哈尔滨师范大学化学化工学院
  教  师  情  况  简  介
姓   名
   
朱广山
   
系别
   
化学系
     
出生日期
   
1971-02-01
   
性别
   
男
专   业
   

  无机化学
研究方向
   

  功能无机孔材料的合成与组装
职   称
   
教授
   
任职时间
   
2001-10
行政职务
   

暂无
   
担任时间
   
 
办公电话
   

 0431-85168887

 传   真
     
电子信箱
   

  zhugs@mail.jlu.edu.cn


  个 人 履 历 及 学 习 经 历
 

1989－－1993            吉林大学化学系 无机化学专业  学士
1993－－1998            吉林大学化学系 无机化学专业  博士
1997.04                     日本东北大学物理系  访问学者
1999.03-1999.04        德国西门子公司  访问学者
1999.09-2000.09        日本东北大学物理系  博士后
2000.09-2001.09        吉林大学   副教授
2001.10-现在             吉林大学   教授
2003.10-现在             吉林大学  博士生导师
 

 

  科 研 方 向 及 研 究 成 果

 

研究方向：

一、不同凝聚态分子筛孔材料的合成、制备与功能研究
分子筛孔材料是具有规则孔道或笼无机非金属材料。本研究主要通过选择反应原料、调整反应配比、优化反应条件和使用新颖的合成技术进行不同凝聚态分子筛孔材料的合成、制备与功能组装。同时研究分子筛孔材料生长机理、光电磁性质、气体或有机分子分离性质和催化性能等。
1.分子筛纳米晶的合成。分子筛纳米晶的合成与制备对晶体表面科学、生长机理，催化，制备反应膜等具有重要的作用。
2.分子筛大单晶的合成与组装及性能研究。高质量分子筛大单晶的合成对材料晶体结构、晶体生长机理、纳米复合材料、主客体材料、光电磁微器件研究方面有重要意义。
3.分子筛有序膜的合成与制备及性能研究。分子筛膜因其规则的微孔结构和良好的化学稳定性，使其在工业分离与催化领域有着广泛的应用背景。
二、新型金属有机刚性骨架（MOF）结构的设计合成与制备化学
本研究利用刚性带有多节点羧基或胺基的环状、链状、枝状和手性配体为有机构筑基元，过渡金属离子或金属氧簇为无机构筑单元，合成具有特殊孔道，大孔道或手性孔道，高孔体积的金属有机刚性骨架纳米孔材料，并对其热稳定性、储氢、分子识别等性质进行系统的研究。包括：
1.大孔径金属有机骨架新材料开发。这一研究是近年无机材料化学研究的一个全新热点领域。由于特殊的骨架特征以及开阔的孔道结构而表现出优异的吸附性能，是理想的储氢材料。
2.具有手性孔道的金属有机骨架结构的设计合成。

承担项目：
 
1      功能无机孔材料的合成与制备 国家自然科学基金杰出青年基金  朱广山  2007-2010  200.00万
2      高机械强度大面积有序分子筛膜的制备与性质研究 国家自然科学基金  朱广山 2006-2008 30.00万
3      高质量巨大分子筛单晶合成、组装与性质研究 国家自然科学基金  朱广山 2002-2004  16.00万
4      以分子筛为主体的光学微器件的制备与性质研究 国家自然科学基金  朱广山 2003-2005  28.00万
5      分子筛大单晶的制备 教育部优秀留学回国基金   朱广山  2001-2002    4.00万
6      教育部新世纪优秀人才计划     教育部 朱广山 2005-2007 6.00万
7      无机纳米孔膜的制备与气体分离 吉林省科技发展计划 朱广山 2006-2008 20.00万
8      先进无机储氢材料的设计、制备与性质研究  吉林省杰出青年科技基金 朱广山    2005-2007 10.00万
9      物质创造与化学转化过程中的若干前沿科学问题研究 国家重点基础研究发展计划（973）    裘式纶    2006-2011  660.00万
10    创造新物质的分子工程学研究 国家重点基础研究发展计划（973） 裘式纶  2006-2011  350.00万

 

  教 学 工 作 及 教 研 成 果

 

获奖：
1        含杂原子分子筛与层状材料的基础研究  吉林省科技进步奖  一等 2002 6
2        教育部新世纪优秀人才  教育部  2004  
3        吉林省杰出人才 2005  
4        纳米孔道材料的合成、组装与性质研究  吉林省科技进步奖   一等 2006 2

研究成果：

 
 
