li*, Base-Mediated Tandem Reaction of α-Aryloxyacetophenones with Phosphonates: Selective Synthesis of Enol Phosphates, Synthesis 2012, 44(7), 1119-1125. (第一作者)
53.Ren-Jie Song, Yan-Yun Liu, Ji-Cheng Wu, Yu Liu, Guo-Bo Deng, Xiao-Xu Qi, Ye-Xiang Xie,* Lu-Bin Gong, Wei Liu, and Jin-Heng Li*, Synthesis of Methylene-Bridged 2,4-Diarenoxy-1,5-diarylpentane-1,5-diones by Base-Mediated Tandem Reaction, Synthesis 2012, 44(18), 2919-2925. (第一作者)
54.Bo-Xiao Tang+, Ren-Jie Song+, Cui-Yan Wu, Zhi-Qiang Wang, Yu Liu, Xiao-Cheng Huang, Ye-Xiang Xie, Jin-Heng Li*, Ruthenium-Catalyzed Intramolecular Carbocyclization of Alkynes with an sp3 Carbon Involving an Oxidative Deprotonation Process, Chem. Sci. 2011, 2(11), 2131-2134 (+共同第一作者).
55.Ren-Jie Song, Yu Liu, Rui-Xiang Hu, Yan-Yun Liu, Ji-Cheng Wu, Xu-Heng Yang, Jin-Heng Li*, Oxidative Cleavage of the Carbon-Carbon s-Bond Using Reusable Copper on Iron, Adv. Synth. Catal. 2011, 353(9), 1467-1473. (第一作者)
56.Ren-Jie Song, Yu Liu, Yan-Yun Liu, Jin-Heng Li*, Palladium-Catalyzed Conjugate Addition to Electron-Deficient Alkynes with Benzenesulfinic Acid Derived from 1,2-Bis(phenylsulfonyl)ethane: Selective Synthesis of (E)-Vinyl Sulfones, J. Org. Chem. 2011, 76(3), 1001-1004. (第一作者)
57.Ren-Jie Song, Yu Liu, Rong-Jiang Li, Jin-Heng Li*, Selective Synthesis of 3-Methyleneindolin-2-ones by One-pot Multicatalytic Processes, Tetrahedron Lett. 2009, 50(27), 3912-3916. (第一作者)
58.Ren-Jie Song, Chen-Liang Deng, Ye-Xiang Xie, Jin-Heng Li*, Solvent-Free Copper/Iron co-Catalyzed N-Arylation Reactions of Nitrogen-Containing Heterocycles with Trimethoxysilanes in Air, Tetrahedron Lett. 2007, 48(44), 7845-7848. (第一作者)
59.Yan-Yun Liu,+ Xu-Heng Yang,+ Ren-Jie Song, Shenglian Luo* and Jin-Heng Li*, Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles, Nat. Commun. 2017, 8, 14720. (第一作者,学生在前).
60.Bang Liu,+ Cheng-Yong Wang,+ Ming Hu, Ren-Jie Song, Fan Chen* and Jin-Heng Li*, Copper-promoted [2+2+2] annulation of 1,n-enynes through decomposition of azobis(alkyl nitrile)s, Chem. Commun. 2017, 53, 1265-1268.
61.Ming Hu, Ling-Yu Guo, Ying Han*, Fang-Lin Tan, Ren-Jie Song and Jin-Heng Li*, Intermolecular cascade annulations of N-(arylsulfonyl)acrylamides with dual C(sp3)-H bonds: divergent access to indanes and pyrrolidin-2-ones, Chem. Commun. 2017, 53, 6081-6084.
62.Ming Hu, Meng Li, Fang-Lin Tan, Ren-Jie Song, Ye-Xiang Xie* and Jin-Heng Li*, Oxidative Divergent Bicyclizations of 1,n-Enynes through α-C(sp3)-H Functionalization of Alkyl Nitriles, Adv. Synth. Catal. 2017, 359, 120-129.
63.Ji Yang, Yan-Yun Liu, Ren-Jie Song, Zhi-Hong Peng*, Jin-Heng Li*, Copper-Mediated 1,2-Difunctionalization of Styrenes with Sodium Arylsulfinates and tert-Butyl Nitrite: Facile Access to a-Sulfonylethanone Oximes, Adv. Synth. Catal. 2016, 358(14), 2286-2292.
