陈利娟
学历：博士
职称：副教授，博士生导师
职务：
邮箱：ljchen@henu.edu.cn
学历及学术经历：
1998.9-2002.7 河南大学化学化工学院 化学 本科
2002.9-2005.7 河南大学特种功能材料重点实验室 高分化学与物理 硕士
2005.9-2009.1 中国科学院兰州化学物理研究所 物理化学 博士
2008.7-2013.10 河南大学基础实验教学中心 讲师
2013.10-至今 河南大学化学化工学院 副教授
2010.7-2018.12 河南大学化学化工学院 硕士生导师
2018.12-至今 河南大学化学化工学院 博士生导师
研究领域：
(1) 具有孤对电子空间效应的杂原子多钨氧酸盐过渡-稀土异金属磁性材料的设计合成和电化学、荧光及药物活性研究
(2) 杂多钼氧酸盐3d-4f异金属衍生材料的设计合成及其对有机染料光降解性能研究
在Inorg. Chem., J. Mater. Chem. C, Cryst. Growth Des., Dalton Trans., Chem. Asian J., CrystEngComm等国外知名杂志上发表学术论文50余篇。
主要成果：
论文
1. Yamin Li, Hailou Li, Jun Jiang, Lijuan Chen,* Junwei Zhao,* Three types of distinguishing L-alanine-decorated and rare-earth-incorporated arsenotungstate hybrids prepared in a facile one-step assembly strategy, Inorg. Chem. 2019, 58, 3479–3491.
2. Huijie Li, Peijun Gong, Jun Jiang, Yamin Li, Jingjing Pang, Lijuan Chen,* Junwei Zhao,* Organic–inorganic hybrids assembled from plenary Keggin-type germanotungstate units and 3d–4f heterometal clusters, Dalton Trans. 2019, 48, 3730–3742.
3. Jing-Lin Liu, Meng-Tian Jin, Li-Juan Chen,* Jun-Wei Zhao*, First dimethyltin- functionalized rare-earth incorporated tellurotungstates consisting of {B-α-TeW₇O₂₈} and {W₅O₁₈} mixed building units, Inorg. Chem. 2018, 57, 12509–12520.
4. Yanhong Chen, Longhui Sun, Shenzhen Chang, Lijuan Chen,* Junwei Zhao*, Synergistic Effect between Different Coordination Geometries of Lanthanides and Various Coordination Modes of 2?Picolinic Acid Ligands Tuning Three Types of Rare 3d?4f Heterometallic Tungstoantimonates, Inorg. Chem. 2018, 57, 15079?15092.
5. Qing Han, Jian-Cai Liu, Yue Wen, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Tellurotungstate-based organotin?rare-earth heterometallic hybrids with four organic components, Inorg. Chem. 2017, 56, 7257–7269.
6. Qing Han, Yue Wen, Jian-Cai Liu, Wu Zhang, Li-Juan Chen,* Jun-Wei Zhao,* Rare-Earth-Incorporated Tellurotungstate Hybrids Functionalized by 2-Picolinic Acid Ligands: Syntheses, Structures, and Properties, Inorg. Chem. 2017, 56, 13228?13240.
7. Hailou Li, Yajie Liu, Rui Zheng, Lijuan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Trigonal pyramidal {AsO₂(OH)} bridging tetra-nuclear rare-earth encapsulated polyoxotungstate aggregates, Inorg. Chem. 2016, 55, 3881?3893.
8. Jiancai Liu, Jie Luo, Qing Han, Jing Cao, Lijuan Chen,* You Song,* Junwei Zhao,* Coexistence of long-range ferromagnetic ordering and spin-glass behavior observed in the first inorganic–organic hybrid 1-D oxalate-bridging nona-Mn^II sandwiched tungstoantimonate chain, J. Mater. Chem. C, 2017, 5, 2043–2055.
9. Hai-Lou Li, Ya-Jie Liu, Ya-Min Li, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Unprecedented Selenium and Lanthanide Simultaneously Bridging Selenotungstate Aggregates Stabilized by Four Tetra-vacant Dawson-like {Se₂W₁₄} Units, Chem. Asian J. 2018, 13, 2897–2907.
10. Pei-Jun Gong, Jing-Jing Pang, Hui-Fen Hu, Hui-Jie Li, Li-Juan Chen,* Jun-Wei Zhao*, Ligand-Controlled Assembly of Heteropolyoxomolybdates Constructed from Plenary Keggin Germanomolybdates and Cu-Ln Heterometallic Units, Chem. Asian J. 2018, 13, 3762–3775.