2006
1. Zheng, L. Y.; Zhang, S. Q.; Zhao, L. F.; Zhu, G. S.; Yang, X. Y.; Gao, G.; Cao, S. G., Resolution of N-(2-ethyl-6-methylphenyl)alanine via free and immobilized lipase from Pseudomonas cepacia. Journal of Molecular Catalysis B-Enzymatic 2006, 38, (3-6), 119-125.
2. Zhao, L.; Zhu, G. S.; Zhang, D. L.; Di, Y.; Qiu, S. L., Synthesis and characterization of mesoporous silica marterial with partly-ordered pore walls. Chemical Journal of Chinese Universities-Chinese 2006, 27, (2), 208-211.
3. Zhang, Z. D.; Yan, X. X.; Tian, B. Z.; Yu, C. Z.; Tu, B.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Synthesis of ordered small pore mesoporous silicates with tailorable pore structures and sizes by polyoxyethylene alkyl amine surfactant. Microporous and Mesoporous Materials 2006, 90, (1-3), 23-31.
4. Xue, M.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Qiu, S. L., Design, structure and properties of a novel 3D metal-organic framework constructed from N-donor ligand supporting Cd(II)-carboxylate layer. Inorganic Chemistry Communications 2006, 9, (6), 603-606.
5. Xue, M.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Qiu, S. L., Solvothermal synthesis, structure and magnetism of two novel 3D metal-organic frameworks based on infinite helical Mn-O-C rod-shaped building units. Journal of Molecular Structure 2006, 796, (1-3), 165-171.
6. Xu, R.; Zhu, G. S.; Yin, X. J.; Wan, X.; Qiu, S. L., In situ growth of AlPO4-5 molecular sieve on stainless steel support. Microporous and Mesoporous Materials 2006, 90, (1-3), 39-44.
7. Xu, R.; Zhu, G. S.; Yin, X. J.; Wan, X.; Qiu, S. L., Epitaxial growth of highly-oriented AlPO4-5 molecular sieve films for microlaser systems. Journal of Materials Chemistry 2006, 16, (22), 2200-2204.
8. Wang, C. Y.; Zhu, G. S.; Gao, B.; Wang, R. W.; Li, J.; Xin, M. H.; Qiu, S. L., In-situ synthesis and activity of nano-hydroxyapatite/lysozyme composite. Chemical Journal of Chinese Universities-Chinese 2006, 27, (8), 1421-1423.
9. Tian, G.; Zhu, G. S.; Fang, Q. R.; Xin, M. H.; Guo, X. D.; Xue, M.; Qiu, S. L., Synthesis, structure of a novel two-dimensional inorganic-organic framework Ni(PDC) (H2O)(2) with double helical chains. Chemical Journal of Chinese Universities-Chinese 2006, 27, (6), 1020-1022.
10. Tian, G.; Zhu, G. S.; Fang, Q. R.; Guo, X. D.; Xue, M.; Sun, J. Y.; Qiu, S. L., Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,4 '-bipyridine. Journal of Molecular Structure 2006, 787, (1-3), 45-49.
11. Sun, J. Y.; Zhou, Y. M.; Fang, Q. R.; Chen, Z. X.; Weng, L. H.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Construction of 3D layer-pillared homoligand coordination polymers from a 2D layered precursor. Inorganic Chemistry 2006, 45, (21), 8677-8684.
12. Sun, J. Y.; Zhou, Y. M.; Chen, Z. X.; Zhu, G. S.; Fang, Q. R.; Yang, R. J.; Qiu, S. L.; Zhao, D. Y., Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3)with a rare (10,3)-d net. Journal of Solid State Chemistry 2006, 179, (4), 1230-1236.
13. Sun, F. X.; Zhu, G. S.; Ye, L.; Fang, Q. R.; Qiu, S. L., Synthesis and crystal structure of a 3D metal-organic framework microporous compound Cd-5 (BTC)(4)(H2O)(8) center dot 6H(2)O. Chemical Journal of Chinese Universities-Chinese 2006, 27, (8), 1418-1420.
14. Shi, C. F.; Wang, R. W.; Zhu, G. S.; Qiu, S. L.; Long, J., In situ synthesis, characterization of SiPMo-X, and different catalytic properties of SiPMo-X and SiPW-X. European Journal of Inorganic Chemistry 2006, (15), 3054-3060.
15. Shi, C. F.; Wan, L. F.; Wang, R. W.; Long, J.; Zhu, G. S.; Qiu, S. L., Synthesis and characterization of a new HPMo/SBA-15 composite. Chemical Journal of Chinese Universities-Chinese 2006, 27, (7), 1194-1197.
16. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Zhang, W. W.; Sun, J. Y.; Li, S. G.; Qiu, S. L., A controlled release of ibuprofen by systematically tailoring the morphology of mesoporous silica materials. Journal of Solid State Chemistry 2006, 179, (7), 2027-2035.
17. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Zhang, W. W.; Li, S. G.; Qiu, S. L., Synthesis of mesoporous silica with spiral morphology by using chiral anionic surfactant. Chemical Journal of Chinese Universities-Chinese 2006, 27, (4), 602-604.
18. Qu, F. Y.; Zhu, G. S.; Lin, H. M.; Sun, J. Y.; Zhang, D. L.; Li, S. G.; Qiu, S. L., Drug self-templated synthesis of ibuprofen/mesoporous silica for sustained release. European Journal of Inorganic Chemistry 2006, (19), 3943-3947.
