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江西师范大学化学化工学院导师教师师资介绍简介-陈军民(副教授)

本站小编 Free考研考试/2021-05-04





个人简介:
陈军民,男,1975年10月出生,博士,副教授,硕士生导师。2009年毕业于中国科学院成都有机所,获理学博士学位。目前主要的研究方向是有机合成方法学和重要医药及其中间体的新工艺研究。现主持国家自然基金项目一项、江西省自然基金项目一项、江西省教育厅基金项目一项,并作为主要成员参与江西省教育厅重点项目的研究工作一项。在J. Am. Chem. Soc., Adv. Synth. Catal.,等国际主要SCI学术刊物上发表论文30余篇。

要研究方向:

金属有机化学;有机合成;不对称合成;创新医药合成工艺技术。
承担的科研项目情况:

1. 基于钯催化碳氢键活化反应合成磺胺类药物活性单元的研究 (国家自然基金批准号:**,在研 )
2. 钯催化碳氢键活化在磺酰胺类药物合成中的应用研究(主持在研)。
3. 失配的Lewis对: 非金属不对称催化氢化的新策略(主持在研)。
4. 江西师范大学教育部功能有机小分子重点实验室开发基金(主持在研)。
5. PEG介质中铜催化偶联反应构筑碳-杂键及其在杂环天然产物中的应用(基金批准号:GJJ13246),2013-2015(已结题)。
6. 液态聚乙二醇为绿色反应介质在有机合成反应中的应用研究(博士启动基金),2009-2012(已结题)。
7. 手性亚砜诱导氮邻位sp3 C–H不对称金属化及生物碱的合成研究,江西省自然基金项目(基金批准号:2010GQH0064),2011-2013(已结题)。
8. 手性叔丁基亚砜在不对称金属铟作用下Barbier(-type)反应中的应用研究,江西省教育厅项目(基金批准号:GJJ11066),2011-2013(已结题)。
其它应用合作项目。

近三年主要发表的学术成果:

[15] 异丙基-β-D硫代半乳糖苷的合成方法,专利(2017),授权号:CNB;
[14] 2 ,2'-联氮-二(3-乙基-苯并噻唑-6-磺酸)二铵盐的合成方法, 专利(2018),授权号:CNA;
[13] Metal-free sequential dual oxidative amination of C(sp3)–H bonds: A direct approach to benzothiadiazine 1,1-dioxide derivatives, Dongyin Wang, Xiaokang Li, Yongli Zhao, Junmin Chen*, Synthetic Communications, 2017,47, 351-356.
[12] Palladium-Catalyzed Mono-Selective ortho C-H Arylation of Aryl Sulfonamides in Water: A Concise Access to Biaryl Sulfoamide Derivatives Mono-Selective orthoC-H Arylation of Aryl Sulfonamides in Water: A Concise Access to Biaryl Sulfoamide Derivatives,Wei Liu, Dongyin Wang, Yongli Zhao, Fei Yi,a and Junmin Chen* Advanced Synthesis & Catalysis. 2016, 358, 1968-1974.,
[11] Palladium-catalyzed direct C–H arylation of 3-aryl-2H-benzo[1,2,4]thiadiazine 1,1-dioxides: an efficient strategy to the synthesis of benzothiadiazine-1,1-dioxide derivatives,Dongyin Wang,Wei Liu,Fei Yi,Yongli Zhao,Junmin Chen* Organic & Biomolecular Chemistry, 2016, 14,1921-1924.
[10] Palladium(II)/copper(I)-catalyzed sequential CeH arylation and oxidative C-N bond cleavage of aryl sulfonamino acids: Efficient one pot synthesis of primary biaryl sulfonamides, Wei Liu, Yongli Zhao, Fei Yi, Junmin Chen*, Tetrahedron, 2016, 72, 8382-8386.
[9] Cu(II)-catalyzed decarboxylation/elimination of N-arylsulfonyl amino acids to primary aryl sulfonamides, Liandi Zhou, Xiaokang Li, Wei Liu, Yongli Zhao & Junmin Chen*, Synthetic Communications, 2016, 46, 1299-1306.
[8] Cu(Ⅱ)-promoted oxidative C-N bond cleavage of N-benzoylamino acids to primary aryl amides, Liandi Zhou, Wei Liu,Yongli Zhao, and Junmin Chen* ARKIVOC 2016 (v) 497-506.
[7] Copper-catalyzed cyanation of aryl halides with sodium nitroprusside in polyethyleneglycol 400 (PEG-400) Minhu Jiang, Tangjun Yuan, Fei Yi, and Junmin Chen*ARKIVOC 2016 (v) 13-21.
[6] Tosylhydrazine mediated conjugate reduction and sequential reductive coupling cyclization: synthesis of 2-arylchromans Xuyang Shang a,b, Xiaomeng Zhou a,b,Wei Zhang a,b, ChangfengWan a, Junmin Chen*, Tetrahedron, 2015, 71, 8187-8193.
[4] Palladium-catalyzed ortho-arylation of benzoic acid derivatives via C–H bond activation using an aminoacetic acid bidentate directing group, Xiaomeng Zhou, Qing Wang, Weihua Zhao, Songsong Xu, Wei Zhang, Junmin Chen *, Tetrahedron Letters, 2015, 56, 851–855.
[3] Novel copper/PEG-400 catalyst systems for chemoselective S- and N-arylation of 2-mercaptobenzothiazole, Xiaokang Li, Tangjun Yuan, Yu Yang, Junmin Chen *, Tetrahedron, 2014, 70, 9652-9660.
[2] HIGHLY EFFICIENT AND PRACTICAL METHOD FOR SYNTHESIS OF 2,2’-AZINO-BIS(3-ETHYLBENZOTHIAZOLINE- 6-SULFONIC ACID) (ABTS)AND ITS DIAMMONIUM SALT, Junmin Chen*, Xiaomeng Zhou, and Tangjun Yuan, Synthetic Communications, 2014,44, 3630–3636.
[1] A novel transition metal-free conjugate reduction of a,b-unsaturated ketones with tosylhydrazine as a hydrogen source, Xiaomeng Zhou, Xiaokang Li, Wei Zhang, Junmin Chen*,Tetrahedron Letters, 2014, 55, 5137–5140.

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