11. Ya-Jie Liu, Meng-Tian Jin, Li-Juan Chen*, Jun-Wei Zhao*, Recent advances in isopolyoxotungstates and their derivatives, Acta Cryst. 2018, C74, 1202–1221.
12. Xing Ma, Hailou Li, Lijuan Chen*, Junwei Zhao*, The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties, Dalton Trans. 2016, 45, 4935–4960.
13. Jiancai Liu, Jing Yu, Qing Han, Yue Wen, Lijuan Chen,* Junwei Zhao,* First quadruple-glycine bridging mono-lanthanide-substituted borotungstate hybrids, Dalton Trans. 2016, 45, 16471–16484.
14. Lijuan Chen, Fang Zhang, Xing Ma, Jie Luo, Junwei Zhao*, Two types of novel tetra-iron substituted sandwich-type arsenotungastates with supporting lanthanide pendants, Dalton Trans. 2015, 44, 12598–12612.
15. Yajie Liu, Hailou Li, Changtong Lu, Peijun Gong, Xiaoyun Ma, Lijuan Chen,* Junwei Zhao*, Organocounterions-assisted and pH-controlled self-assembly of five nanoscale high-nuclear lanthanide substituted heteropolytungstates, Cryst. Growth Des. 2017, 17, 3917?3928.
16. Xiuhua Wang, Yajie Liu, Mengtian Jin, Yuxing Wu, Lijuan Chen,* Jun-Wei Zhao*, Two families of rare-earth-substituted Dawson-type monomeric and dimeric phosphotungstates functionalized by carboxylic ligands, Cryst. Growth Des. 2017, 17, 5295–530.
17. Hailou Li, Wen Yang, Xiuhua Wang, Jianru Ma, Lijuan Chen,* Junwei Zhao*, Self-assembly of a family of isopolytungstates induced by the synergistic action of lanthanoids and pH variation in the process of reaction: syntheses, structures and properties, Cryst. Growth Des. 2016, 16, 108–120.
18. Jun-Wei Zhao,* Jing-Li Zhang, Yan-Zhou Li, Jing Cao, Li-Juan Chen*, Novel one- dimensional organic?inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper?aminoacid complexes, Cryst. Growth Des. 2014, 14, 1467?1475.
19. Junwei Zhao,* Jing Cao, Yanzhou Li, Jing Zhang, Lijuan Chen,* First tungstoantimonate -based transition-metal–lanthanide heterometallic hybrids functionalized by aminoacid ligands, Cryst. Growth Des. 2014, 14, 6217-6229.
20. Junwei Zhao,* Hailou Li, Yanzhou Li, Chunyang Li, Zhenling Wang, Lijuan Chen,* Rectangle versus square oxalate-connective tetra-lanthanide cluster anchored in lacunary Lindqvist isopolytungstates: syntheses, structures and properties, Cryst. Growth Des. 2014, 14, 5495?5505.
21. Yingjie Liu, Jing Cao, Yujie Wang, Yanzhou Li, Junwei Zhao,* Lijuan Chen,* Pengtao Ma, Jingyang Niu, Hydrothermal synthesis and structural characterization of an organic–inorganic hybrid sandwich-type tungstoantimonate [Cu(en)₂(H₂O)]₄[Cu(en)₂(H₂O)₂] [Cu₂Na₄(α-SbW₉ O₃₃)₂]·6H₂O, J. Solid State Chem. 2014, 209, 113–119.
22. Junwei Zhao,* Dongying Shi, Lijuan Chen,* Pengtao Ma, Jingping Wang, Jian Zhang,* Jingyang Niu,* Tetrahedral polyoxometalate nanoclusters with tetrameric rare-earth cores and germanotungstate vertexes, Cryst. Growth Des. 2013, 13, 4368?4377.
23. Junwei Zhao,* Dongying Shi, Lijuan Chen,* Yanzhou Li, Pengtao Ma, Jingping Wang, Jingyang Niu,* Novel polyoxometalate hybrids consisting of copper–lanthanide heterometallic/lanthanide germanotungstate fragments, Dalton Trans. 2012, 41, 10740–10751.
24. Junwei Zhao,* Dongying Shi, Lijuan Chen,* Xiaomeng Cai, Zhiqiao Wang, Pengtao Ma, Jingping Wang, Jingyang Niu,* Two organic–inorganic hybrid 1-D and 3-D polyoxotungstates constructed from hexa-Cu^II substituted sandwich-type arsenotungstate units, CrystEngComm 2012, 14, 2797–2806.