64.Xu-Heng Yang, Ren-Jie Song, Ye-Xiang Xie*, Jin-Heng Li*, Iron Catalyzed Oxidative Coupling, Addition, and Functionalization, ChemCatChem, 2016, 8(15), 2429 – 2445.
65.Cheng-Yong Wang, Ren-Jie Song, Ye-Xiang Xie,* and Jin-Heng Li,* Silver-Promoted Oxidative Ring Opening/Alkynylation of Cyclopropanols: Facile Synthesis of 4-Yn-1-ones, Synthesis, 2016, 2, 223-230.
66.Yu Liu,* Ren-Jie Song, and Jin-Heng Li*, The Cycloaddition Reaction Using Visible Light Photoredox Catalysis, Science China Chemistry, 2016, 59(2), 161-170.
67.Ming Hu, Ren-Jie Song, and Jin-Heng Li*, Metal-Free Radical 5-exo-dig Cyclizations of Phenol-Linked 1,6-Enynes for the Synthesis of Carbonylated Benzofurans, Angew. Chem. Int. Ed. 2015, 54(2), 608-612.
68.Ming Hu, Jian-Hong Fan, Yu Liu, Xuan-Hui Ouyang, Ren-Jie Song, and Jin-Heng Li*, Metal-Free Radical [2+2+1] Carbocyclization of Benzene-Linked 1,n-Enynes: Dual C(sp3)-H Functionalization Adjacent to a Heteroatom, Angew. Chem. Int. Ed. 2015, 54(33), 9577-9580.
69.Yuan Yang, Ming-Bo Zhou, Xuan-Hui Ouyang, Rui Pi, Ren-Jie Song, and Jin-Heng Li*, Rhodium(III)-Catalyzed [3+2]/[5+2] Annulation of 4-Aryl 1,2,3-Triazoles with Internal Alkynes through Dual C(sp2)-H Functionalization, Angew. Chem. Int. Ed. 2015, 54(22), 6595-6599.
70.Wen-Ting Wei, Hai-Bing Li, Ren-Jie Song, and Jin-Heng Li*, Copper-catalyzed oxidative oxyalkylation of enol ethers with alpha-amino carbonyl compounds and hydroperoxides, Chem. Commun. 2015, 51(56), 11325-11328.
71.Rui Pi, Ming-Bo Zhou, Yuan Yang, Cai Gao, Ren-Jie Song, and Jin-Heng Li*, Rhodium(III)-catalyzed oxidative bicyclization of 4-arylbut-3-yn-1-amines with internal alkynes through C-H functionalization, Chem. Commun. 2015, 51(70), 13550-13553.
72.Cheng-Yong Wang, Ren-Jie Song, Wen-Ting Wei, Jian-Hong Fan, and Jin-Heng Li*, Copper-catalyzed oxidative coupling of acids with alkanes involving dehydrogenation: facile access to allylic esters and alkylalkenes, Chem. Commun. 2015, 51(12), 2361-2363.
73.Jian-Hong Fan, Ji Yang, Ren-Jie Song, and Jin-Heng Li*, Palladium-Catalyzed Oxidative Heck-Type Alkylation/Aryl Migration/Desulfonylation between Alkenes with alpha-Carbonyl Alkyl Bromides, Org. Lett. 2015, 17(4), 836-839.
74.Ming Hu, Bang Liu, Xuan-Hui Ouyang, Ren-Jie Song, and Jin-Heng Li*, Nitrative Cyclization of 1-Ethynyl-2-(vinyloxy)benzenes to Access 1- 2-(Nitromethyl)benzofuran-3-yl Ketones Through Dioxygen Activation, Adv. Synth. Catal. 2015, 357(14-15), 3332-3340.
75.Peng-Cheng Qian, Yu Liu, Ren-Jie Song, Ming Hu, Xu-Heng Yang, Jian-Nan Xiang, and Jin-Heng Li*, (Diacetoxyiodo) benzene-Mediated Oxygenation of Benzylic C(sp3)-H Bonds with N-Hydroxyamides at Room Temperature, Eur. J. Org. Chem. 2015, (8), 1680-1684.
76.Peng-Cheng Qian, Ren-Jie Song, Hui-Ying Liao, Hong-Tao Wang, Ye-Xiang Xie*, Jian-Nan Xiang and Jin-Heng Li*, Synthesis of Malonates from 3-Halopropynoates, Alcohols, and Water Using DABCO, Synthesis 2015, 47(21), 3309-3314.