19. Qu, F. Y.; Zhu, G. S.; Huang, S. Y.; Li, S. G.; Sun, J. Y.; Zhang, D. L.; Qiu, S. L., Controlled release of Captopril by regulating the pore size and morphology of ordered mesoporous silica. Microporous and Mesoporous Materials 2006, 92, (1-3), 1-9.
20. Qu, F. Y.; Zhu, G. S.; Huang, S. Y.; Li, S. G.; Qiu, S. L., Effective controlled release of captopril by silylation of mesoporous MCM-41. Chemphyschem 2006, 7, (2), 400-406.
21. Li, H.; Zhu, G. S.; Guo, X. D.; Sun, F. X.; Ren, H.; Chen, Y.; Qiu, S. L., Synthesis, structure, and magnetism of a highly thermally stable microporous metal organodiphosphonate with reversible dehydration/rehydration behavior. European Journal of Inorganic Chemistry 2006, (20), 4123-4128.
22. Guo, Z.; Zhu, G. S.; Xin, M. H.; Gao, B.; Qiu, S. L., Adsorption behavior of VB12 on mesoporous carbon molecular sieves with different pore diameters. Chemical Journal of Chinese Universities-Chinese 2006, 27, (1), 9-12.
23. Guo, X. D.; Zhu, G. S.; Sun, F. X.; Li, Z. Y.; Zhao, X. J.; Li, X. T.; Wang, H. C.; Qiu, S. L., Synthesis, structure, and luminescent properties of microporous lanthanide metal-organic frameworks with inorganic rod-shaped building units. Inorganic Chemistry 2006, 45, (6), 2581-2587.
24. Guo, X. D.; Zhu, G. S.; Li, Z. Y.; Sun, F. X.; Yang, Z. H.; Qiu, S. L., A lanthanide metal-organic framework with high thermal stability and available Lewis-acid metal sites. Chemical Communications 2006, (30), 3172-3174.
25. Guo, X. D.; Zhu, G. S.; Li, Z. Y.; Chen, Y.; Li, X. T.; Qiu, S. L., Rare earth coordination polymers with zeolite topology constructed from 4-connected building units. Inorganic Chemistry 2006, 45, (10), 4065-4070.
26. Guo, H. L.; Zhu, G. S.; Li, H.; Zou, X. Q.; Yin, X. J.; Yang, W. S.; Qiu, S. L.; Xu, R., Hierarchical growth of large-scale ordered zeolite silicalite-1 membranes with high permeability and selectivity for recycling CO2. Angewandte Chemie-International Edition 2006, 45, (42), 7053-7056.
27. Gao, B.; Zhu, G. S.; Fu, X. Q.; Teng, L. R.; Chen, J.; Wang, C. Y.; Qiu, S. L., Modification of mesoporous material and stability of immobilization of penicillin G acylase. Chemical Journal of Chinese Universities-Chinese 2006, 27, (10), 1823-1826.
28. Fang, Q. R.; Zhu, G. S.; Xue, M.; Zhang, Q. L.; Sun, J. Y.; Guo, X. D.; Qiu, S. L.; Xu, S. T.; Wang, P.; Wang, D. J.; Wei, Y., Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units. Chemistry-a European Journal 2006, 12, (14), 3754-3758.
29. Fang, Q. R.; Zhu, G. S.; Xue, M.; Sun, J. Y.; Sun, F. X.; Qiu, S. L., Structure, luminescence, and adsorption properties of two chiral microporous metal-organic frameworks. Inorganic Chemistry 2006, 45, (9), 3582-3587.
30. Fang, Q. R.; Zhu, G. S.; Xue, M.; Sun, J. Y.; Qiu, S. L., Porous coordination polymers with zeolite topologies constructed from 4-connected building units. Dalton Transactions 2006, (20), 2399-2402.
31. Fang, Q. R.; Zhu, G. S.; Jin, Z.; Xue, M.; Wei, X.; Wang, D. J.; Qiu, S. L., A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters. Angewandte Chemie-International Edition 2006, 45, (37), 6126-6130.
32. Chen, Y.; Li, X. T.; Guli, M. N.; Zhao, L.; Zhu, G. S.; Qiu, S. L., Photoluminescence property of meso-structure silica film doped with laser dye by solvent evaporation method. Chemical Journal of Chinese Universities-Chinese 2006, 27, (9), 1618-1620.
33. Chen, Y.; Li, X. T.; Guli, M. N.; Li, N.; Zhu, G. S.; Qiu, S. L., Optical properties of mesoporous MCM-41 powders and fibers doped with laser dye coumarin 151. Chemical Journal of Chinese Universities-Chinese 2006, 27, (3), 397-400.
34. Cai, X. H.; Zhu, G. S.; Xin, M. H.; Wang, C. L.; Zhang, D. L.; Wei, Y. H.; Zhang, W. W.; Qiu, S. L.; Wang, C., Studies on removing template from mesoporous materials by oxidation treatment. Chemical Journal of Chinese Universities-Chinese 2006, 27, (7), 1214-1216.
35. Cai, X. H.; Zhu, G. S.; Gao, B.; Zhang, W. W.; Zhang, D. L.; Wei, Y. H.; Qiu, S. L.; Wang, C., Preparation of Ag/SBA-15 nanocomposite and its bactericidal activity. Chemical Journal of Chinese Universities-Chinese 2006, 27, (11), 2042-2044.
36. Cai, X.; Zhu, G. S.; Zhang, W. W.; Zhao, H. Y.; Wang, C.; Qiu, S. L.; Wei, Y., Diatom-templated synthesis of ordered meso/macroporous hierarchical materials. European Journal of Inorganic Chemistry 2006, (18), 3641-3645.

