卓克垒
博士，教授，博士生导师，实验室建设与设备管理处处长，中国化学会化学热力学与热分析专业委员会委员，中国化工学会离子液体专业委员会委员，河南省化学会常务理事、物理化学专业委员会主任。河南省****基金获得者，河南省科技创新杰出人才，河南省学术技术带头人，河南省高等学校创新人才，绿色化学介质与反应省部共建教育部重点实验室学术带头人，河南省高等学校教学名师，河南省师德先进个人，河南省高等教育教学工作先进个人，河南省政府特殊津贴专家。
电话：；传真：
E-mail: kzhuo@htu.cn, klzhuo@263.net
联系地址：化学北楼S309





教育与研究经历：
1985.09-1989.07 河南师范大学化学系 理学学士
1989.09-1992.07 河南师范大学化学系 理学硕士
1992.09-1997.09 河南师范大学化学系讲师、副教授
1997.09-2000.07 中国科学院兰州化学物理研究所 理学博士
2000.07-2002.12 河南师范大学化学系 教授
2003.01-2008.09 河南师范大学化学与环境科学院 教授、博导、副院长
2008.09-2012.12 河南师范大学化学与环境科学院 教授、博导、院长
2013.01-今 河南师范大学化学化工学院 教授、博导、实验室建设与设备管理处处长
2004年作为国家选派高级访问****到日本东京工业大学进行合作研究
研究领域与兴趣：
功能溶液化学、绿色介质、应用电化学、功能化绿色材料
近年来主持的主要科研项目:
1. 国家自然科学基金(**)：仿生离子液体的设计与性质及其在生物催化中的应用。
2. 国家自然科学基金(**)：离子液体在水及糖水溶液中的性质及其与结构关系的研究。
3. 国家自然科学基金(**)：电解质和寡糖的相互作用及其与糖链立体结构的关系研究。
4. 河南省科技创新杰出人才计划(4)：仿生离子液体的设计、合成及其在生物传感器中的应用。
5. 河南省高校创新人才培养基金(豫高教[2002]129号)：模型生物体系的生物物理化学性质的研究。
获奖情况:
1.“新世纪高师物理化学的教学模式的探索与实践”，高等教育国家级教学成果奖二等奖，证书编号：**。
2.“化学类专业人才培养方案与课程体系综合改革与实践”，河南省高等教育省级教学成果奖一等奖，证书编号：豫教[2012]00756。
3.《糖和氨基酸与电解质弱相互作用的热力学研究》，河南省科学技术进步奖一等奖，证书号：2004-J-006-R02/10。
4. 《锂离子电池电解质的微观结构研究》，河南省科学技术进步奖一等奖，证书号：2009-J-011-R05/08。
5.多次获得河南省优秀硕士学位论文指导教师、河南师范大学优秀研究生指导教师。
代表性成果：
学术著作：
1.《Solution Chemistry Research Progress》，Nova Science Publishers, Inc, 2008。
2.《Chemical principles and focuses》(《化学原理与热点》)，郑州大学出版社，2007。
学术论文：

1. Wang ZJ, Pei YC, Zhao J, Li ZY, Chen YJ, Zhuo KL*. Formation of ether-functionalized ionic liquid-based aqueous two-phase systems and their application in separation of protein and saccharides. J. Phys. Chem. B., 2015, 119(12): 4471-4478.
2. Liu JM, Zhang X, Yi H, Liu C, Liu R, Zhang H, Zhuo KL*, Lei AW*. Chloroaceta te-promoted selective oxidation of heterobenzylic methylenes under copper catalysis. Angew. Chem. Int. Ed., 2015, 54(4): 1261-1265.
3. Zhuo KL*, Du QZ, Bai GY, Wang CY, Chen YJ, Wang JJ*. Hydrolysis of cellulose catalyzed by novel acidic ionic liquids. Carbohydr. Polym., 2015, 115: 49-53.
4. Chen YJ, Zhuo KL*, Chen JJ, Bai GY, Volumetric and viscosity properties of dicationic ionic liquids. J. Chem. Thermodyn., 2015, 86: 13-19.
5. Chen YJ, Zhang HH, Li AQ, Zhuo KL*. Conductivities for ZnSO₄/MgSO₄ + sucrose/trehalose + water systems at 298.15 K. Fluid Phase Equilib., 2015, 388: 78-83.
