李斌 高分子化学教研室

李斌 1962年10月出生，博士，教授，博士生导师。1997年9月毕业于北京理工大学国家阻燃材料研究实验室并获工学博士学位。

现任高分子化学与物理黑龙江省重点学科学科带头人；黑龙江省阻燃材料分子设计与制备重点实验室主任。

主要研究方向

环境友好无卤阻燃高分子材料；功能纳米复合高分子材料；生物质与医用高分子材料。

发表学术论文150余篇，其中被SCI收录100余篇，并被SCI他人引用500余次。专著1部，主编教材1部，主审教材2部。获得国家发明专利11项，申报发明专利3项。获省自然科学奖一等奖1项，省科技进步二等奖3项，高校科技奖一等奖3项，二等奖1项，省教学成果二等奖1项，省有机化学精品课程负责人。主持国家“十一五”科技支撑计划、国家自然科学基金项目等20余项。有5项科研成果实现产业化。

龙江学者特聘教授、国务院政府特殊津贴获得者、省杰出青年科学基金获得者、获省优秀教师和省优秀共产党员称号。任中国阻燃学会常务理事、黑龙江省化学学会副理事长、黑龙江省化工学会常务理事、黑龙江省分析测试学会副理事长、黑龙江省塑料工程学副理事长，《化学与粘合》杂志编委等。

研究工作简历（近5年）

1. 新型耐热耐水含磷无卤阻燃环氧树脂制备与性能基础研究（**）， 国家自然科学基金项目，2012.1-2015.12，60万元。李斌(主持)

2.木材纤维素选择性氧化新体系的构建与新材料潜在应用基础研究（**），国家自然科学基金项目，2014.1-2017.12,84万元。李斌（主持）

3.木粉基表面接枝环糊精功能材料及其包结复合物的制备与基础研究（**），国家自然科学基金项目，2010.1-2012.12，33万元，李斌(主持)

4.过渡金属羧酸盐硼桥聚氧硅烷衍生物的合成其阻燃机理（**），国家自然科学基金项目，2008.1-2010.12，26万元，李斌(主持)

5.大分子三嗪成炭-发泡剂及高效膨胀阻燃剂，黑龙江省科技成果推广项目，2010.1-2012.12，20万元。李斌(主持)

6. 环保无卤阻燃材料的技术开发与产业化（2009GJB20013），科技部科技人员服务企业专项，2009-2011，50万元，李斌(主持)

7. 核电站用1E级电缆研制与开发（GA09A201），黑龙江省重大攻关项目，2009-2011，100万元，李斌(第三主持人，经费20万元)

8. 膨胀性低烟无卤阻燃护套电缆材料的研制与开（2007BAE27B02），科技部十一五科技支撑计划，2007.10-2010.8，274万，李斌(主持)

9. 替代含溴阻燃材料的系列产品开发及产业化(子课题：成炭剂合成与阻燃聚丙烯)（2006BAE03B05），科技部十一五科技支撑计划，2006.10-2009.12，45万，李斌(主持)

10. 高效成炭发泡剂及膨胀阻燃剂，佳木斯沃尔德电缆有限公司，2007.1-2009.12，60万元，李斌(主持)

11. 高效膨胀阻燃聚乙烯树脂产业化，江苏安格特新材料科技有限公司，2009.10-2012.10，30万元，李斌(主持)

12. 无卤膨胀阻燃聚丙烯母粒制备技术，黑龙江省润特科技有限公司，2013.5-2014.9,50万元，李斌（主持）

主要学术论文（近五年）

1.Lili Wang,Bin Li*, Chunxia Chen, Lina Jia. Structural characterization and related properties of the stearate anionsintercalated Ni–Al hydrotalcite-like compound prepared by the microwave crystallization, Journal of Alloys and Compounds, 2010, 508: 426–432.

2.Huanfeng Wang and Bin Li*.Synergistic effects of b-cyclodextrin containing silicone oligomer on intumescent flame retardant polypropylene system., Polym. Adv. Technol,2010, 21 691–697.