2005
1. Zhao, L.; Zhu, G. S.; Zhang, D. L.; Di, Y.; Chen, Y.; Terasaki, O.; Qiu, S. L., Synthesis and structural identification of a highly ordered mesoporous organosilica with large cagelike pores. Journal of Physical Chemistry B 2005, 109, (2), 764-768.
2. Zhao, L.; Zhu, G. S.; Zhang, D. L.; Chen, Y.; Qiu, S. L., A surface modification scheme for incorporation of nanocrystals in mesoporous silica matrix. Journal of Solid State Chemistry 2005, 178, (10), 2980-2986.
3. Zhang, Z. D.; Yan, X. X.; Tian, B. Z.; Shen, S. D.; Chen, D. H.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Synthesis of large-pore periodic mesoporous organosilica (PMO) with bicontinuous cubic structure of Ia-3d symmetry. Chemistry Letters 2005, 34, (2), 182-183.
4. Zhang, Z. D.; Yan, X. X.; Tian, B. Z.; Shen, S. D.; Chen, D. H.; Fang, Q. R.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y., Synthesis of highly ordered large-pore mesoporous organosilicas by non-aqueous solvent evaporation method. Chemical Journal of Chinese Universities-Chinese 2005, 26, (4), 603-606.
5. Yin, X. J.; Zhu, G. S.; Yang, W. S.; Li, Y. S.; Zhu, G. Q.; Xu, R.; Sun, J. Y.; Qiu, S. L.; Xu, R. R., Stainless-steel-net-supported zeolite NaA membrane with high permeance and high permselectivity for oxygen over nitrogen. Advanced Materials 2005, 17, (16), 2006-+.
6. Xue, M.; Zhu, G. S.; Wang, L. F.; Fang, Q. R.; Sun, J. Y.; Sun, F. X.; Guo, X. D.; Zhao, X. J.; Tian, G.; Qiu, S. L., Synthesis and structure of a novel metal-organic polymer Mn-3(BTC)(2)(H2O)(9)center dot(H2O). Chemical Journal of Chinese Universities-Chinese 2005, 26, (12), 2211-2213.
7. Xu, L.; Zhu, G. S.; Chu, B.; Shi, C. F.; Gan, M. N.; Xie, Y. R.; Shen, Q. H.; Wang, R. W.; Qiu, S. L., Synthesis and characterization of a new type of mesoporous SAPO. Chemical Journal of Chinese Universities-Chinese 2005, 26, (9), 1585-1588.
8. Xin, M. H.; Wang, Y.; Zhu, G. S.; Sun, J. Y.; Xue, M.; Sun, F. X.; Fang, Q. R.; Tian, G.; Qiu, S. L., Hydrothermal synthesis and structure characterization of diamine-templated two-dimenisional cerium sulfate, [C6N2H14][Ce(SO4)(2)(H2O)(2)]center dot 0.5SO(4)center dot 2.5H(2)O. Chemical Research in Chinese Universities 2005, 21, (5), 619-621.
9. Xin, M. H.; Wang, Y.; Zhu, G. S.; Sun, J. Y.; Xue, M.; Sun, F. X.; Fang, Q. R.; Tian, G.; Guo, X. D.; Qiu, S. L., Hydrothermal synthesis and structure characterization of an acidic cerium sulfate hydrate, H3O[Ce(SO4)(2)(H2O)(3)]H2O. Chemical Journal of Chinese Universities-Chinese 2005, 26, (11), 2007-2009.
10. Wang, R. W.; Xu, L.; Zhao, L.; Chu, B.; Hu, L.; Shi, C. F.; Zhu, G. S.; Qiu, S. L., Synthesis, characterization, and catalytic activities of mesostructured aluminophosphates assembled with preformed MFI zeolite nanoclusters. Microporous and Mesoporous Materials 2005, 83, (1-3), 136-144.
11. Wang, R. W.; Hu, L.; Chu, B.; Zhao, L.; Zhu, G. S.; Qiu, S. L., Synthesis, characterization, and catalytic activities of mesostructured titanosilicates assembled from quaternary alkylammonium with preformed titanosilicate precursors under alkaline and acidic conditions. Catalysis Communications 2005, 6, (7), 485-490.
12. Wang, C. L.; Zhu, G. S.; Shang, T. C.; Cai, X. H.; Liu, C. Z.; Li, N.; Wei, Y. H.; Li, J.; Zhang, W. W.; Qiu, S. L., Ordered hexagonal mesoporous aluminosilicates synthesized using zeolite as precursor and the wall-thickness tuned by pH control. Solid State Communications 2005, 135, (4), 257-259.
13. Wang, C. L.; Zhu, G. S.; Li, J.; Cai, X. H.; Wei, Y. H.; Zhang, D. L.; Qiu, S. L., Rigid nanoscopic containers for highly dispersed, stable metal and bimetal nanoparticles with both size and site control. Chemistry-a European Journal 2005, 11, (17), 4975-4982.
