张永明 ，男， 1960 年出生， 1999 年毕业于华东理工大学，获材料科学与工程专业博士学位，同年进入上海交通大学工作，现为上海交通大学教授，上海市领军人才，全国劳动模范，享受国务院政府特殊津贴专家，“泰山****”特聘专家。从事含氟聚合物和含氟功能膜的研发。主持并圆满完成国家 863 计划、支撑计划重大项目，实现了氯碱工业全氟离子膜的产业化，结束了中国没有全氟离子膜的历史，打破了制约我国氯碱工业安全运行和健康发展的瓶颈，是中国氯碱工业发展的里程碑。同时开展的研究包括燃料电池新能源汽车核心材料、催化分离膜材料、海水淡化膜材料、储能电池膜材料、特种润滑材料等。所著《含氟功能材料》被评为化工领域科技图书一等奖。


主要研究方向

特种功能高分子材料

新能源汽车核心材料

催化分离膜材料、储能电池膜材料

光电功能材料与生物材料


主持项目

欧盟第七框架项目
“十五” 863 计划重大课题“全氟离子交换膜材料关键技术研究”
“十一五”国家支撑计划重大项目“全氟离子膜工程技术研究”
“十一五” 863 计划重点项目“新型制氢及高温质子交换膜燃料电池技 术研发与应用示范”
“十二五”国家支撑计划重点项目“氯碱离子膜大规模应用研究”
欧盟第六框架项目
中加合作项目“新型燃料电池质子膜研究”


获奖情况

2007 年山东省“泰山****”
2009 年山东省技术发明一等奖（排名第一）
2010 全国劳动模范
2010 年享受国务院特殊津贴专家
2010 年所著《含氟功能材料》获中国石化工业优秀出版物奖（图书奖）一等奖（排名第一）
2010 年“全氟离子交换膜工程技术研究”入选“十一五”国家重大科技成就
2011 年“全氟离子膜工程技术研究团队”获“十一五”国家科技计划执行优秀团队奖
2011 年获中国石化联合会科技进步二等奖（排名第一）
2011 年获国家技术发明二等奖（排名第一）
2012 年获“何梁何利科学与技术进步奖”
2012 年获“上海市领军人才”称号
2013 年上海交通大学“凯原十佳教师”



主要学术兼职

国家分离膜标准化技术委员会委员
科技部国际合作评审专家
中国科技奖励评审专家
中国膜工业协会 专家
中国氯碱协会专家
中国氟硅协会专家
中国无机盐协会专家
中国仪表功能膜材料协会专家
《膜科学与技术》编委
《氯碱工业》编委


Publication List

2013

69 Yuan, W. Z.; Tan, Y.; Gong, Y.; Lu, P.; Lam, J. W. Y.; Shen, X. Y.; Feng, C.; Sung, H. H-Y.; Lu, Y.; Williams, I. D.; Sun, J. Z.; Zhang, Y.; Tang, B. Z.“Synergy between Twisted Conformation and Effective Intermolecular Interactions: Strategy for Efficient Mechanochromic Luminogens with High Contrast”Advanced Materials2013, 26, 2837.

68 Gong, Y.; Tan, Y.; Liu, J.; Lu, P.; Feng, C.; Yuan, W. Z.; Lu, Y.; Sun, J. Z.; He, G.; Zhang, Y.“Twisted D–pi–A solid emitters: efficient emission and high contrast mechanochromism”Chemical Communications2013, 49, 4009.

67 Zhu, Y.; Pei, S.; Tang, J.; Li, H.; Wang, L.; Yuan, W. Z.; Zhang, Y.“Enhanced chemical durability of perfluorosulfonic acid membranes through incorporation of terephthalic acid as radical scavenger”Journal of Membrane Science2013, 432,

66 Yang, L.; Tang, J.; Li, L.; Ai, F.; Chen, X.; Yuan, W. Z.; Zhang, Y.“Properties of precursor solution cast PFSI membranes with various ion exchange capacities and annealing temperatures”RSC Advances2013, 3, 7289.

65 Tang, J.; Yuan, W.; Zhang, Z.; Li, H.; Zhang, Y.“Evidence for a crystallite-rich skin on perfluorosulfonate ionomer membranes”RSC Advances2013, 3, 8947.

64 Wang, C.; Li, H.; Zhao, J.; Zhu, Y.; Yuan, W. Z.; Zhang, Y.“Graphene Nanoribbons as A Novel Support Material for High Performance Fuel Cell Electrocatalysts”International Journal of Hydrogen Energy2013, 38, 13230.