3.Jinfeng Dai, Bin Li*. Synthesis, Thermal Degradation, and Flame Retardance of Novel Triazine Ring-Containing Macromolecules for Intumescent Flame Retardant Polypropylene, Journal of Applied Polymer Science, 2010,116: 2157–2165.

4.Peng Bai, Bin Li*, Suliang Gao, Mo Lin, Mi Wang. Investigation on Flame Retardancy and Antidripping of New Intumescent Flame Retardant Polypropylene Film, Polymers & polymer composites,2010,18:469-476.

5.Lili Wang, Bin Li*, Mingfei Yang, Chunxia Chen, Yongsheng Liu. Effect of Ni cations and microwave hydrothermal treatment on the related properties of layered double hydroxide–ethylene vinyl acetate copolymer composites, Journal of Colloid and Interface Science, 2011，356，519–525.

6.Shengqiang Zhang, Bin Li*, Mo Lin, Qifei Li, Suliang Gao, Wei Yi. Effect of a Novel Phosphorus-Containing Compound on the Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Polypropylene, Journal of Applied Polymer Science, 2011, 122, 3430–3439.

7.Mo Lin, Bin Li*, Qifei Li, Sheng Li, Shengqiang Zhang. Synergistic Effect of Metal Oxides on the Flame Retardancy and Thermal Degradation of Novel Intumescent Flame-Retardant Thermoplastic Polyurethanes, Journal of Applied Polymer Science, 2011, 121, 1951–1960.

8.Fengxia Li, Xiaoli Li, Bin Li*. Preparation of magnetic polylactic acid microspheres and investigation of its releasing property for loading curcumin, Journal of Magnetism and Magnetic Materials, 2011, 323, 2770–2775.

9.Sheng Li,Bin Li*. Effect of Elastomer on Flame Retardancy, Thermal Degradation, and Mechanical Properties of Intumescent Flame-Retardant Polyethylene, Journal of Elastomers and Plastics, 2011, 43, 257-272.

10.Lihua Guo,Bin Li*, Huanfeng Wang. Effect of Maleic Anhydride/Vinyltrimethoxysilaneco- Grafting Polypropylene on the Propertiesof Wood-Flour/Polypropylene Composites by Electron-Beam Preirradiation, Journal of Applied Polymer Science, 2011, 121, 402–409.

11.Ting Wang,Bin Li*, Hongyan Si, Li Lin, Li Chen. Release characteristics and antibacterial activity of solid state eugenol/b-cyclodextrin inclusion complex, J Incl Phenom Macrocycl Chem. 2011, 71:207–213.

12.Ting Wang, Bin Li*, Yanchun Feng, Qingqi Guo. Preparation, quantitive analysis and bacteriostasis of solid state iodine inclusion complex with b-cyclodextrin, J Incl Phenom Macrocycl Chem, 2011, 69: 255–262.

13.Suliang Gao, Bin Li*, Peng Bai, Shengqiang Zhang. Effect of polysiloxane and silane-modified SiO2 on a novel intumescent flame retardant polypropylene system, Polym. Adv. Technol, 2011, 22: 2609–2616.

14.Mi Wang, Bin Li*, Jing Wang, Peng Bai. Preparation and properties of polysiloxane grafting multi-walled carbon nanotubes/ polycarbonate nanocomposites, Polym. Adv. Technol,2011, 22: 1738–1746.

15.Ting Wang, Bin Li* Hongyan Si and Li Lin. Investigation on surface activity of cyclodextrins grafting cellulose beads through phenolphthalein probe molecule, Surf. Interface Anal, 2011, 43, 1532–1538.

16.Jinsong Peng, Tonghui Chen, Chunxia Chen, and Bin Li*. Palladium-Catalyzed Intramolecular C?H Activation/C?C Bond Formation: A Straightforward Synthesis of Phenanthridines, J. Org. Chem. 2011, 76, 9507?9513.

17.Lili Wang, Bin Li*, Xiucheng Zhang, Chunxia Chen, Feng Zhang. Effect of intercalated anions on the performance of Ni–Al LDH nanofiller of ethylene vinyl acetate composites. Applied Clay Science, 2012, 56:110-119.