77.Ming-Bo Zhou, Ren-Jie Song, and Jin-Heng Li,* Hexafluoroantimonic Acid Catalyzed Formal [3+2+2] Cycloaddition of Aziridines with Two Alkynes, Angew. Chem. Int. Ed. 2014, 53, 4196-4199.
78.Ming-Bo Zhou, Rui Pi, Ming Hu, Yuan Yang, Ren-Jie Song, Yuanzhi Xia, and Jin-Heng Li, Rhodium(III)-Catalyzed [3+2] Annulation of 5-Aryl-2,3-dihydro-1H-pyrroles with Internal Alkynes through C(sp2)-H/Alkene Functionalization, Angew. Chem. Int. Ed. 2014, 53(42), 11338-11341.
79.Jian-Hong Fan, Wen-Ting Wei, Ming-Bo Zhou, Ren-Jie Song, Jin-Heng Li*, Palladium-Catalyzed Oxidative Difunctionalization of Alkenes with α-Carbonyl Alkyl Bromides Initiated through a Heck-type Insertion: A Route to Indolin-2-ones, Angew. Chem. Int. Ed. 2014, 53, 6650-6654.
80.Yu Liu, Jia-Ling Zhang, Ren-Jie Song, Peng-Cheng Qian, Jin-Heng Li*, Cascade Nitration/Cyclization of 1,7-Enynes with tBuONO and H2O: One-Pot Self-Assembly of Pyrrolo[4,3,2-de]quinolinones, Angew. Chem. Int. Ed. 2014, 53, 9017-9020.
81.Yu Liu, Jia-Ling Zhang, Ren-Jie Song, and Jin-Heng Li, Sulfur Incorporation: Copper-Catalyzed Cascade Cyclization of 1,7-Enynes with Metal Sulfides toward Thieno[3,4-c]quinolin-4(5H)-ones, Org. Lett. 2014, 16(22), 5838-5841.
82.Yan-Yun Liu, Xu-Heng Yang, Ji Yang, Ren-Jie Song, Jin-Heng Li*, Silver-mediated radical cyclization: construction of Δ2-isoxazolines from α-halo ketoximes and 1,3-dicarbonyl compounds, Chem. Commun. 2014, 50, 6906-6908.
83.Xu-Heng Yang, Wen-Ting Wei, Hai-Bing Li, Ren-Jie Song, and Jin-Heng Li, Oxidative coupling of alkenes with amides using peroxides: selective amide C(sp3)-H versus C(sp2)-H functionalization, Chem. Commun. 2014, 50(85), 12867-12869.
84.Yu Liu, Jia-Ling Zhang, Ming-Bo Zhou, Ren-Jie Song, and Jin-Heng Li, Copper-catalyzed cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides toward selective assembly of benzo[j]phenanthridin-6(5H)-ones, Chem. Commun. 2014, 50(92), 14412-14414.
85.Wen-Ting Wei, Ren-Jie Song, Xuan-Hui Ouyang, Yang Li, Hai-Bing Li and Jin-Heng Li* Copper-catalyzed oxidative ipso-carboalkylation of activated alkynes with ethers leading to 3-etherified azaspiro[4.5]trienones, Org. Chem. Front. 2014, 1, 484-489.
86.Yu Liu, Jia-Ling Zhang, Ren-Jie Song, and Jin-Heng Li, 1,2-Alkylarylation of activated alkenes with dual C-H bonds of arenes and alkyl halides toward polyhalo-substituted oxindoles, Org. Chem. Front. 2014, 1(11), 1289-1294.
87.Ming-Bo Zhou, Xiao-Cheng Huang, Yan-Yun Liu, Ren-Jie Song, Jin-Heng Li,* Alkylation of Terminal Alkynes with Transient s-Alkylpalladium(II) Complexes: A Carboalkynylation Route to Alkyl-Substituted Alkynes, Chem. Eur. J. 2014, 20(7), 1843–1846.
88.Yan-Yun Liu, Ji Yang, Ren-Jie Song, and Jin-Heng Lia, Synthesis of 5-(Fluoromethyl)-4,5-dihydroisoxazoles by Silver-Catalyzed Oxyfluorination of Unactivated Alkenes, Adv. Synth. Catal. 2014, 356(14-15), 2913-2918.