6. 李奡麒，陈玉娟，胡晓宇，卓克垒*. 低共熔溶剂辅助水热法合成分层球状微/纳米ZnO晶体及其光催化性能. 高等学校化学学报, 2015, 36(1): 165-170.
7. Liu JM*, Zhang X, Shi LJ, Liu MW, Yue YY, Li FW*, Zhuo KL*. Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions. Chem. Commun., 2014, 50(69): 9887-9890.
8. Wang CF, Sun D, Zhuo KL*, Zhang HC, Wang JJ*. Simple and green synthesis of nitrogen-, sulfur-, and phosphorus-co-doped carbon dots with tunable luminescence properties and sensing application. RSC Adv., 2014, 4(96): 54060-54065.
9. Yue YY, Zhang YL, Song WW, Zhang X, Liu JM*, Zhuo KL*. Manganese dioxide-mediated oxidative coupling of 1,3-dicarbonyl compounds with a,b-unsaturated ketones: direct access to 3,4-dicarbonyl substituted furans. Adv. Synth. Catal., 2014, 50(69): 2459-2464.
10. Wang CF, Xu PP, Zhuo KL*. Ionic Liquid Functionalized Graphene-Based Electrochemical Biosensor for Simultaneous Determination of Dopamine and Uric Acid in the Presence of Ascorbic Acid. Electroanalysis, 2014, 26, 191-198.
11. Zhuo KL*, Ren H, Wei YJ, Chen YJ, Ma JJ. Activity Coefficients of [Cnmim]Br (n = 3 to 8) Ionic Liquids in Aqueous Fructose Solution at T = 298.15 K. J. Chem. Eng. Data, 2014, 59, 640-648.
12. Wang CF, Chen YJ, Zhuo KL*, Wang JJ. Simultaneous reduction and surface functionalization of graphene oxide via an ionic liquid for electrochemical sensors. Chem. Commun., 2013, 49, 3336-3338.
13. Zhuo KL*, Wei YJ, Ma JJ, Chen YJ, Bai GY. Response of PVC membrane ion-selective electrodes to alkylmethylimidazolium ionic liquid cations. Sensors and Actuators B: Chemical, 2013, 186, 461-465.
14. Liu JM*, Zhang NF, Yue YY, Liu GH, Liu R, Zhang YL, Zhuo KL*. One-Pot Synthesis of Benzimidazo[1,2-f]phenanthridines by Cascade Palladium-Catalyzed N-Arylation and Intramolecular C–H Coupling. Eur. J. Org. Chem, 2013, 7683–7687.
15. Zhao J, Chen YJ, Liu YH, Zhuo KL*. Conductivity in MnSO₄-saccharide-water solutions at 298.15 K. Fluid Phase Equilib., 2013, 352, 28-33.
16. Liu JM, Zhang NF, Yue YY, Wang D, Zhang YL, Zhang X, Zhuo KL*. A simple and efficient approach to 2-alkynylbenzofurans under mild copper(I)-catalyzed conditions. RSC Adv., 2013, 3, 3865–3868.
17. Liu JM, Liu MW, Yue YY, Zhang NF, Zhang YL, Zhuo KL*. Construction of the flavones and aurones through regioselective carbonylative annulation of 2-bromophenols and terminal alkynes. Tetrahedron Letters, 2013, 54, 1802-1807.
18. 胡晓宇，刘千阁，卓克垒*，王键吉. 咪唑类离子液体辅助水热法合成棒状微/纳米ZnO晶体. 高等学校化学学报, 2013, 34, 324-330.
19. 张宁飞，张远丽，刘规划，张欣，王永丽，刘建明*，卓克垒*. Pd₂ dba₃高效催化碘代芳烃的双羰化反应合成α-酮酰胺. 分子催化, 2013, 27, 250-255.
20. Zhuo KL*, Fu YY, Bai GY, Wang JJ, Yan HK, Wang HQ. Calorimetric and Theoretical Study of the Interaction between Some Saccharides and Sodium Halide in Water. J. Phys. Chem. B, 2012, 116, 10026-10035.
21. Chen YJ, Xuan XP, Zhang HH, Zhuo KL*. Conductivities of 1-alkyl-3-methylimidazolium chloride ionic liquids in monosaccharide + water solutions at 298.15 K, Fluid Phase Equilib., 2012, 316, 164-171.