63 Yang, L.; Li, H.; Ai, F.; Chen, X.; Tang, J.; Zhu, Y.; Wang, C.; Yuan, W. Z.; Zhang, Y.“A New Method to Prepare High Performance Perfluorinated Sulfonicacid Ionomer/Porous Expanded Polytetrafluoroethylene Composite Membranes Based on Perfluorinated Sulfonyl Fluoride Polymer Solution”Journal of Power Sources2013, 243, 392.

62 Gong, YY.; Tan, YQ.; Mei, J.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z.“Room temperature phosphorescence from natural products: Crystallization matters”Science China Chemistry2013, 56, 1178.

61 Gong, YY.; Tan, YQ.; Li, H.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z.“Crystallization-induced phosphorescence of benzils at room temperature”Science China Chemistry2013, 56, 1183.

60 Lu, YW.; Tan, YQ.; Gong, YY.; Li, H.; Yuan, WZ.; Zhang, YM.; Tang, B. Z.“High efficiency D-A structured luminogen with aggregation-induced emission and mechanochromic characteristics”Chinese Science Bulletin2013, 58, 2719.


2012

59 Tang, J.; Yuan, W.; Wang, J.; Tang, J.; Li, H.; Zhang, Y.“Perfluorosulfonate ionomer membranes with improved through-plane proton conductivity fabricated under magnetic field”Journal of Membrane Science2012, 423–424, 267.

58 Cai, Z.; Li, L.; Su, L.; Zhang, Y.“Supercritical carbon dioxide treated Nafion 212 commercial membranes for direct methanol fuel cells”Electrochemistry Communications2012, 14, 9.

57 Cai, Z.; Liu, Y.; Zhao, J.; Li, L.; Zhang, Y.; Zhang, J.“Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries”Journal of Power Sources2012, 202, 341.

56 Yang, L.; Yuan, W.; Zhao, J.; Ai, F.; Chen, X.; Zhang, Y.“A Novel Approach to Prepare Uniaxially Aligned Nanofibers and Longitudinally Aligned Seamless Tubes Through Electrospinning”Macromolecular Materials and Engineering2012, 297, 604.

55 Li, L.; Su, L.; Zhang, Y.“Enhanced performance of supercritical CO2 treated Nafion 212 membranes for direct methanol fuel cells”International Journal of Hydrogen Energy2012, 37, 4439.

54 Cai, Z.; Liu, Y.; Liu, S.; Li, L.; Zhang, Y.“High performance of lithium-ion polymer battery based on non-aqueous lithiated perfluorinated sulfonic ion-exchange membranes”Energy & Environmental Science2012, 5, 5690.

53 Chen, X.; Yuan, W. Z.; Zhao, J.; Yang, L.; Li, H.; Li, L.; Zhang, Y.“Thermal-mechanical stability of ethylene tetrafluoroethylene alternating copolymer, and modification thereof”Journal of Polymer Research2012, 19, 9820.

52 Xu, A.; Yuan, W. Z.; Zhang, H.; Wang, L.; Li, H.; Zhang, Y.“Low-molecular-weight polytetrafluoroethylene bearing thermally stable perfluoroalkyl end-groups prepared in supercritical carbon dioxide”Polymer International2012, 61 , 901.

51 Chen, X.; Yuan, W. Z.; Li, H.; Zhang, Y.“Rheological study on tetrafluoroethylene/hexafluoropropylene copolymer and its implication for processability”Journal of Applied Polymer Science2012, 125, 3361.

50 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y.“Fluorine-containing block copolymer particles with surface and internal hierarchical microphase separation structures”Soft Matter2012, 8, 2471.

49 Qin, S.; Yuan, W. Z.; Li, H.; Zhang, Y.“Order–order phase transition and transformation in co-assembled particles from fluorinated FA/FB type diblock copolymers”Soft Matter2012, 8, 8405.

48 Xu, A.; Li, H.; Yuan, W. Z.; Geng, B.; Zhang, S.; Zhang, H.; Wang, L.; Zhang, Y.“Radical homopolymerization of tetrafluoroethylene initiated by perfluorodiacyl peroxide in supercritical carbon dioxide: Reaction mechanism and initiation kinetics”European Polymer Journal2012, 48,1431.

47 Yang, L.; Tang, J.; Li, L.; Chen, X.; Ai, F.; Yuan, W. Z.; Wang, L.; Zhang, Y.“High quality pristine perfluorosulfonated ionomer membranes prepared from perfluorinated sulfonyl fluoride solution”RSC Advances2012, 2, 5950.