25. Lijuan Chen, Dongying Shi, Junwei Zhao,* Yulong Wang, Pengtao Ma, Jingping Wang, Jingyang Niu,* Three transition-metal substituted polyoxotungstates containing Keggin fragments: from trimer, one-dimensional chain to two-dimensional sheet, Cryst. Growth Des. 2011, 11, 1913–1923.
26. Jingli Zhang, Jie Li, Lijie Li, Haozhe Zhao, Pengtao Ma, Junwei Zhao,* Lijuan Chen,* Syntheses, structures, spectroscopic and electrochemical properties of two 1D organic– inorganic Cu^II–Ln^III heterometallic germanotungstates, Spectrochim Acta A 2013, 114, 360–367.
27. Yuye Li, Shuanbao Tian, Yanzhou Li, Junwei Zhao,* Pengtao Ma, Lijuan Chen,* Two 2D Cu–Ln heterometallic polyoxometalate aggregates constructed from bis(undecatungstophosphate) lanthanate units and copper-complex bridges, Inorg. Chim. Acta, 2013, 405, 105–110.
28. Shuanbao Tian, Yanzhou Li, Junwei Zhao,* Pengtao Ma, Lijuan Chen,* A novel organic –inorganic hybrid sandwich-type germanotungstate with discrete [Fe₄(en)₂(α-GeW₉O₃₄)₂]^8? polyoxoanions and 1-D [Fe₄(en)(α-GeW₉O₃₄)₂]_n^8n? polymeric chains, Inorg. Chem. Commun. 2013, 33, 99–104.
29. Dongying Shi, Suzhi Li, Junwei Zhao,* Weijia Niu, Sensen Shang, Yanzhou Li, Pengtao Ma, Lijuan Chen,* Synthesis, structure and properties of a metal–organic complex built up from ferrous sulfate chains and 2,2'-bipyridyl-5,5'-dicarboxylic acid ligands, Inorg. Chem. Commun. 2012, 20, 277–281.
30. Yun Liu, Qiang Wang, Lijuan Chen,* Haozhe Zhao, Junwei Zhao,* A novel organic –inorganic hybrid 3D framework based on neodymium oxalate–selenites [Nd₂(SeO₃)₂(C₂O₄)(H₂O)₂]·2H₂O, Synth. Met. 2012, 162, 1648–1653.
31. Junwei Zhao,* Yamin Cheng, Sensen Shang, Fang Zhang, Li Chen, Lijuan Chen,* Syntheses, structures and properties of three new two-dimensional Cu^I–Ln^III heterometallic coordination polymers based on 2,2’-dipyridyl-5,5’-dicarboxylate ligands, Spectrochim Acta A 2013, 116, 348–354.
32. Dongying Shi, Sensen Shang, LijuanChen,* Xiaomeng Cai, Xiaoying Wang, Junwei Zhao,* Three novel 2D organic–inorganic hybrid Cu^II–Ln^III heterometallic arsenotungstates, Synth. Met. 2012, 162, 1030–1036.
33. Jie Luo, Chunli Leng, Lijuan Chen,* Jing Yuan, Huiying Li, Junwei Zhao,* Three 3D organic –inorganic hybrid heterometallic polyoxotungstates assembled from 1:2-type [Ln(α- SiW₁₁O₃₉)₂]^13? silicotungstates and [Cu(dap)₂]²⁺ linkers, Synth. Met. 2012, 162, 1558–1565.
34. Huijie Li, Jingjing Pang, Lijuan Chen,* Junwei Zhao,* A 1-D chain transition-metal substituted germanomolybdate constructed from di-Cu^II-substituted sandwich-type heteropolyoxomolybdate units linked by doubly di-Na^I-cluster bridges, Inorg. Chem. Commun. 2019, 99, 119–125.
35. Lijuan Chen, Dongying Shi, Junwei Zhao,* Yulong Wang, Pengtao Ma, Jingyang Niu,* Synthesis, structure and magnetism of a 2-D organic–inorganic hybrid tetra-Co^II-substituted sandwich- type Keggin germanotungstate: {[Co(dap)₂(H₂O)]₂[Co(dap)₂]₂[Co₄(Hdap)₂(B-α- HGeW₉O₃₄)₂]}·7H₂O, Inorg. Chem. Commun. 2011, 14, 1052–1056.
