姓名 曾小军
性别 男
职称 ****
学位 博士
专业 有机化学
电子邮箱 xjzeng@ncu.edu.cn
研究方向 有机（放射性）氟化学、 过渡金属催化、不对称催化
教育工作经历
2015.09-2018.07 东华大学-路易斯维尔大学 博士(导师: 胥波、GB.Hammond 教授)
2010.09-2013.07 浙江师范大学 硕士（导师: 朱向明教授）
2006.09-2010.07 井冈山大学 学士

工作简历
2020.09-至今 南昌大学 ****
2019.04-2020.08 迈阿密大学 博士后 (导师: Wei Liu 教授）
2018.08-2019.03 路易斯维尔大学 博士后 (导师: GB.Hammond 教授)
2014.06-2015.05 南方科技大学 研究助理 (导师: 徐晶教授)
2013.08-2014.03 杭州英特尔外国语中学 教师
科研简介
主要围绕含有氟（放射性氟）切块的高效构建，以及过渡金属催化不对称合成方法学研究。目前已在JACS., Angew. Chem. Int. Ed.等国内外学术期刊发表论文多篇。
课题组网页：https://www.x-mol.com/groups/zeng_xiaojun
科研项目
社会兼职
代表性论文
Zeng, X.+; Yan, W+.; Paeth, M.; Zacate, S. B.; Cai.A, Wang Y.; Yang, D.; Yang, K.; Liu, W*., “Copper-Catalyzed Deaminative Difluoromethylation”. ”Angew. Chem. Int. Ed. 2020，ASAP. (+ contributed equally)
Zeng, X.; Liu,S.; Hao,Y.; Yi,Y.; Hammond, G. B*.; Xu, B*, “Widely Applicable Regio- and Stereoselective Synthesis of 1,2-Dihaloalkenes Using in situ Generated ICl, IBr, BrCl, I2, and Br2” Chem, 2020,6, 1018-1031.
Zeng, X.; Yan, W.; Paeth, M.; Zacate, S. B.; Hong, P.-H.; Wang, Y.; Yang, D.; Yang, K.; Yan, T.; Song, C.; Cao, Z*.; Cheng, M.-J.; Liu, W*., Copper-Catalyzed, Chloroamide-Directed Benzylic C?H Difluoromethylation. J. Am. Chem. Soc. 2019, 141, 19941-19949.
Zeng, X.; Yan, W.; Zacate, S. B.; Chao, T.-H.; Sun, X.; Cao, Z*.; Bradford, K. G. E.; Paeth, M.; Tyndall, S. B.; Yang, K.; Kuo, T.-C.; Cheng, M.-J.; Liu, W*., "Copper Catalyzed Decarboxylative Difluoromethylation". J. Am. Chem. Soc. 2019, 141, 11398-11403.
Zeng, X.; li,J.; Hammond, G. B*.; Xu, B*, “Nucleophilic (Radio)Fluoro-Click Reaction Enabled by Hydrogen Bonding Clusters” Angew. Chem. Int. Ed. 2018, 57, 2924-2928.
Zeng, X.; Liu, S.; Shi, Z.; Liu, G.; Xu, B*. “Synthesis of α-Fluoroketones by Insertion of HF into a Gold Carbene” Angew. Chem. Int. Ed. 2016, 55, 10032-10036.
Zeng, X.; Liu, S.; Hammond, G. B*.; Xu, B*,“Hydrogen Bonding Assisted Br?nsted Acid and Gold Catalysis: Access to both E- and Z-1, 2-Haloalkenes via Hydrochlorination of Haloalkynes” ACS Catal. 2018,8,904-909.
Zeng, X.; B.Chen.; Hammond, G. B*.; Xu, B*, “Homogeneous/Nanoparticle gold catalyzed Hydrothiocyanation of Haloalkynes” Org. Lett., 2019, 21, 2772-2776.