18.Ligang Chen and Bin Li*.Application of magnetic molecularly imprinted polymers in analytical chemistry. Analytical Methods, 2012, 4:2613-2621.

19.Chunxia Chen, Rong Xu and Bin Li*. Controlled/living ring-opening polymerization of ε-caprolactone catalyzed by phosphoric acid. Science China Chemistry, 2012, 55(7):1257-1262.

20.Ligang Chen, Bin Li*. Determination of imidacloprid in rice by molecularly imprinted-matrix solid-phase dispersion with liquid chromatography tandem mass spectrometry. Journal of Chromatography B,2012, 897:32-36.

21.Lili Wang, Bin Li*, Xiaohong Zhao, Chunxia Chen, Jingjing Cao. Effect of Rare Earth Ions on the Properties of Composites Composed of Ethylene Vinyl Acetate Copolymer and Layered Double Hydroxides. PLoS ONE,2012, 7(6):1-11.

22.Chunxia Chen, Chen Chen, Bin Li*.Jingwei Tao and Jinsong Peng. Aqueous Synthesis of 1-H-2-Substituted Benzimidazoles via Transition-Metal-Free Intramolecular Amination Process of Aryl iodides. Molecules,2012, 17:12506-12520.

23.Xiaoli Li, Zhiguo Li, Yingqi Jing, Baichun Bing, Bin Li*. Fluorescent organic nanoparticles self-assembled from hexa[p-(carbonyl glycin methyl ester) phenoxy] cyclotriphosphazene in solution.Journal of Colloid and Interface Science,2012, 375:41-49.

24.Xiaoli Li, Bin Li*, Zhiguo Li and Shiyao Zhang. Self-assembly of nanoparticles from cyclotriphosphazenes grafted with hexa-[p-(carbonyl tryptophan ethyl ester) phenoxy)] group. RSC Advances,2012, 2:5997-6004.

25.Wei Zhao, Bin Li*, Miaojun Xu. Effect of Phosphorus Compounds on Flame Retardancy and Thermal Degradation of Polycarbonate and Acrylonitrile Butadiene Styrene.Journal of Macromolecular Science, Part B: Physics,2012, 51:2141–2156.

26.Wei Zhao, Bin Li*, Miaojun Xu, Lili Zhang, Fangmeng Liu, Limin Guan. Synthesis of a Novel Flame Retardant Containing Phosphorus and Sulfur and Its Application in Polycarbonate. Polymer Engineering and Science, 2012, 52(11):2327-2335.

27.Wei Zhao, Bin Li*, Miaojun Xu, Fangmeng Liu, Limin Guan. Synthesis of a Phenylene Phenyl Phosphine Oligomer and Its Flame Retardancy for Polycarbonate. Journal of Applied Polymer Science, 2012, 127(4):2855-2866.

28.Lina Jia, Bin Li*, Baoli Shi, Hongjie Zhang, Yongqiang Lan, Xin Zhang, Yue Wang and Lili Wang. Quantitative Analysis of Interfacial Tension Effect on the Impact Strength of Organic Flame Retardants and ABS Blends. Journal of Applied Polymer Science, 2012, 124:1815-1823.

29.Qifei Li, Bin Li*, Shengqiang Zhang, Mo Lin. Investigation on effects of aluminum and magnesium hypophosphites on flame retardancy and thermal degradation of polyamide 6. Journal of Applied Polymer Science, 2012, 125:1782-1789.

30.Wei Zhao, Bin Li*, Miaojun Xu, Kun Yang and Li Lin. Novel intumescent flame retardants: synthesis and application in polycarbonate. Fire and Materials,2013, 37(7): 530-546.

31.Jinsong Peng,Guoning Shang,Chunxia Chen,Zhongshuo Miao and Bin Li*. Nucleophilic Addition of Benzimidazoles to Alkynyl Bromides/Palladium-Catalyzed Intramolecular C–H Vinylation: Synthesis of Benzo[4,5]imidazo[2,1-a]isoquinolines. J. Org. Chem.,2013,78(3): 1242–1248.