36. Lijuan Chen, Junwei Zhao,* Pengtao Ma, Qiuxia Han, Jingping Wang, Jingyang Niu,* An organic–inorganic hybrid nickel-substituted arsenotungstate consisting of three types of polyoxotungstate units, Inorg. Chem. Commun. 2010, 13, 50–53.
项目
1.氮杂环多羧酸参与构建的多钨氧酸盐过渡-稀土异金属簇聚物和框架材料的设计合成及其电化学生物传感性能研究（**），国家自然科学基金面上项目，2019年1月至2022年12月，主持。
2. 含共轭电子有机功能配体调控的多核稀土离子嵌入的杂多钨氧簇材料的合成、结构、发光性能及发光机理研究（**），国家自然科学基金面上项目，2017年1月至2020年12月，主持。
3. 以三价砷/锑/铋为杂原子多钨氧酸盐过渡-稀土异金属磁性材料的设计合成和性能研究（**），国家自然科学基金，2014年1月至2016年12月，主持。
4. 杂多钼氧酸盐3d-4f异金属衍生材料的设计合成及其对偶氮类染料光降解性能研究（U**），国家自然科学基金-河南人才培养联合基金，2014年1月至2016年12月，主持。
5. 有机无机复合钨氧簇基材料的设计及铁电磁性能研究（6），河南省科技厅自然科学基金，2012年1月至2014年12月，主持。
6. 含砷/锑多钨酸盐过渡-稀土异金属磁性材料的合成和性能（**），河南省博士后一等资助，2015年4月至2017年6月，主持。
获奖成果
1. 钨/钼氧簇分子基功能材料结构设计及性能调控，河南省教育厅科技成果一等奖，排名第二，2018年5月。
2. Three transition-metal substituted polyoxotungstates containing Keggin fragments: from trimer, one-dimensional chain to two-dimensional sheet，河南省第二届自然科学学术奖—河南省自然科学优秀学术论文一等奖，排名第一，2013年12月。
3. Synthesis, structure and magnetism of a 2-D organic–inorganic hybrid tetra-Co^II-substituted sandwich- type Keggin germanotungstate: {[Co(dap)₂(H₂O)]₂[Co(dap)₂]₂[Co₄(Hdap)₂(B-α- HGeW₉O₃₄)₂]}?7H₂O，河南省第二届自然科学学术奖—河南省自然科学优秀学术论文二等奖，排名第一，2013年12月。
4. Two types of novel tetra-iron substituted sandwich-type arsenotungstates with supporting lanthanide pendants, 河南省第四届自然科学学术奖—河南省自然科学优秀学术论文三等奖，排名第一，2018年1月。
5. The first purely inorganic polyoxotungstates constructed from dimeric tungstoantimonate- based iron-rare-earth heterometallic fragments, 开封市第13届自然科学优秀学术成果奖—优秀学术论文奖一等奖，排名第一，2017年9月。
专利
1. 一种十核铽取代砷钨氧酸盐纳米簇合物及其制备方法和应用，专利号：ZL 2015 1 **.4, 中国专利局授予的发明专利, 授权时间：2017年12月，排名：第一。
2. 一种铋钨酸盐纳米簇合物及其制备方法与应用，专利号：ZL 2017 1 **.4, 中国专利局授予的发明专利, 授权时间：2018年12月28日，排名：第二。
3. 铜-铕异金属取代砷钨酸盐及其制备方法和应用，专利号：ZL 2015 1 **.3, 中国专利局授予的发明专利, 授权时间：2016年4月，排名：第二。
4. 具有自旋玻璃行为的铁磁性有机-无机杂化九核锰取代的夹心型锑钨氧酸盐、制备及应用，专利号：ZL 2016 1 **.7, 中国专利局授予的发明专利, 授权时间：2019年1月4日，排名：第三。
5. 有机-无机杂化过渡-稀土异金属取代锗钨酸盐晶态储氢材料及其制备方法，专利号：ZL 2012 1 **.0, 中国专利局授予的发明专利, 授权时间：2014年4月，排名：第三。
6. 二(2-乙酰吡嗪基)硫代缩二氨基脲及其铋(III)配合物的制备方法及应用，专利号：ZL 2012 1 **.4, 中国专利局授予的发明专利, 授权时间：2014年9月，排名：第三。
7. 一种镝-异烟酸包含的Waugh锰钼酸盐及其制备方法和应用，专利号：ZL 2016 1 **.7, 中国专利局授予的发明专利, 授权时间：2018年2月，排名：第四。