14. Wang, C. L.; Zhu, G. S.; Cai, X. H.; Shang, T. C.; Zhao, L.; Li, N.; Wang, R. W.; Wei, Y. H.; Li, J.; Qiu, S. L., Synthesis of higher aluminum content hexagonal and cubic mesoporous aluminosilicates toward catalysts. Topics in Catalysis 2005, 35, (1-2), 25-34.
15. Tian, G.; Zhu, G. S.; Yang, X. Y.; Fang, Q. R.; Xue, M.; Sun, J. Y.; Wei, Y.; Qiu, S. L., A chiral layered Co(II) coordination polymer with helical chains from achiral materials. Chemical Communications 2005, (11), 1396-1398.
16. Sun, J.; Zhu, G. S.; Yin, X. J.; Chen, Y.; Cui, Y. J.; Qiu, S. L., Preparation of an ordered zeolite MFI film by epitaxial growth. Chemical Communications 2005, (8), 1070-1072.
17. Shi, X.; Zhu, G. S.; Wang, X. H.; Li, G. H.; Fang, Q. R.; Zhao, X. J.; Wu, G.; Tian, G.; Xue, M.; Wang, R. W.; Qiu, S. L., Polymeric frameworks constructed from a metal-organic coordination compound, in 1-D and 2-D systems: Synthesis, crystal structures, and fluorescent properties. Crystal Growth & Design 2005, 5, (1), 341-346.
18. Shi, X.; Zhu, G. S.; Wang, X. H.; Li, G. H.; Fang, Q. R.; Wu, G.; Ge, T.; Xue, M.; Zhao, X. J.; Wang, R. W.; Qiu, S. L., From a 1-D chain, 2-D layered network to a 3-D supramolecular framework constructed from a metal-organic coordination compound. Crystal Growth & Design 2005, 5, (1), 207-213.
19. Shi, C. F.; Xin, M. H.; Wang, R. W.; Xie, Y. R.; Hu, L.; Xu, L.; Zhang, R. M.; Zhu, G. S.; Qiu, S. L., Synthesis and characterization of a new mesoporous HPW/SiO2 composite material. Chemical Journal of Chinese Universities-Chinese 2005, 26, (7), 1198-1201.
20. Shi, C. F.; Wang, R. W.; Zhu, G. S.; Qiu, S. L.; Long, J., Synthesis, characterization, and catalytic properties of SiPW-X mesoporous silica with heteropolyacid encapsulated into their framework. European Journal of Inorganic Chemistry 2005, (23), 4801-4807.
21. Li, N.; Li, X. T.; Geng, W. C.; Zhao, L.; Zhu, G. S.; Wang, R. W.; Qiu, S. L., Template synthesis of boron nitride nanotubes in mesoporous silica SBA-15. Materials Letters 2005, 59, (8-9), 925-928.
22. Li, H.; Zhu, G. S.; Guo, X. D.; Li, Y.; Li, C. J.; Qiu, S. L., In situ synthesis of aluminophosphate microporous molecular sieve 8-hydroxyquinoline-AlPO4-5 with blue-emitting luminescence property. Microporous and Mesoporous Materials 2005, 85, (3), 324-330.
23. Guo, Z.; Zhu, G. S.; Xin, M. H.; Liu, C. Z.; Qiu, S. L., Synthesis and fluorescence properties of fulleride encapsulated in mesoporous SBA-15 host. Chemical Journal of Chinese Universities-Chinese 2005, 26, (10), 1917-1920.
24. Guo, Z.; Zhu, G. S.; Gao, B.; Zhang, D. L.; Tian, G.; Chen, Y.; Zhang, W. W.; Qiu, S. L., Adsorption of vitamin B12 on ordered mesoporous carbons coated with PMMA. Carbon 2005, 43, (11), 2344-2351.
25. Guo, X. D.; Zhu, G. S.; Fang, Q. R.; Xue, M.; Tian, G.; Sun, J. Y.; Li, X. T.; Qiu, S. L., Synthesis, structure and luminescent properties of rare earth coordination polymers constructed from paddle-wheel building blocks. Inorganic Chemistry 2005, 44, (11), 3850-3855.
26. Gao, B.; Zhu, G. S.; Fu, X.; Xin, M. H.; Chen, J.; Wang, C. L.; Qiu, S. L., Stability of penicillin G acylase immobilized on different silica mesoporous materials. Chemical Journal of Chinese Universities-Chinese 2005, 26, (10), 1852-1854.
27. Fang, Q. R.; Zhu, G. S.; Xue, M.; Sun, J. Y.; Wei, Y.; Qiu, S. L.; Xu, R. R., A metal-organic framework with the zeolite MTN topology containing large cages of volume 2.5 nm(3). Angewandte Chemie-International Edition 2005, 44, (25), 3845-3848.

