基本信息科学研究教学研究论文著作
个人简介
张镇，男，教授，博士生导师，哈尔滨工业大学大科学工程专项建设指挥部暨空间基础科学研究中心。


工作经历

标题工作经历

职位,职务,职称教授

工作地点,工作单位哈尔滨工业大学大科学工程专项建设指挥部暨空间基础科学研究中心

起讫时间2016.01 - 至今

简单介绍空间综合环境表面效应研究平台建设及空间表面化学研究。


标题工作经历

职位,职务,职称Research Scientist

工作地点,工作单位Department of Chemistry, University of Virginia

起讫时间2011.07 - 2015.12



标题工作经历

职位,职务,职称Research Associate

工作地点,工作单位Department of Chemistry, University of Virginia

起讫时间2008.03 - 2011.07



教育经历

标题教育经历

起讫时间1997.09 - 2001.07

所学专业化学

学习机构南京大学

学历本科



标题教育经历

起讫时间2001.09 - 2008.03

所学专业物理化学

学习机构中国科学院大连化学物理研究所

学历博士


研究领域
(1) 模拟空间环境下材料表面结构及物理化学

(2) 氧化物表面缺陷的催化化学与光催化化学

(3) 金属/氧化物界面结构与表面物理化学

(4) 光或电子与材料表面的相互作用

科研项目
招生信息
硕士/博士 1-2人/年

欢迎有志于表面科学，空间化学，催化化学，光催化化学等领域研究者报考。

论文期刊

论文标题Anatase-Selective Photoluminescence Spectroscopy of P25 TiO2 Nanoparticles: Different Effects of Oxygen Adsorption on the Band Bending of Anatase

作者Shiliang Ma, Matthew E. Reish, Zhen Zhang, Ian Harrison, and John T. Yates, Jr.

期刊名称Journal of Physical Chemistry C

期卷2017, 121 (2), pp 1263–1271

简单介绍Photoluminescence (PL) spectroscopy was used to infer that oxygen adsorption changes the band bending of the anatase phase of TiO2 within P25 nanopowder in different ways. On the one hand, oxygen can adsorb through irreversible reaction with defects which reduces the intrinsic upward band bending at the TiO2 surface and results in increased PL emission. On the other hand, oxygen exposure also leads to molecular chemisorption that yields an outermost negative charge at the surface which increases the upward band bending of TiO2 and decreases the PL emission. Since band bending plays an active role in directing charge carrier migration to the surface, the finding that oxygen adsorption can have two different, and quite opposite, effects on the band bending of TiO2 provides a new perspective on how oxygen may influence photocatalytic reaction efficiencies.


论文标题A new form of chemisorbed photo- and electro-active atomic H species on the TiO2(110) surface

作者Zhen Zhang, John T. Yates, Jr.

期刊名称Surface Science

期卷2016, 652, 195–199

简单介绍Hydrogen adsorption on TiO2 is of importance in chemical and photochemical reduction processes. Using several surface science methods, we clearly distinguish two kinds of H species on the surface of rutile TiO2(110)-1 × 1. In contrast with the well-studied bridge-bonded OH species (α-H) originating from H2O dissociation on the surface oxygen vacancy site on TiO2(110), atomic H adsorption on the TiO2(110) (denoted as β-H) exhibits special high sensitivity to the electronic excitation of the TiO2(110) by either electrons or UV photons. The formation of molecular H2 gas by photoexcitation of β-H/TiO2(110) surfaces has been observed, which may shed light on the basic understanding of the processes of photocatalytic H2 production by splitting water.


论文标题How Annealing and Charge Scavengers Affect Visible Emission from ZnO Nanocrystals

作者Matthew E. Reish, Zhen Zhang, Shiliang Ma, Ian Harrison, Henry O. Everitt

期刊名称Journal of Physical Chemistry C

期卷2016, 120, 5108-5113

简单介绍Simultaneous transmission infrared (IR) absorption and photoluminescence (PL) spectroscopies are used to reveal the correlation of free electron and defect densities during the stepwise annealing of ZnO nanocrystals in high vacuum. For increasing annealing temperatures between 700 and 1000 K, the free electron density increases with a negligible increase in PL yield. With increased annealing temperature above 1000 K, the free electron density decreases and the PL yield increases in inverse proportion. Accompanying the free electron loss are indications of increased bound charges and changes in the multiphonon bands in the infrared spectrum, which collectively suggest that structural change and defect formation accompanies the loss of free electrons and the increase in PL. Exposure of the previously annealed sample to electron (O2) and hole (MeOH) scavengers shows that the buildup of holes quenches visible emission, while additional electrons have a marginal effect on the PL yield. Given that certain neutral donors bind excitons and facilitate energy transfer to visible emitting sites, the buildup of free holes appears to quench PL intensity by ionizing those neutral donors.