89.Wen-Ting Wei, Ren-Jie Song, Jin-Heng Li*, Copper-Catalyzed Oxidative α-Alkylation of α-Amino Carbonyl Compounds with Ethers via Dual C(sp3)-H Oxidative Cross-Coupling, Adv. Synth. Catal. 2014, 356(8), 1703-1707.
90.Ye-Xiang Xie, Ri-Yuan Tang,* Ren-Jie Song, Jian-Nan Xiang, and Jin-Heng Li,* Synthesis of Benzocyclohepta[b]indoles by Lewis Acid Catalyzed Annulation of Two 3-(1H-Isochromen-1-yl)-1H-indoles, J. Org. Chem. 2014, 79(2), 686-691.
91.Xiao-Cheng Huang, Xu-Heng Yang, Ren-Jie Song, and Jin-Heng Li,* Rhodium-Catalyzed Synthesis of Isoquinolines and Indenes from Benzylidenehydrazones and Internal Alkynes, J. Org. Chem. 2014, 79(3), 1025–1031.
92.Xu-Heng Yang, Kai Li, Ren-Jie Song and Jin-Heng Li*, Room-Temperature Palladium-Catalyzed Intramolecular Oxidative Aminocarbonylation of Vinylic C(sp2)-H Bonds with Amines and CO, Eur. J. Org. Chem. 2014, (3), 616–623.
93.Yu Liu, Jia-Ling Zhang, Ren-Jie Song, Jin-Heng Li, Visible-Light-Facilitated 5-exo-trig Cyclization of 1,6-Dienes with Alkyl Chlorides: Selective Scission of the C(sp3)–H Bond in Alkyl Chlorides, Eur. J. Org. Chem. 2014, (6), 1177–1181.
94.Jia-Ling Zhang, Yu Liu, Ren-Jie Song, Guo-Fang Jiang*, Jin-Heng Li* 1,2-Alkylarylation of Activated Alkenes with Two C–H Bonds by Using Visible-Light Catalysis, Synlett, 2014, 25(07), 1031-1035.
95.Guo-Bo Deng, Zhi-Qiang Wang, Jia-Dong Xia, Peng-Cheng Qian, Ren-Jie Song, Ming Hu, Lu-Bin Gong, and Jin-Heng Li*, Tandem Cyclization of 1,6-Enynes with Arylsulfonyl Chlorides Using Visible Light Photoredox Catalysis, Angew. Chem. Int. Ed. 2013, 52(5), 1535–1538.
96.Wen-Ting Wei, Ming-Bo Zhou, Jian-Hong Fan, Wei, Liu, Ren-Jie Song, Yu Liu, Ming Hu, Peng Xie, and Jin-Heng Li*, Synthesis of Oxindoles by Iron-Catalyzed Oxidative Alkylarylation of Activated Alkenes with an Aryl C(sp2)-H bond and a C(sp3)-H Bond Adjacent to a Heteroatom, Angew. Chem. Int. Ed. 2013, 52(13), 3638-3641.
97.Ming-Bo Zhou, Ren-Jie Song, Cheng-Yong Wang, and Jin-Heng Li*, Synthesis of Azepine Derivatives by Silver-Catalyzed [5+2] Cycloaddition of γ-Amino Ketones with Alkynes, Angew. Chem. Int. Ed. 2013, 52(41), 10805–10808.
98.Ming-Bo Zhou, Cheng-Yong Wang, Ren-Jie Song, Yu, Liu, Wen-Ting Wei, and Jin-Heng Li*, Oxidative 1,2-difunctionalization of activated alkenes with benzylic C(sp3)-H bonds and aryl C(sp2)-H bonds, Chem. Commun. 2013, 49(92), 10817-10819.
99.Peng Xie, Zhi-Qiang Wang, Guo-Bo Deng, Ren-Jie Song, Jia-Dong Xia, Ming Hu, and and Jin-Heng Li*, Copper-Catalyzed Aerobic Oxidative Carbocyclization-Ketonization Cascade: Selective Synthesis of Quinolinones, Adv. Synth. Catal. 2013, 355(11-12), 2257-2262.
100.Yan-Yun Liu, Xu-Heng, Yang, Xiao-Cheng Huang, Wen-Ting Wei, Ren-Jie Song and Jin-Heng Li*, Palladium-Catalyzed Methylation of Alkynyl C(sp)-H Bonds with Dimethyl Sulfonium Ylides, J. Org. Chem., 2013, 78(22), 10421-10426.