2004
1. Zhu, G. S.; Wan, C.; Zhang, Y. H.; Guo, N.; Zhao, Y. Y.; Wang, R. W.; Qiu, S. L.; Wei, Y.; Baughman, R. H., highly effective sulfated zirconia nanocatalysts grown out of colloidal silica at high temperature. Chemistry-a European Journal 2004, 10, (19), 4750-4754.
2. Zhang, Z. D.; Tian, B. Z.; Yan, X. X.; Shen, S. D.; Liu, X. Y.; Chen, D. H.; Zhu, G. S.; Zhao, D. Y.; Qiu, S., An easy route for the synthesis of ordered three-dimensional large-pore mesoporous organosilicas with Im-3m symmetry. Chemistry Letters 2004, 33, (9), 1132-1133.
3. Wang, X. H.; Li, W. H.; Zhu, G. S.; Qiu, S. L.; Zhao, D. Y.; Zhong, B., Effects of ammonia/silica molar ratio on the synthesis and structure of bimodal mesopore silica xerogel. Microporous and Mesoporous Materials 2004, 71, (1-3), 87-97.
4. Wang, R. W.; Hu, L.; Chu, B.; Zhu, G. S.; Qiu, S. L., Synthesis, characterization and catalytic properties of mesoporous materials with loading of TS-1 precursors. Chemical Journal of Chinese Universities-Chinese 2004, 25, (8), 1485-1489.
5. Tian, G.; Liu, X. J.; Fang, Q. R.; Zhu, G. S.; Xin, M. H.; Shi, X.; Wu, G.; Qiu, S. L., Synthesis, structure and fluorescence properties of a novel two-dimensional inorganic-organic framework material Zn-3(PTC)(2)(H2O)(8)center dot 4H(2)O. Chemical Journal of Chinese Universities-Chinese 2004, 25, (4), 784-786.
6. Shi, Y. Y.; Wang, X. Q.; Li, X. Q.; Zheng, W. Q.; Ding, H.; Zhu, G. S.; Liu, G. F., Investigation of light-harvest material: Synthesis and characterization of nanometer porphyrin trimer. Chemical Research in Chinese Universities 2004, 20, (3), 262-265.
7. Shi, X.; Zhu, G. S.; Qiu, S. L.; Huang, K. L.; Yu, J. H.; Xu, R. R., Zn-2[(S)-O3PCH2NHC4H7CO2](2): A homochiral 3D zinc phosphonate with helical channels. Angewandte Chemie-International Edition 2004, 43, (47), 6482-6485.
8. Shi, X.; Zhu, G. S.; Fang, Q. R.; Wu, G.; Tian, G.; Wang, R. W.; Zhang, D. L.; Xue, M.; Qiu, S. L., Novel supramolecular frameworks self-assembled from one-dimensional polymeric coordination chains. European Journal of Inorganic Chemistry 2004, (1), 185-191.
9. Shi, S. H.; Wei, Q.; Li, G. H.; Li, W.; Yuan, H. M.; Xu, J. N.; Zhu, G. S.; Song, T. Y.; Qiu, S. L., Building three-dimensional metal phosphites from the corner-shared four-membered rings chain. Journal of Solid State Chemistry 2004, 177, (9), 3038-3044.
10. Shi, S. H.; Wang, L.; Yuan, H. M.; Li, G. H.; Xu, J. N.; Zhu, G. S.; Song, T. Y.; Qiu, S. L., Hydrothermal synthesis and characterization of a new 3D vanadium(III) phosphite (C4H8N2H4)(0.5)(C4H8N2H3)[V-4(HPO3)(7)(H2O)(3)]1.5H(2)O. Journal of Solid State Chemistry 2004, 177, (11), 4183-4187.
11. Shi, S. H.; Li, G. H.; Xin, H. M.; Ding, H.; Xu, J. N.; Zhu, G. S.; Song, T. Y.; Qiu, S. L., Hydrothermal synthesis and structure characterization of C4H8N2H4 center dot Zn(HPO3)(2). Chemical Journal of Chinese Universities-Chinese 2004, 25, (2), 230-232.
12. Qu, F. Y.; Zhu, G. S.; Huang, S. Y.; Li, S. G.; Qiu, S. L., Preparation and sustained release, of a new water-soluble drug carrier system Captopril/Si-MCM-41. Chemical Journal of Chinese Universities-Chinese 2004, 25, (12), 2195-2198.
13. Ohsuna, T.; Slater, B.; Gao, F. F.; Yu, J. H.; Sakamoto, Y.; Zhu, G. S.; Terasaki, O.; Vaughan, D. E. W.; Qiu, S. L.; Catlow, C. R. A., Fine structures of zeolite-linde-L (LTL): Surface structures, growth unit and defects. Chemistry-a European Journal 2004, 10, (20), 5031-5040.
14. Liu, X. J.; Fang, Q. R.; Zhu, G. S.; Xue, M.; Shi, X.; Wu, G.; Tian, G.; Qiu, S. L.; Fang, L., Crystal structure and fluorescence of a novel 3D inorganic-organic hybrid polymer with mixed ligands. Inorganic Chemistry Communications 2004, 7, (1), 31-34.
15. Li, N.; Li, X. T.; Zhang, T.; Qiu, S. L.; Zhu, G. S.; Zheng, W. T.; Yu, W. X., Host-guest composite materials of LiCl/NaY with wide range of humidity sensitivity. Materials Letters 2004, 58, (10), 1535-1539.
16. Leng, S. W.; Wu, G.; Xin, M. H.; Tang, L. L.; Zhu, G. S.; Fan, Y.; Shi, S. H., Synthesis and crystal structure of zinc coordination polymer with ferrocenedicarboxylic acid as ligand. Chemical Journal of Chinese Universities-Chinese 2004, 25, (5), 817-819.
17. Gao, F. F.; Zhu, G. S.; Chen, Y.; Li, Y.; Qiu, S. L., Assembly of p-nitroaniline molecule in the channel of zeolite MFI large single crystal for NLO material. Journal of Physical Chemistry B 2004, 108, (11), 3426-3430.
18. Gao, B.; Chen, J.; Zhu, G. S.; Fu, X. Q.; Wang, C. L.; Qiu, S. L., Immobilization and property of penicillin G acylase in the channel of silica mesoporous material MCFs. Chemical Journal of Chinese Universities-Chinese 2004, 25, (11), 1998-2000.
19. Fang, Q. R.; Zhu, G. S.; Xue, M.; Sun, J. Y.; Tian, G.; Wu, G.; Qiu, S. L., Influence of organic bases on constructing 3D photoluminescent open metal-organic polymeric frameworks. Dalton Transactions 2004, (14), 2202-2207.
20. Fang, Q. R.; Zhu, G. S.; Xin, M. H.; Zhang, D. L.; Shi, X.; Wu, G.; Tian, G.; Tang, L. L.; Xue, M.; Qiu, S. L., Synthesis and crystal structure of a 3D inorganic-organic hybrid compound [Zn-3(BTC)(2)(H2O)(3-)](n) with micropores. Chemical Journal of Chinese Universities-Chinese 2004, 25, (6), 1016-1018.
21. Fang, Q. R.; Zhu, G. S.; Xin, M. H.; Xue, M.; Zhang, Z. J.; Ji, C. Z.; Shi, X.; Wu, G.; Tian, G.; Qiu, S. L., Synthesis and crystal structure of 3D inorganic-organic hybrid framework microporous compound Mn-3 (BTC)(2)(DMF)(4). Chemical Journal of Chinese Universities-Chinese 2004, 25, (8), 1425-1427.
22. Fang, Q. R.; Zhu, G. S.; Shi, X.; Wu, G.; Tian, G.; Wang, R. W.; Qiu, S. L., Synthesis, structure and fluorescence of a novel three-dimensional inorganic-organic hybrid polymer constructed from trimetallic clusters and mixed carboxylate ligands. Journal of Solid State Chemistry 2004, 177, (4-5), 1060-1066.
23. Fang, Q. R.; Zhu, G. S.; Ding, H.; Xue, M.; Xin, M. H.; Wu, G.; Tian, G.; Qiu, S. L., Synthesis and crystal structure characterization of a 3D inorganic-organic hybrid framework microporous compound Mn3(BTC)(2)(bpy) (EG) (DMF) center dot (DMF) center dot 1/3(C2H5OH). Chemical Journal of Chinese Universities-Chinese 2004, 25, (12), 2218-2220.