46 Chen, X.Y.; Yuan, W. Z.; Ai, F.; Li, H.; Li, L.; Wang, J.; Zhang, Y.“Melt rheological properties of ETFE: an attempt to illuminate the fluorine-substitution effect”Polymer Bulletin2012, 69, 375.

45 Ai, F.; Wang, Q.; Yuan, W. Z.; Li, H.; Chen, X.; Yang, L.; Zhang, Y.; Pei, S.“Biocompatibility and anti-cracking performance of perfluorocarboxylic acid ionomer membranes for implantable biosensors”Journal of Materials Science2012, 47, 5181.

44 Xu, A.; Yuan, W. Z.; Zhao, J.; Li, H.; Zhang, H.; Zhang, Y.“Copolymerizations of tetrafluoroethylene and perfluoropropylvinyl ether in supercritical carbon dioxide: Polymer synthesis, characterization, and thermal properties”Journal of Applied Polymer Science2012, 124, 1785.

43 Zhu, H.; Tong, H.; Gong, Y.; Shao, S.; Deng, C.; Yuan, W. Z.; Zhang, Y.“Fluorene-and benzimidazole-based blue light-emitting copolymers: Synthesis, photophysical properties, and PLED applications”Journal of Polymer Science Part A: Polymer Chemistry2012, 50 , 2172.

42 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y.“Fabrication of polymeric honeycomb microporous films: breath figures strategy and stabilization of water droplets by fluorinated diblock copolymer micelles”Journal of Materials Science2012, 47, 6862.

41 Ai, F.; Li, H.; Wang, Q.; Yuan, W. Z.; Chen, X.; Yang, L.; Zhao, J.; Zhang, Y.“Surface characteristics and blood compatibility of PVDF/PMMA membranes”Journal of Materials Science2012, 47, 5030.

40 Chen, X. Y.; Zhang, Y. M.“Determining molecular weight scale and molecular weight distribution of ethylene-tetrafluoroethylene alternating copolymer via a rheological technique”Journal of Applied Polymer Science2012, 125, 2442.

39 Yuan, W. Z.; Gong, Y.; Chen, S.; Shen, X. Y.; Lam, J. W.; Lu, P.; Lu, Y.; Wang, Z.; Hu, R.; Xie, N.“Efficient Solid Emitters with Aggregation-Induced Emission and Intramolecular Charge Transfer Characteristics: Molecular Design, Synthesis, Photophysical Behaviors, and OLED Application”Chemistry of Materials2012, 24, 1518.

38 Yang, C.; Castelvetro, V.; Zhang, Y.; Hu, C.“Facile hydrophobic modification of hybrid poly (urethane-urea) methacrylate aqueous dispersions and films through blending with novel waterborne fluorinated acrylic copolymers”Colloid and Polymer Science2012, 290, 491.

37 Ai, F.; Yuan, W. Z.; Wang, Q.; Li, H.; Zhang, Y.; Pei, S.“Enhancing the anti-cracking performance of perfluorosulfonic acid membranes for implantable biosensors through supercritical CO2 treatment”Journal of Materials Science2012, 47, 3602.


2011

36 Zhao, J.; Xu, A.; Yuan, W. Z.; Gao, J.; Tang, J.; Wang, L.; Ai, F.; Zhang, Y.“Evaluation of electrospun nanofiber formation of perfluorosulfonic acid and poly (N-vinylpyrrolidone) through solution rheology”Journal of Materials Science2011, 46, 7501.

35 Peron, J.; Edwards, D.; Haldane, M.; Luo, X.; Zhang, Y.; Holdcroft, S.; Shi, Z.“Fuel cell catalyst layers containing short-side-chain perfluorosulfonic acid ionomers”Journal of Power Sources2011, 196, 179.

34 Yang, C.; Castelvetro, V.; Scalarone, D.; Bianchi, S.; Zhang, Y.“Three different β-cyclodextrins direct the emulsion copolymerization of a highly fluorinated methacrylate toward distinctive nanostructured particle morphologies’’Journal of Polymer Science Part A: Polymer Chemistry2011, 49, 4518.

33 Zhao, J.; Yuan, W. Z.; Xu, A.; Ai, F.; Lu, Y.; Zhang, Y.“Perfluorinated sulfonic acid ionomer/poly (N-vinylpyrrolidone) nanofiber membranes: Electrospinning fabrication, water stability, and metal ion removal applications”Reactive and Functional Polymers2011, 71, 1102.