101.Ji-Cheng Wu, Lu-Bing Gong, Yuan-zhi Xia, Ren-Jie Song, Ye-Xiang Xie, and Jin-Heng Li*, Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents Leading to Alkenes and Modified Arylketones, Angew. Chem. Int. Ed. 2012, 51(39), 9909-9913.
102.Bo-Xiao Tang, Yue-Hua Zhang, Ren-Jie Song, Dong-Jun Tang, Guo-Bo Deng, Zhi-Qiang Wang, Ye-Xiang Xie, Yuan-Zhi Xia, Jin-Heng Li*, Intramolecular ipso-Halocyclization of 4-(p-Unsubstituted aryl)-1-alkynes Leading to Spiro[4,5]trienones: Scope, Application, and Mechanistic Investigations, J. Org. Chem. 2012, 77(6), 2837-2849.
103.Cui-Yan Wu, Ming Hu, Yu Liu, Ren-Jie Song, Yong Lei, Bo-Xiao Tang, Rong-Jiang Li, Jin-Heng Li*, Ruthenium-Catalyzed annulation of Alkynes with Amides via Formyl Translocation, Chem. Commun. 2012, 48(26), 3197-3199.
104.Wen-Ting Wei, Peng Xie, Jia-Dong Xia, Ye-Xiang Xie,* Ren-Jie Song, Jian-Nan Xiang, and Jin-Heng Li*, Au-Catalyzed Skeletal Rearrangement of 1-(2-(1H-Isochromen-3-yl)aryl)ethanones with Alcohols, Synthesis 2012, 44(13), 2049-2057.
105.Yan-Yun Liu, Ren-Jie Song, Cui-Yan Wu, Lu-Bin Gong, Ming Hu, Zhi-Qiang Wang, Ye-Xiang Xie, Jin-Heng Li*, Palladium-Catalyzed Oxidative C-C Bond Cleavage Cyclization of Biaryl-2-amines with Alkenes Involving C-H Olefination and Carboamination, Adv. Synth. Catal. 2012, 354(2-3), 347-353.
106.Bo Yao, Ren-Jie Song, Yan Liu, Ye-Xiang Xie, Jin-Heng Li*, Meng-Ke Wang, Ri-Yuan Tang, Xing-Guo Zhang, Chen-Liang Deng,* Palladium-Catalyzed C-H Oxidation of Isoquinoline N-Oxides: Selective Alkylation with Dialkylsulfoxides and Halogenation with Dihalosulfoxides, Adv. Synth. Catal. 2012, 354(10), 1890-1896.
107.谢叶香,宋仁杰,向建南*,李金恒*,过渡金属催化C-H氧化反应研究,有机化学(Chin. J. Org. Chem.) 2012, 32(9), 1555-1567.
108.Zhi-Qiang Wang, Yong Lei, Ming-Bo Zhou, Guo-Xiang Chen, Ren-Jie Song, Ye-Xiang Xie, Jin-Heng Li*, Iron-Mediated [3+2] or [3+3] Annulation of 2-(2-(Ethynyl)phenoxy)-1-arylethanones: Selective Synthesis of Indeno[1,2-c]chromenes and 5H-Naphtho[1,2-c]chromenes, Org. Lett. 2011, 13(1), 14-17.
109.Guo-Bo Deng, Zhi-Qiang Wang, Ren-Jie Song, Ming-Bo Zhou, Wen-Ting Wei, Peng Xie, Jin-Heng Li*, Synthesis of 3-(Aminomethylene)-2-oxoindolines by Palladium-Catalyzed Annulation of 3-Chloro-2-iodo-N-Arylacrylamides with Amides or Amines, Chem. Commun. 2011, 47(28), 8151-8153.
110.Rong-Jiang Li, Shao-Feng Pi, Yun Liang,* Zhi-Qiang Wang, Ren-Jie Song, Guo-Xiang Chen, Jin-Heng Li*, Palladium-Catalyzed Annulations of Arynes with 2-(2-Iodophenoxy)-1-substituted ethanones through a-Arylation of Ketones, Chem. Commun. 2010, 46(43), 8183-8185.
111.Bo-Xiao Tang, Ren-Jie Song, Cui-Yan Wu, Yu Liu, Ming-Bo Zhou, Wen-Ting Wei, Guo-Bo Deng, Du-Lin Yin, Jin-Heng Li*, Copper-Catalyzed Intramolecular C-H Oxidation/Acylation of Formyl-N-arylformamides Leading to Indoline-2,3-diones, J. Am. Chem. Soc. 2010, 132(8), 8900-8902.