2003
1. Xin, S.; Fang, Q. R.; Gang, W.; Ge, T. I.; Zhu, G. S.; Ling, Y.; Wang, C. L.; Zhang, Z. D.; Qiu, S. L., Synthesis and characteristics of 2-D inorganic-organic hybrid layered net framework crystals. Acta Chimica Sinica 2003, 61, (6), 863-868.
2. Wu, G.; Shi, X.; Fang, Q. R.; Tian, G.; Wang, L. F.; Zhu, G. S.; Addison, A. W.; Wei, Y.; Qiu, S. L., Triethylammonium benzene-1,3,5-tricarboxylato(pyridine)zinc(II): a two-dimensional undulating mesh network. Inorganic Chemistry Communications 2003, 6, (4), 402-404.
3. Li, Y. F.; Cui, W.; Zhu, G. S.; Qiu, S. L.; Fang, Q. R.; Wang, C. L., Hydrothermal synthesis and characteristic of [C6N2H18](2)[Mo5O15(HPO4)(2)] center dot H2O. Chemical Journal of Chinese Universities-Chinese 2003, 24, (3), 394-397.
4. Gao, B.; Zhu, G. S.; Fu, X. Q.; Xin, M. H.; Qiu, S. L., Immobilization and catalytic property of alpha-chymotrypsin in the channel of silica mesoporous material SBA-15. Chemical Journal of Chinese Universities-Chinese 2003, 24, (6), 1100-1102.
5. Fang, Q. R.; Zhu, G. S.; Shi, X.; Xin, M. H.; Wu, G.; Tian, G.; Ye, L.; Wang, C. L.; Zhang, Z. D.; Qiu, S. L., Synthesis and characteristic of a 3-D inorganic-organic hybrid framework microporous material Cd(HBTC)(EG) center dot 8(H2O). Chemical Journal of Chinese Universities-Chinese 2003, 24, (5), 776-778.
6. Fang, Q. R.; Shi, X.; Xin, M. H.; Wu, G.; Tian, G.; Zhu, G. S.; Li, Y. F.; Ye, L.; Wang, C. L.; Zhang, Z. D.; Tang, L. L.; Qiu, S. L., A 3-D inorganic-organic hybrid framework microporous material - Synthesis and characteristic of [CO3 (BTC) (RBTC) (H2BTC) (C2H4O2)(3)] center dot 3(DMF)-6(H3O). Chemical Journal of Chinese Universities-Chinese 2003, 24, (1), 28-30.
7. Fang, Q. R.; Shi, X.; Xin, M. H.; Wu, G.; Tian, G.; Zhu, G. S.; Li, Y. F.; Ye, L.; Wang, C. L.; Zhang, Z. D.; Tang, L. L.; Qiu, S. L., Synthesis and characteristic of 3-D inorganic-organic hybrid framework microporous material [Co-3(BDC)(3)(EG)(4)] center dot 2DMF. Chemical Journal of Chinese Universities-Chinese 2003, 24, (6), 980-982.
8. Fang, Q. R.; Shi, X.; Wu, G.; Tian, G.; Zhu, G. S.; Wang, R. W.; Qiu, S. L., The synthesis and characterization of a new 3-D inorganic-organic hybrid framework porous material Zn-3(bbdc)(3)(4,4 '-bpy)center dot 2(DMF)center dot 4(H2O). Journal of Solid State Chemistry 2003, 176, (1), 1-4.

