姓名

武杰

性别

男

出生年月

1978年7月

职称

教授

民族

回

籍 贯

河南

电子邮箱

wujie@zzu.edu.cn

最终学位

博士

学术头衔/兼职

河南省青年骨干教授

河南省教育厅学术技术带头人

郑州大学化学学院教授委员会委员

研究方向

金属有机骨架材料（MOFs）在小分子催化方面的应用

主要学习、科研和工作经历

2017年-2018年 Northwestern University (hupp and farha group) 访问学者

2016年5月-至今 郑州大学化学学院 教授

2010年5月-2016年4月 郑州大学化学学院 副教授

2007年9月-2010年4月 郑州大学化学学院 讲师

代表性

教学成果与荣誉

近五年来，承担化学专业本科生《 无机化学原理》、《元素无机化学》、《无机化学实验》课程的教学任务，工作量饱满。主持承担河南省一流本科课程建设项目一项、河南省精品在线开放课程建设项目一项、河南省教育厅教师教育课程改革研究项目一项、郑州大学线下精品在线开放课程建设项目一项、郑州大学 “MOOC”课程建设项目一项、国家级大学生创新创业项目一项。带领学生获得全国大学生化学实验竞赛二等奖一项。被评为河南省高等学校省级青年骨干教师、校级青年骨干教师、郑州大学三育人先进个人、郑州大学优秀共产党员等荣誉称号。

代表性

科研成果

一、 科研项目

（1） 国家自然科学基金面上项目，基于非贵金属配合物可逆结构转化诱导的氨气和小分子胺N-H键裂解及其在催化胺化反应中的应用（**），主持。

（2） 一类新药FNC技术02，横向，100万，主持

（3） 国家自然科学基金青年基金项目，基于D-A-D-A型不对称共轭四联氮杂环配体构筑的配体介导型金属有机骨架材料的研究(**)，国家自然科学基金青年基金，主持

（4） 河南省自然科学基金面上项目，基于可控可逆氧化还原转化的新型晶态多孔金属—有机框架催化材料的研究（**0243），主持

（5） 抗肿瘤胞苷类似物修饰的新型铂(II)药物分子的合成、表征及生物活性研究，国家博士后基金特别资助(**1)，主持

（6） 核苷类化合物金属药物分子修饰的研究，国家博士后基金一等资助(**095)，主持

二、 论文论著

主要研究方向：

1. 光催化MOFs材料的制备及催化性能研究

金属有机骨架材料作为一种新型多微孔晶态材料，凭借其独特的多孔性、可修饰性以及超高的比表面积，在催化领域获得了广泛的应用，有效结合了均相催化剂和非均相催化剂两者的优势，补充了传统微孔材料和介孔材料之间孔的尺寸的空白。

课题组设计合成新型的MOFs可见光催化剂；通过SIM法、半导体复合等方法进一步调节催化剂带隙结构，提高可见光催化效率；研究MOFs可见光催化剂在光催化水裂解，CO2还原，氮气还原等热门研究领域的应用。

近年来，在“Coord. Chem. Rev.”、、“Chem. Commun.”、“ Chem. Eur. J”、“Inorg. Chem.”等上面发表SCI论文50余篇发。

代表性论文：

(1) Metal-Organic Framework (MOF)-Based Materials as Heterogeneous Catalysts for C-H Bond Activation. Chem-Eur J 2019, 25 (12), 2935-2948。

(2) Co(II)-cluster-based metal-organic frameworks as efficient heterogeneous catalysts for selective oxidation of arylalkanes. Crystengcomm 2019, 21 (10), 1666-1673.

(3) Cu(I)-Based Metal-Organic Frameworks as Efficient and Recyclable Heterogeneous Catalysts for Aqueous-Medium C-H Oxidation. Cryst Growth Des 2019, 19 (2), 976-982.

(4) A Highly Sensitive and Recyclable Ln-MOF Luminescent Sensor for the Efficient Detection of Fe3+ and Cr-VI Anions. Chem-Asian J 2019, 14 (20), 3721-3727.

(5) Design, synthesis, and biological evaluation of novel 2 '-deoxy-2 '-fluoro-2 '-C-methyl 8-azanebularine derivatives as potent anti-HBV agents. Bioorg Med Chem Lett 2019, 29 (11), 1291-1297.

(6) Co-Cluster-Based Metal–Organic Frameworks as Selective Catalysts for Benzene Tandem Acylation–Nazarov Cyclization to Benzocyclopentanone, Chem. Eur. J., 2018, 24, 1416-1424. (corresponding author).

(7) Design, synthesis, and biological evaluation of new 1,2,3-triazolo-20-deoxy-20-fluoro- 40-azido nucleoside derivatives as potent anti-HBV agents, Eur. J. Med. Chem. 2018, 143, 137-149.

(8) Efficient Catalytic Performance for Acylation-Nazarov Cyclization Based on an Unusual Postsynthetic Oxidization Strategy in a Fe(II)-MOF, Inorg. Chem. 2018, 57, 10224-1031. (corresponding author).