32 Luo, X.; Holdcroft, S.; Mani, A.; Zhang, Y.; Shi, Z.“Water, proton, and oxygen transport in high IEC, short side chain PFSA ionomer membranes: consequences of a frustrated network”Physical Chemistry Chemical Physics2011, 13, 18055.

31 Xu, A.; Zhao, J.; Yuan, W. Z.; Li, H.; Zhang, H.; Wang, L.; Zhang, Y.“Tetrafluoroethylene Copolymers with Sulfonyl Fluoride Pendants: Syntheses in Supercritical Carbon Dioxide, Polymerization Behaviors, and Properties”Macromolecular Chemistry and Physics2011, 212, 1497.

30 Qin, S.; Li, H.; Yuan, W.; Zhang, Y.“Hierarchical self-assembly of fluorine-containing diblock copolymer: From onion-like nanospheres to superstructured microspheres”Polymer2011, 52, 1191.

29 Yuan, W. Z.; Chen, S.; Lam, J. W.; Deng, C.; Lu, P.; Sung, H. H.; Williams, I. D.; Kwok, H. S.; Zhang, Y.; Tang, B. Z.“Towards high efficiency solid emitters with aggregation-induced emission and electron-transport characteristics”Chemical Communications2011, 47, 11216.


2010

28 Li, L.; Shang, F.; Wang, L.; Pei, S.; Zhang, Y.“Transport properties of PFSA membranes with various ion exchange capacities for direct methanol fuel cell application”Energy & Environmental Science2010, 3, 114.

27 Wen, X. W.; Pei, S. P.; Li, H.; Ai, F.; Chen, H.; Li, K. Y.; Wang, Q.; Zhang, Y. M.“Study on an antifouling and blood compatible poly (ethylene–vinyl acetate) material with fluorinated surface structure”Journal of Materials Science2010, 45, 2788.

26 Pei, S.; Qu, S.; Zhang, Y.“Direct Electrochemistry and Electrocatalysis of Hemoglobin at Mesoporous Carbon Modified Electrode”Sensors2010, 10, 1279.


2009

25 Zhao, H.; Yang, J.; Li, L.; Li, H.; Wang, J.; Zhang, Y.“Effect of over-oxidation treatment of Pt–Co/polypyrrole-carbon nanotube catalysts on methanol oxidation”International Journal of Hydrogen Energy2009, 34, 3908.

24 Su, L.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C.“Perfluorosulfonic acid membranes treated by supercritical carbon dioxide method for direct methanol fuel cell application”Journal of Membrane Science2009, 335, 118.

23 Li, W.; Li, H.; Zhang, Y. M.“Preparation and investigation of PVDF/PMMA/TiO2 composite film”Journal of Materials Science2009, 44, 2977.

22 Su, L.; Li, L.; Li, H.; Tang, J.; Zhang, Y.; Yu, W.; Zhou, C.“Preparation of polysiloxane modified perfluorosulfonic acid composite membranes assisted by supercritical carbon dioxide for direct methanol fuel cell”Journal of Power Sources2009, 194, 220.

21 Su, L.; Pei, S.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C.“Preparation of polysiloxane/perfluorosulfonic acid nanocomposite membranes in supercritical carbon dioxide system for direct methanol fuel cell”International Journal of Hydrogen Energy2009, 34, 6892.

20 Shang, F.; Li, L.; Zhang, Y.; Li, H.“PWA/silica/PFSA composite membrane for direct methanol fuel cells”Journal of Materials Science2009, 44, 4383.

19 Chen, H.; Li, H.; Pei, S.; Wen, X.; Zhang, Y.“Synthesis and characterization of fluoropoly (amide–sulfonamide) s via polycondensation”Polymer2009, 50, 4317.

18 Chen, H.; Huang, Z.; Li, H.; Zhang, Y.; Liu, Y.“Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization”Polymer Bulletin2009, 62, 151.

17 Han, L.; Zhang, Y.; Li, H.; Li, L.“The synthesis and surface activity of perfluoro-2, 5-dimethyl-3,6-dioxanonanoic acid ester fluorocarbon surfactants’’Colloids and Surfaces A: Physicochemical and Engineering Aspects2009, 334, 176.


2008

16 Luan, Y.; Zhang, Y.; Zhang, H.; Li, L.; Li, H.; Liu, Y.“Annealing effect of perfluorosulfonated ionomer membranes on proton conductivity and methanol permeability”Journal of Applied Polymer Science2008, 107, 396.