Zeng, X.; Liu, S.; Z.Shi,; Xu, B*, “Hydrogen Bonding Cluster-Enabled Addition of Sulfonic Acids to Haloalkynes: Access to Both (E)- and (Z)-Alkenyl Sulfonates” Org. Lett. 2016, 18, 4770-4773.
Zeng, X.; Lu, Z.; Liu, S.; Hammond, G. B*.; Xu, B*, Metal-free, Regio-, and Stereo-Controlled Hydrochlorination and and Hydrobromination of Ynones and Ynamides” J. Org. Chem. 2017, 83, 13179-13187.
Zeng, X.; Liu, S.; Lu, Z.; Hammond, G. B*.; Xu, B*, “Gold-catalyzed Fluorination of Alkynyl Esters and Ketones: Efficient Access to Fluorinated 1,3-Dicarbonyl Compounds” Adv. Synth. Catal.,2017, 359,4062-4066.
Zeng, X.; Liu, S.; Hammond, G. B*.; Xu, B*, “Divergent Regio- and Stereoselective Gold-catalyzed Synthesis of α-Fluorosulfones and β-Fluorovinylsulfones from Alkynylsulfones” Chem. Eur. J. 2017, 23, 11977-11981.
Zeng, X.; Liu, S.; Xu, B*,“Stable Yet Reactive Cationic Gold Catalysts With Carbon Based Counterions” RSC Adv. 2016, 6, 77830-77833.
Zeng, X.; Smith, R.; Zhu, X*, “Synthesis of Thioglycoside Analogues of Maradolipid” J. Org. Chem. 2013, 78, 4165-4170.
S.Liu, ; X. Zeng*.; B. Xu*.“ Regio- and Stereoselective Halothiolation of Alkynes using Lithium Halides and N-thiosuccinimides” Org. Chem. Front. 2020, 7, 1690-1695.
S.Liu, ; X. Zeng*.; B. Xu*.“ Practical Fluorothiolation and Difluorothiolation of Alkenes using Pyridine-HF and N-thiosuccinimides” Org. Chem. Front. 2020,7,119-125.
S.Liu.; Chen, B.; Yang, Y.; Yang, Y.; Chen, Q.; X. Zeng*.; B. Xu*, “Electrochemical oxidations of thioethers: Modulation of oxidation potential using a hydrogen bonding network”. Electrochem. Commun. 2019, 109, 106583.
L.Lin,; X. Zeng*.; B. Xu*.“Synthesis of Z?Enamides through Heterogeneous Gold-Catalyzed Stereoselective Hydrogenation of Ynamides” J. Org. Chem. 2019, 83, 13179-13187.
B. Chen.; Y. Yang.; Y. Yang.; S. Liu.; Q. Chen.; X. Zeng*.; B. Xu*. “Effects of the Hydrogen Bonding Network on Electrophilic Activation and Electrode Passivation: Electrochemical Chlorination and Bromination of Aromatics” ChemElectroChem.,
2019, 6, 3726-3730.
S. Liu.; X. Zeng*.; B. Xu*.“Hydrogen bonding Assisted Regioselective sulfenylation and Trifluoromethylthiolation of Electron-Rich (Het) arenes” Asian J. Org. Chem., 2019, 8, 1372-1375.
X. Xia.; B. Chen.; X. Zeng*.; B. Xu*. “Synthesis of α‐Trifluromethylthiolated and α‐Thiocyanated Ketones Using Umpoled Enolates” Adv. Synth. Catal.2018, 360, 4429-4437.
X. Xia.; B. Chen.; X. Zeng*, B. Xu*. “Synthesis of α-Amino Ketones through Aminations of Umpoled Enolates” Org. Biomol. Chem. 2018,16,6918-6922.
B. Chen.; X. Xia.; X. Zeng*, B. Xu*. “Hydrogen Bonding Network Assisted Regio- and Stereo- Controlled Hydrohalogenation of Sulfonyl Alkynes” Tetrahedron Lett. 2018, 59,3950-3954.