(9) Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C−H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect, Inorg. Chem. 2017, 56, 13329-13336. (corresponding author).

(10)Solvent-Induced Assembly of Sliver Coordination Polymers (CPs) as Cooperative Catalysts for Synthesizing of Cyclopentenone[b]pyrroles Frameworks, Inorg. Chem. 2017, 56, 4874-4884. (corresponding author).

(11)The first example of palladium-catalyzed cascade amidine arylation–intramolecular ester amidationfor the synthesis of hypoxanthines: application to the synthesis of 8-azanebularine analogues, Org. Biomol. Chem. 2017, 15, 379-386.

(12)Crystalline central-metal transformation in metal–organic frameworks, Coor. Chem. Rev. 2016, 307, 130-146. (corresponding author).

(13)Surfactant-Assisted Nanocrystalline Zinc Coordination Polymers: Controlled Particle Sizes and Synergistic Effects in Catalysis. Chem. Eur. J., 2016, 22, 6389-6396. (corresponding author).

(14)A Hofmann Rearrangement–Ring Expansion Cascade for the Synthesis of 1-Pyrrolines: Application to the Synthesis of 2,3-Dihydro-1H-pyrrolo[2,1-a]isoquinolinium Salts, Adv. Synth. Catal. 2016, 358, 1130–1135 (corresponding author).

(15)Microcrystalline Zinc Coordination Polymers as Single-site Heterogeneous Catalysts for the Selective Synthesis of Mono-oxazolines from Amino Alcohol and Dinitriles, Chem. Asian J. 2016, 11, 1856-1862. (corresponding author).

(16)Synthesis of pyrrol-pyridazyl-triazolyl-pyridines via Cu(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition reaction, Syn. Comm.2016, 46, 1118-1123.(corresponding author).

(17)Reversible conversion of valence-tautomeric copper metal–organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C–H bonds activation reaction, Chem. Comm. 2015, 51, 10353-10356. (corresponding author).

(18)Solvent Templates Induced Porous MetalOrganic Materials: Conformational Isomerism and Catalytic Activity, Inorg. Chem. 2015, 54, 1405-1413. (corresponding author).

(19)Copper(II) Coordination Polymers: Tunable Structures and Different Activation Effect of Hydrogen Peroxide for the Degradation of Methyl Orange under Visible Light Irradiation, Dalton, 2015, 44, 1406-1411 (corresponding author).

(20)Selective synthesis of 2,5-disubstituted furan-3-carboxylates and the isomeric 2,4-disubstituted furan-3-carboxylates RSC Adv., 2015, 5, 79906-79914.

(21)Template Induced Diverse Metal-organic Materials as Catalysts for Tandem Acylation-Nazarov Cyclization, Chem. Eur. J. 2014, 20, 16156-16163 (Hot Paper, corresponding author)

(22)Structural Variability, Topological Analysis and Photocatalytic Properties of Neoteric Cd(II) Coordination Polymers Based on Semirigid Bis(Thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers, Dalton, 2014, 43, 12790-12799. (corresponding author) .

(23) Metal–organic frameworks based on the [1,1':3',1'-terphenyl]-3,3'',5,5''-tetracarboxylic acid ligand: syntheses, structures and magnetic properties, Dalton, 2014, 43, 15475-15481. (corresponding author).

(24) Mn(II) Coordination Polymers Assembled from 8 or 9-Connected Trinuclear Secondary Building Units: Topology Analysis and Research of Magnetic Properties, CrystEngComm, 2014, 16, 8736-8746. (corresponding author).

(25)Seven Dicarboxylate-Based Coordination Polymers with Structural Varieties and Solvent Resistance Property Changing Derived from the Introduction of Small Organic Linkers, CrystEngComm, 2014, 16, 2615-2625. (corresponding author).

(26)Design, synthesis, and biological evaluation of new 2'-deoxy-2'-fluoro-4'-triazole cytidine nucleosides as potent antiviral agents. Eur. J. Med. Chem. 2013, 63, 739-745.

(27) Solvent-Mediated Central Metals Transformation from a Tetranuclear NiII Cage to a Decanuclear CuII “Pocket”, Crystal Growth & Design, 2010, 10, 3835-3836. (corresponding author).

(28) Construction of two discrete molecular high-nuclear copper(II) complexes as heterogeneous catalysts for oxidative coupling polymerization of 2, 6-dimethylphenol, Eur. J. Inorg. Chem., 2009, 2796-2803.

(29)3D Coordination Framework with Uncommon two-fold Interpenetrated {3³·5⁹·6³}-lcy Net and Coordinated Anion Exchange, Chem. Eur. J., 2009, 15, 4049-4056.

(30) Highly Selective Ferric Ion Sorption and Exchange by Crystalline Metal Phosphonates Constructed from Tetraphosphonic Acids, Inorg. Chem., 2007, 46, 7960-7970.

(31) Studies on Cage-Type Tetranuclear Metal Clusters with Ferrocenylphosphonate Ligands, Chem. Eur. J., 2006, 12, 5823-5831.