15 Huang, Z. X.; Zhang, Y. M.; Li, H.; Liu, Y. G.“Controlled/“living” radical polymerization of methyl methacrylate catalyzed by cobalt acetate”Macromolecular Chemistry and Physics2008, 209, 825.

14 Luan, Y.; Zhang, H.; Zhang, Y.; Li, L.; Li, H.; Liu, Y.“Study on structural evolution of perfluorosulfonic ionomer from concentrated DMF-based solution to membranes”Journal of Membrane Science2008, 319, 91.

13 Huang, Z. X.; Zhang, Y. M.; Li, H.; Luan, Y. H.; Liu, Y. G.“Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co (II) hybrid catalyst”Journal of Polymer Science Part A: Polymer Chemistry2008, 46 , 1416.

12 Li, L.; Zhang, Y. “Chemical modification of Nafion membrane with 3,4-ethylenedioxythiophene for direct methanol fuel cell application”Journal of Power Sources2008, 175, 256.

11 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.“Co@ Pt–Ru core-shell nanoparticles supported on multiwalled carbon nanotube for methanol oxidation”Electrochemistry Communications2008, 10, 1527.

10 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.“Nanostructured polypyrrole/carbon composite as Pt catalyst support for fuel cell applications”Journal of Power Sources2008, 184, 375.

9 Luan, Y.; Zhang, Y.; Li, L.; Zhang, H.; Zhang, Q.; Huang, Z.; Liu, Y.“Perfluorosulfonic ionomer solution in N, N-dimethylformamide”Journal of Applied Polymer Science2008, 107, 2892.

8 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.; Li, H.“Synthesis and characterization of bimetallic Pt–Fe/polypyrrole–carbon catalyst as DMFC anode catalyst”Electrochemistry Communications2008, 10, 876.


2007

7 Huang, Z.; Zhang, Y.; Li, H.; Liu, Y.“A novel immobilized cobalt (II)/copper (II) bimetallic catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate”Applied Catalysis A: General2007, 332, 192.

6 Li, L.; Zhang, Y.; Drillet, J. F.; Dittmeyer, R.; Jüttner, K.M.“Preparation and characterization of Pt direct deposition on polypyrrole modified Nafion composite membranes for direct methanol fuel cell applications”Chemical Engineering Journal2007, 133, 113.


2006

5 Li, H.; Zhang, Y. M.; Zhang, H.; Xue, M. Z.; Liu, Y. G.“Novel, well-defined polystyrene with a fluorine cluster end-capped group: Synthesis, characterization, and surface properties”Journal of Polymer Science Part A: Polymer Chemistry2006, 44, 3853.

4 Huang, Z.; Zhang, Y.; Zhao, C.; Qin, J.; Li, H.; Xue, M.; Liu, Y.“Direct gas-phase epoxidation of hexafluoropropylene with molecular oxygen using Ag catalyst”Applied Catalysis A: General2006, 303, 18.


2005

3 Dou, H. Y.; Ni, H.-B.; Zhao, C.-X.; Zhang, Y. M.“EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent”Journal of Fluorine Chemistry2005, 126, 1130.

2 Li, Z. H.; Zhang, Y. M.; Xue, M. Z.; Zhou, L.; Liu, Y. G.“Atom transfer radical polymerization of methyl methacrylate catalyzed by cobalt catalyst system”Journal of Polymer Science Part A: Polymer Chemistry2005, 43, 5207.

1 Li, Z.; Li, H.; Zhang, Y.; Xue, M.; Zhou, L.; Liu, Y.“A hybrid supported nickel catalyst for the controlled radical polymerization of methyl methacrylate”Applied Catalysis A: General2005, 292, 61.


著作 ：

1 生物高分子 第 2 卷 类聚异戊二烯 /[ 日 ] 古山种俊 (Koyama, T.), [ 德 ] A. 斯泰阴比歇尔 (Steinb ü chel, A.) 主编 ; 刘燕刚，薛敏钊，张永明主译 . 北京：化学工业出版社 ( 现代生物技术与医药科技出版中心 ) 2004, 8.

2 含氟功能材料 . 张永明，李虹，张恒 . 北京：化学工业出版社 2008.


3 PEM Fuel Cell Failure and Mode Analysis. Wang, H.; Li, H.; Yuan, X.-Z. Eds; Chapter 4, Luan, Y.; Zhang, Y. Membrane Degradation, Boca Raton: CRC Press, Taylor & Francis Group, 2011, December


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E-mail : ymzhang@sjtu.edu.cn