112.Yu Liu, Ren-Jie Song, Jin-Heng Li*, Yb(OTf)3-Promoted ZnCl2-Catalyzed Conia-ene Reactions of Linear β-Alkynic β-Dicarbonyls, Synthesis 2010, (21), 3663-3669.
113.Chen-Liang Deng, Ren-Jie Song, Yi-Lin Liu, Jin-Heng Li*, Gerneral Zinc-Catalyzed Conia-Ene Reactions of 1,3-dicarbonly Compounds with Alkynes Including the Classsically Challenging Substrates under Neat Conditions, Adv. Synth. Catal. 2009, 351(18), 3096-3100.
114.Chen-Liang Deng, Tao Zou, Zhi-Qiang Wang, Ren-Jie Song, Jin-Heng Li*, Copper/Silver-Cocatalyzed Conia-Ene Reactions of 2-Alkynic 1,3-Dicabonyl Compounds, 2009, J. Org. Chem. 74(1), 412-414.
115.Chen-Liang Deng, Ren-Jie Song, Sheng-Mei Guo, Zhi-Qiang Wang, Jin-Heng Li*, Copper/Silver-Cocatalyzed Conia-Ene Reaction of Linear α-Alkynic β-Ketoesters, Org. Lett. 2007, 9(24), 5111-5114.
116.Yue-Hua Zhang, Ren-Jie Song, Ye-Xiang Xie, Chen-Liang Deng, Yun Liang, Jin-Heng Li*, β-Keto Amides: Inexpensive and Efficient Ligands for the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction, Synthesis 2007, (19), 2957-2966.
(二)专著:
1.Ren-Jie Song, Jin-Heng Li, Copper-catalyzed alkynylation, alkenylation, and allylation reactions of aryl derivatives, in Copper-Mediated Cross-Coupling Reactions (Eds.: Evano, Gwilherm; Blanchard, Nicolas), John Wiley & Sons, Hoboken, New Jersey, pp. 401 – 453, 2014.
2.Jin-Heng Li, Ren-Jie Song, Fe-, Ag-Catalyzed synthesis of heterocycles in Transition-metal catalyzed heterocycle synthesis via C-H activation, (Eds.: Xiao-Feng Wu), Wiley-VCH, Weinheim, pp. 291 – 315, 2016.
(三)会议论文:
1.宋仁杰,李金恒*, 1,n-烯炔环化串联反应新方法研究, 中国化学会第九届有机化学学术会议论文集,2015,长春,口头报告.
2.Ren-Jie Song, New Strategy For The Synthesis of Oxindoles: The C-H Oxidative Functionalization, 中国化学会第七届有机化学学术会议论文集,2013,重庆,优秀墙报奖.
3.Jin-Heng Li,* Ren-Jie Song, Zhi-Qiang Wang, Xiao-Cheng Huang, Ji-Cheng Wu, and Ye-Xiang Xie. Transition Metal-Catalyzed C(sp3)-H Oxidation,第十七届全国金属有机化学学术讨论会论文摘要集(1),2012,P13,北京.
4.宋仁杰,邓国博,魏文廷,夏家栋,王成勇,李金恒*,铜催化氧化偶联反应合成酰胺类化合物,第十七届全国金属有机化学学术讨论会论文摘要集(2),2012, P4-43,北京.
5.宋仁杰,邓国博,周明波,刘宇,钱鹏程,李金恒*,过渡金属催化C-H氧化串联反应研究,中国化学会第七届有机化学学术会议论文集, 2011,P140,南京,口头报告.
6.宋仁杰,刘 宇,唐伯孝,李金恒*,1,2-联苯磺酰乙烷在有机合成中的应用,第六届有机化学学术会议论文集,2009,P212,西安,口头报告.
(四)专利
(1)宋仁杰,雍馨,李金恒,一种1,1-二芳基烷烃类化合物的制备方法,9.5,发明专利,中国,2018.
(2)宋仁杰,李金恒,欧阳旋慧,一种光氧化还原铁(II)催化下烯烃类化合物的分子间1,2-二烷基反应方法,9.2,发明专利,中国,2018.
(3)李金恒,宋仁杰,胡超,一种萘酮类化合物的制备方法,6.2,发明专利,中国,2018.
讲授课程:有机化学、药物化学等
奖励与荣誉:湖南省自然科学一等奖(排名第2)
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