22. Liu JM, Liu MW, Yue YY, Yao MH, Zhuo KL*. Environmental Friendly Azide-Alkyne Cycloaddition Reaction of Azides, Alkynes, and Organic Halides or Epoxides in Water: Efficient "Click" Synthesis of 1,2,3-Triazole Derivatives by Cu Catalyst. Chin. J. Chem., 2012, 30, 644-650.
23. Zhuo KL*, Chen YJ, Chen J, Bai GY, Wang JJ. Interactions of 1-butyl-3-methylimidazolium carboxylate ionic liquids with glucose in water: a study of volumetric properties, viscosity, conductivity and NMR. Phys. Chem. Chem. Phys., 2011, 13(32), 14542-14549.
24. Chen YJ, Zhao Y, Chen J, Zhuo KL*. Aggregation behavior of a model ionic liquid surfactant in monosaccharide + water solutions. J. Colloid Interf. Sci., 2011, 364, 388-394.
25. Dong WY, Zhao Y, Zhuo KL*, Chen YJ. Reply to "Comment on 'Individual Ionic Activity Coefficients of Sodium Halides in Glucose-Water Solutions at 298.15 K' ". Ind. Eng. Chem. Res., 2011, 50, 9472.
26. Zhu AL, Li LJ, Wang JJ, Zhuo KL. Direct nucleophilic substitution reaction of alcohols mediated by a zinc-based ionic liquid. Green Chem., 2011, 13(5), 1244-1250.
27. Liu JM, Yue YY, Liu MM, Zhang NF, Zhuo KL*. Synthesis and interaction studies of benzimidazole derivative with human serum albumin. Spectrochim. Acta, Part A: Molecular and Biomolecular Spectroscopy, 2011, 82, 299-305.
28. Zhuo KL*, Liu QG, Liu HX, Wang YF, Chen YJ, Wang JJ. Relative Permittivities for the Galactose + Glycine + Water Solution from (278.15 to 313.15) K. J. Chem. Eng. Data, 2010, 55(1), 526-530.
29. Ma JJ, Zhang XK, Zhuo KL*, Liu HX, Wang JJ. Activity coefficients of CaCl₂ in (serine or proline + water) mixtures at T = 298.15 K. J. Chem. Thermodyn., 2010, 42(5), 689-694.
30. 卓克垒*，董伟燕，赵扬. 298.15 K下果糖水溶液中卤化钠单个离子活度系数. 中国科学：化学, 2010, 40(9), 1363-1370.
31. Dong WY, Zhao Y, Zhuo KL*, Chen YJ. Individual Ionic Activity Coefficients of Sodium Halides in Glucose-Water Solutions at 298.15 K. Ind. Eng. Chem. Res., 2010, 49, 9430-9435.
32. Zhuo KL*, Liu HX, Tang JM, Chen YJ, Wang JJ. Interactions of Sodium Halides with Sugars in Water: A Study of Viscosity and 1H Spin-Lattice Relaxation Time. J. Phys. Chem. B, 2009, 1139(41), 13638-13644.
33. Zhuo KL*, Liu YH, Liu HX, Wang JJ. Conductivity in NiSO₄–d-glucose–water solutions at 278.15–308.15K. Fluid Phase Equilibria, 2009, 284(1), 50-55.
34. Zhuo KL*, Chen YJ, Wang WH, Wang JJ. Conductivities of CuSO₄ and CdSO₄ in Sucrose/Trehalose-Water Systems at 298.15 K. Ind. Eng. Chem. Res., 2009, 48(13), 6432-6435.
35. Zhuo KL*, Liu YH, Zhao QF, Liu HX, Wang JJ. Volumetric properties of D-galactose in aqueous HCl solution at 278.15 to 318.15 K. Journal of Molecular Liquids, 2009, 147(3), 186-190.
36. Zhuo KL*, Chen YJ, Kang L, Xu SJ, Wang JJ. Dielectric Constants for Binary Amino Acid-Water Solutions from (278.15 to 313.15) K. J. Chem. Eng. Data, 2009, 54(1), 137-141.
37. Wang HY, Wang JJ, Zhang SL, Pei YC, Zhuo KL. Ionic Association of the Ionic Liquids [C₄mim], [BF₄], [C₄mim][PF₆], and [C_nmim]Br in Molecular Solvents. Chem. Phys. Chem., 2009, 10(14), 2516-2523.