2002
1. Song, H. H.; Zheng, L. M.; Zhu, G. S.; Shi, Z.; Feng, S. H.; Gao, S.; Xin, X. Q., Synthesis, structure and properties of a new iron (II) diphosphonate: [NH3(CH2)(5)NH3] [Fe-2{O3PC (CH3) (OH) (PO3H)}(2)] center dot 2H(2)O. Chinese Journal of Inorganic Chemistry 2002, 18, (1), 67-71.
9. Song, H. H.; Zheng, L. M.; Zhu, G. S.; Shi, Z.; Feng, S. H.; Gao, S.; Hu, Z.; Xin, X. Q., Structures and magnetic properties of iron diphosphonates: [NH3(CH2)(2)NH3][Fe-II{HO3PC(CH3)(OH)(PO3H)}(2)] center dot 2H(2)O and [NH3(CH2)(2)NH2(CH2)(2)NH3][Fe-III{O3PC(CH3)(OH)(PO3H)}(2)] center dot H2O. Journal of Solid State Chemistry 2002, 164, (2), 367-373.
10. Shi, X.; Fang, Q. R.; Xin, M. H.; Wu, G.; Tian, G.; Zhu, G. S.; Li, Y. F.; Wang, L. F.; Wang, C. L.; Shang, T. C.; Qiu, S. L., Synthesis and structure of a novel inorganic-organic hybrid framework microporous material Cd-3(BDC)(0.5)(BTC)(2)(DMF) (H2O)center dot 3DMF center dot H3O center dot H2O. Chemical Journal of Chinese Universities-Chinese 2002, 23, (11), 2040-2042.
11. Li, Y. F.; Cui, W.; Zhu, G. S.; Shi, Z.; Xu, X. Z.; Xiao, F. S.; Qiu, S. L., Syntheses and structure of alpha-(+)-Co(en)(3)V3O6 center dot H2O. Chemical Journal of Chinese Universities-Chinese 2002, 23, (7), 1243-1245.
12. Li, Y. F.; Cui, W.; Zhu, G. S.; Qiu, S. L.; Fang, Q. R.; Wang, C. L., Hydrothermal synthesis and characterization of Ni-3(PO4)(2) center dot 8H(2)O with 8-ring and 4-ring network structure. Chemical Journal of Chinese Universities-Chinese 2002, 23, (8), 1480-1482.
13. Li, Y. F.; Cui, W.; Wu, G.; Fang, Q. R.; Zhu, G. S.; Li, B. S.; Gao, F. F.; Wang, C. L.; Qiu, S. L., Hydorthermal synthesis and characterization of a new compound [Co(en)(3)](2)center dot 2H(3)O center dot[As8V14O42(HPO4)]center dot 2H(2)O. Chemical Journal of Chinese Universities-Chinese 2002, 23, (5), 783-785.
14. Li, D. S.; Zhu, G. S.; Li, Y. F.; Gao, F. F.; Li, B. S.; Qiu, S. L., Syntheses and characterization of novel open-framework zinc germanate phosphates. Chemical Journal of Chinese Universities-Chinese 2002, 23, (9), 1673-1675.
15. Li, B. S.; Zhu, G. S.; Wang, X.; Gao, F. F.; Tu, S. J.; Wang, C. L.; Ben, T.; Qiu, S. L.; Zhang, W. J., Mesoporous aluminosilicate-templated fabrication of poly(aryl ether ketone)s nanotube. Abstracts of Papers of the American Chemical Society 2002, 224, U452-U452.
16. Li, B. S.; Zhu, G. S.; Gao, F. F.; Guo, Z.; Liu, C. Z.; Yin, X. J.; Wang, C. L.; Qiu, S. L., Fabrication of polystyrene nanofiber and nanotube using mesoporous silicate and aluminosilicate as templates. Abstracts of Papers of the American Chemical Society 2002, 224, U451-U451.
17. Fang, Q. R.; Shi, X.; Wu, G.; Tian, G.; Zhu, G. S.; Li, Y. F.; Wang, L. F.; Wang, C. L.; Chen, Y.; Zhang, Z. D.; Guo, Z.; Shang, T. C.; Cai, X. H.; Qiu, S. L., Synthesis and characterization of a 3-D inorganic-organic hybrid framework microporous material Zn-3(bpdc)(3)(4,4 '-bpy)center dot DMF center dot 2H(2)O. Acta Chimica Sinica 2002, 60, (12), 2087-2091.