教 师 基 本 情 况

姓 名： 张勇
性 别： 男
职 称： 副教授
学 位： 博士
专 业： 有机化学
E-mail： yong_zhanggnnu@126.com
研究方向： 有机催化及有机多孔材料

教 育 经 历
2003-2007，赣南师范学院应用化学专业，获学士学位；
2007-2012，兰州大学功能有机分子化学国家重点实验室有机化学专业，获博士学位；
2014-2016，在清华大学从事博士后研究工作，主要从事纳米催化反应研究。
工 作 经 历现为赣南师范大学副教授，硕士生导师。
课 程 教 学

目前承担有机化学、有机化学实验和合成化学等本科生以及研究生课程的教学。

教 研 及 科 研 项 目
1. 新型手性有机分子笼的设计、合成及催化应用研究，国家自然科学基金青年基金项目（21502021），主持。
2. 基于分子笼骨架有机多孔材料的制备及其应用研究，国家自然科学基金地区基金项目（21865003），主持。
2. 有机催化不饱和?-丁内酰胺的不对称合成研究, 省教育厅青年科学基金项目（GJJ 13655），主持。
3. 基于丁内酰胺骨架手性（螺环）季碳的构筑研究，江西省青年科学基金(20144BAB2130003)，主持。
主 要 成 果

[1] Zhang, Y.*; Luo, L.#; Ge, J.; Yan S.-Q.; Peng, Y.-X.; Liu, Y.-R.; Liu, J.-X.; Liu, C.*; Ma,
T.*; Luo, H.-Q. “On Water” Direct Organocatalytic Cyanoarylmethylation of Isatins for the
Diastereoselective Synthesis of 3- Hydroxy-3-cyanomethyl Oxindoles, J. Org. Chem., 2019, 84,
4000-4008.
[2] Zhang, Y.#; Xiong, Y.#; Ge, J.; Lin, R.; Chen, C.; Peng, Q.; Wang, D.-S.*;
Li, Y.-D. Porous organic cage stabilised palladiumnanoparticles: efficient heterogeneous
catalysts for carbonylation reaction of aryl halides,

Chem. Commun., 2018, 54, 2796-2799.

[3] Han, M.-Y.*; Lin, J.; Li, W.; Luan, W.-Y.; Mai, P.-L.; Zhang, Y. Catalyst-free nucleophilic
addition reactions of silyl glyoxylates in water, Green Chem., 2018, 20, 1228-1232.
[4] Zhang, Y.*; Wang, Y.-P.; Ge, J.; Lai, G.-W.; Lu, D.-L.; Liu, J.-X.; Li, X.* ‘Base-catalyzed
cascade 1,6-sulfur- Michael/Henry reaction of trifluoromethyl-substituted styrylisoxazoles:
Diastereoselective synthesis of tetrahydrothiophenes with a trifluoromethylated quaternary
center, Tetrahedron Lett., 2018, 59, 941-944.
[5] Zhang, Y.*; Wei, B.-W.; Wang, W.-X.; Deng, L.-L.; Nie, L.-J.; Luo, H.-Q.; Fan,
X.-L. Direct vinylogous oxidative cross-dehydrogenative coupling of 4-nitroisoxazoles with
N-aryltetrahydroisoquinolines in water under air conditions, RSC Adv., 2017, 7, 1229-1232.
[6] Zhang, Y.*; Wei, B.-W.; Zou, L.-N.; Kang, M.-L.; Luo, H.-Q.; Fan, X.-L.* ‘On water’ direct
vinylogous Henry (nitroaldol) reactions of 3,5-dimethyl-4-nitroisoxazole with
aldehydes and trifluoromethyl ketones, Tetrahedron 2016, 72, 2472-2475.
[7] Zhang, Y.*; Wei, B.-W.; Lin, H.; Cui, W.-R.; Zeng, X.-Q.; Fan, X.-L.*
Organocatalyzed Asymmetric Vinylogous Michael Reactions of 3,5-Dialkyl-Substituted
4-Nitroisoxazoles: A Direct Method for the Synthesis of Chiral Isoxazole Derivatives, Adv. Synth.
Catal., 2015, 357, 1299-1304.
[8] Zhang, Y.*; Wei, B.-W.; Lin, H.; Zhang, L.; Liu, J.-X.; Luo, H.-Q.; Fan, X.-L.* “On water”
direct catalytic vinylogous Henry (nitroaldol) reactions of isatins for the efficient
synthesis of isoxazole substituted 3- hydroxyindolin-2-ones, Green Chem., 2015, 17, 3266-3270.
[9] Zhang, Y.; Shao, Y.-L.; Xu, H.-S.; Wang, W.* Organocatalytic Direct Asymmetric
Vinylogous Michael Reaction of an α?-Unsaturated ?-Butyrolactam with Enone, J. Org. Chem., 2011,
76, 1472-1474.
[10] Zhang, Y.; Li, Z.-J.; Xu, H.-S.; Zhang, Y.; Wang, W.* Organocatalytic asymmetric Henry
reaction of isatins: Highly enantioselective synthesis of 3-hydroxy-2-oxindoles, RSC. Adv., 2011,
1, 389-392.
[11] Zhang, Y.; Wang, W.* Recent Advances in Organocatalytic asymmetric Michael
Reactions, Catal. Sci. Technol., 2012, 2, 42-53.
[12] Zhu, N.; Ma, B.-C.; Zhang, Y.; Wang, W.* Organocatalyzed Highly Enantioselective
and anti-Selective Construction of ?-Butenolides through Vinylogous Mukaiyama Aldol Reaction, Adv.
Synth. Catal., 2010, 352, 1291-1295.
[13] Zhu, J.-L.; Zhang, Y.; Liu, C.; Zheng, A.-M.; Wang, W.* Insights into the Dual
Activation Mechanism Involving Bifunctional Cinchona Alkaloid Thiourea Organocatalysts: An NMR
and DFT Study, J. Org. Chem., 2012, 77, 9813-9825.
[14] Zhang, Y.; Zhang, Y.; Sun, Y.-L.; Du, X.; Shi, J.-Y.; Wang, W.-D.; Wang, W.*
4-N,N-Dimethyl-aminopyridine- Embedded Nanoporous Conjugated Polymer as Highly Active Heterogeneous
Organocatalyst, Chem. Eur. J.,

2012, 18, 6328-6334.

[15] Han, M.-Y.; Zhang, Y.; Wang, H.-Z.; An, W.-K.; Ma, B.-C.; Zhang, Y.; Wang, W.*
Organocatalytic Michael Addition of Nitro Esters to a,b-Unsaturated Aldehydes: Towards the
Enantioselective Synthesis of trans-3- Substituted Proline Derivatives, Adv. Synth. Catal.,
2012, 354, 2635-2640.
[16] Zhang, Y.; Wang, W., C–C Bond Formation by Michael Reaction, Stereoselective
Organocatalysis: Bond Formation Methodologies and Activation Modes, Rios, R. Ed., John
Wiley & Sons, Inc., 2013, Chapter 5, p147-204 .