38. Zhuo KL*, Dong WY, Wang WH, Wang JJ. Activity coefficients of individual ions in aqueous solutionof sodium halides at 298.15K. Fluid Phase Equilibria, 2008, 274(1-2), 80-84.
39. Zhuo KL*, Chen YJ, Wang WH, Wang JJ. Volumetric and Viscosity Properties of MgSO₄ / CuSO₄ in Sucrose + Water Solutions at 298.15 K. J. Chem. Eng. Data, 2008, 53(9), 2022-2028.
40. Zhuo KL*, Liu HX, Zhang XK, Liu YH, Wang JJ. A ¹³C NMR study on the interactions of calcium chloride/potassium chloride with pyranosides in D₂O. Carbohydrate Research, 2008, 343(14), 2428-2432.
41. Zhuo KL*, Liu HX, Zhang HH, Liu YH, Wang JJ. Activity coefficients of CaCl₂ in maltose + water and lactose + water mixtures at 298.15 K. J. Chem. Thermodyn., 2008, 40(5), 889-896.
42. Zhuo KL*, Wang YP, Zhao Y, Liu Q, Wang JJ. Interactions of calcium nitrate with pyranosides in water: a ¹³C NMR study. Spectrochim. Acta Part A, 2008, 71(1), 100-104.
43. Zhuo KL*, Ren QH, Zhao Y, Wang JJ. Debye-Huckel contributions to the Gibbs energy interaction parameters for ternary electrolyte plus non-electrolyte plus water systems. J. Solution Chem., 2008, 37, 283-289.
44. Zhuo KL*, Liu HX, Zhang HH, Liu YH, Wang JJ. Activity coefficients and volumetric properties for the NaI plus maltose plus water system at 298.15 K. J. Chem. Eng. Data, 2008, 53, 57-62.
45. Zhuo KL*, Liu GJ, Wang YP, Ren QH, Wang JJ. Activity coefficients and conductivities of calcium nitrate in glucose/galactose-water mixtures at 298.15 K. Fluid Phase Equilibria, 2007, 258, 78-82.
46. Zhuo KL*, Wang JJ. Activity Coefficients on Different Concentration Scales and Reference States. AIChE J., 2006, 52, 2988-2990.
47. Zhuo KL*, Zhang QF, Xuan XP, Zhang HC, Wang JJ. Volumetric properties of glucose in aqueous HCl solutions at temperatures from 278.15 to 318.15 K. Acta Chim. Sinica, 2006, 64, 1635-1641.
48. Zhuo KL*, Zhao Y, Yang LX, Liu Q, Wang JJ. Volumetric properties for the electrolyte (NaCl, NaBr and NaI)-monosaccharide (D-mannose and D-ribose)-water systems at 298.15 K. J. Chin. Chem. Soc., 2006, 53, 961-970.
49. Zhuo KL*, Liu Q, Wang YP, Ren QH, Wang JJ. Volumetric and viscosity properties of monosaccharides in aqueous amino acid solutions at 298.15 K. J. Chem. Eng. Data, 2006, 51, 919-927.
50. Zhuo KL*, Wang YP, Liu Q, Zhang HH, Wang JJ. Thermodynamic and conductivity properties of Cd(NO₃)(2) in monosaccharide (D-glucose, D-galactose, D-xylose, D-ribose) plus water systems at 298.15 K. J. Solution Chem., 2006, 35, 753-768.
51. Zhuo KL*. Thermodynamic Pair Interaction Parameters on Various Concentration Scales. J. Phys. Chem. B, 2005, 109, 7460-7462.

专利：
1. 卓克垒，王春风，孙东，陈玉娟，刘丽红，徐攀，一种荧光性能可调的硫磷氮共掺杂碳点及其制备方法，申请号：4.X。
2. 卓克垒，刘丽红，王春风，陈玉娟，孙东，闫崇，徐攀攀，王之俊，离子液体/表面活性剂修饰玻碳电极及其制备方法和应用，申请号：1.3。
河南省优秀硕士论文：
1. 刘倩《单糖-氨基酸-水体系的体积、粘度及红外光谱研究》，2007年12月。
2. 刘宏勋《水溶液中糖与电解质相互作用的粘度及核磁共振研究》，2009年12月。