32.Rongjun Song, Yao Fu, Bin Li*. Transferring Noncharring Polyolefins to Charring Polymers with the Presence of Mo/Mg/Ni/O Catalysts and the Application in Flame Retardancy.J. APPL. POLYM. SCI.2013, DOI: 10.1002/APP.38717.

33.Kun Yang, Miao-Jun Xu, Bin Li* Synthesis of N-ethyl triazineepiperazine copolymer and flame retardancy and water resistance of intumescent flame retardant polypropylene. Polymer Degradation and Stability,2013, 98: 1397-1406.

34.Lili Wang, Bin Li*, Zhongqin Hu, Jingjing Cao. Effect of nickel on the properties of composites composed of layered double hydroxides and ethylene vinyl acetate copolymer. Applied Clay Science, 2013,72:138–146.

35. Hongyan Si, Bin Li*, Ting Wang, Li Lin, Zuwei Xu. Preparation of cyclodextrin grafting wood flour and investigation of the release characteristics of eugenol. Wood Sci Technol, 2013, 47: 601–613.

36. Ting Wang, Bin Li*, Li Lin. Preparation, Characterization, and Bacteriostasis of AgNP-Coated β-CD Grafting Cellulose Beads. Appl Biochem Biotechnol, 2013,169:1811–1821.

37. Ligang Chen, Bin Li*. Magnetic molecularly imprinted polymer extraction of chloramphenicol from honey. Food Chemistry, 2013,141:23-28.

38. Yuansheng Zang, Bin Li*, Miaojun Xu. Flame Retardancy and Water Resistance of Novel Intumescent Flame-Retardant Oil-Filled Styrene–Ethylene–Butadiene–Styrene Block Copolymer/Polypropylene Composites. Journal of Applied Polymer Science, 2014, DOI: 10.1002/APP.39575

39. Miaojun Xu, Wei Zhao, Bin Li*, Kun Yang and Li Lin. Synthesis of a phosphorus and sulfur-containing aromatic diamine curing agent and its application in flame retarded epoxy resins. Fire and Materials, 2014, DOI: 10.1002/fam.2252

40. Miaojun Xu, Wei Zhao, Bin Li*. Synthesis of a Novel Curing Agent Containing Organophosphorus and Its Application in Flame Retarded Epoxy Resins. Journal of Applied Polymer Science, 2014, DOI: 10.1002/APP.41159

论著与教材

1. 李楠、廖容苏，李斌主编，有机化学，中国农业大学出版社，2010.8, ISBN978-7-81117-920-0.

2. 于文杰 李杰 郑德等编著，李斌等参编，塑料助剂与配方设计技术，化学工业出版社，2010.7 ISBN 978-7-122-08270-1.

获奖成果

1. 2009年度“高性能磷氮阻燃剂制备与阻燃玻璃纤维增强尼龙66新材料”黑龙江省科技进步二等奖，排名第一。

2. 2007年度“无机纳米材料在木材科学中的应用基础”获教育部自然科学二等奖，排名第六.

3、2014年度“聚合物无卤阻燃与表界面协效基础研究”获黑龙江省自然科学一等奖，排名第一。

发明专利：（近五年）

1.李斌，戴进峰，李艳涛，张秀成.三嗪系齐聚物及其合成方法，国家发明专利，ZL**7.4，(2009年授权)。

2. 李斌，高苏亮，戴进峰.改性聚磷酸铵方法，国家发明专利，**2.X，(2011年授权)。

3. 李斌,白鹏.无卤膨胀阻燃聚丙烯薄膜,中国发明专利，**3.7 (2011年授权)。

4. 李斌，李胜.无卤膨胀阻燃复合材料，国家发明专利，**76.0

5. 李斌，苗越卓，宋荣君.含羧基微孔纳米硅氧烷固体颗粒的制备方法,中国发明专利，**72

6. 李斌，杨坤.三嗪成炭-发泡剂、其合成方法以及其为原料制成的阻燃聚合物复合材料,中国发明专利，**8X