论文标题Defect-Electron Spreading on the TiO2(110) Semiconductor Surface by Water Adsorption

作者Zhen Zhang, Ke Cao, John T. Yates, Jr.

期刊名称Journal of Physical Chemistry Letters

期卷2013, 4 (4), 674-679

简单介绍The dissociative adsorption of water at oxygen-vacancy defect sites on the TiO2(110) surface spatially redistributes the defect electron density originally present at subsurface sites near the defect sites. This redistribution of defect-electrons makes them more accessible to Ti4+ ions surrounding the defects. The redistribution of electron density decreases the O+ desorption yield from surface lattice O2- ions in TiO2, as excited by electron-stimulated desorption (ESD). A model in which OH formation on defect sites redistributes defect electrons to neighboring Ti4+ sites is proposed. This switches off the Knotek–Feibelman mechanism for ESD of O+ ions from lattice sites. Conversely, enhanced O+ reneutralization could also be induced by redistribution of defect electrons. The redistribution of surface electrons by adsorption is further verified by the use of donor and acceptor molecules that add or remove electron density.


论文标题Band Bending in Semiconductors - Chemical and Physical Consequences at Surfaces and Interfaces

作者Zhen Zhang, John T. Yates, Jr.

期刊名称Chemical Reviews

期卷2012, 112, 5520-5551

简单介绍This is the age where the capture of solar energy for useful purposes has gained the attention of the scientific and engineering world. The use of solar energy for the generation of electricity, coupled with its potential to produce fuels from CO2 waste and H2O by solar-induced photochemistry, is a goal being pursued worldwide. The optimization of charge transfer processes at semiconductor surfaces by manipulation of the energy bands is therefore a theme of broad generality and current applicability.(1)The fields of heterogeneous photocatalysis and photochemistry have developed extensively in the past 40 years in response to challenging energy and environmental issues.(2-12) In photocatalysis or photochemistry on surfaces, photon absorption is accompanied by electronic excitation in the substrate or in the adsorbed molecules accompanied by either charge or energy transfer;(6, 11) in heterogeneous catalysis, charge transfer can occur independently of any photon excitation. In photocatalysis, the photogenerated charge carrier transfer process between surface and adsorbed molecules constitutes a complex and fundamental step in chemical processes induced by the absorption of light.There are over 1000 review papers dealing with the topic of “photocatalysis” or “photochemistry”. Most of the review papers are concentrated on some specific area, such as a specific photochemical/photocatalytic process (e.g., photodissociation of H2O; photochemistry and environmental remediation), photocatalyst preparation or modification, or fabrication of photovoltaic devices. Only rarely do review papers attempt to illuminate the general mechanisms that play important roles in heterogeneous photocatalysis or photochemical processes at surfaces.In this review, we focus on the principles of band bending and its effect on photochemistry and photocatalysis. This may be helpful to chemists and material scientists in the understanding of the photoexcitation process and the development of highly efficient photoactive materials and processes. The review is divided into three parts dealing with (1) the physical principles of band bending in semiconductors, (2) the measurement of band bending, and (3) the effects of band bending on photochemistry. The band bending concept is of course well established in semiconductor physics(13, 14) and has become one of the central concepts in electrochemistry(15-17) and gas sensors.(18, 19) As shown in Figure 1, until now, there have been ～10？000 papers with the topic words “band bending” or “Schottky barrier”, but most of the papers are in the field of solid state physics, and only 25 papers are found with the words “band bending” together with “photochemistry” or “photocatalysis”.


论文标题Photoluminescence of TiO2: Effect of UV Light and Adsorbed Molecules on Surface Band Structure

作者Ana Stevanovic, Michael Buttner, Zhen Zhang, John T. Yates, Jr.

期刊名称Journal of the American Chemical Society

期卷2012, 134(1), 324-332

简单介绍The photoluminescence (PL) of TiO2 at 529.5 nm (2.34 eV) has been found to be a sensitive indicator of UV-induced band structure modification. As UV irradiation occurs, the positive surface potential changes and shifts the depth of the depletion layer. In addition, reversible band bending due to the adsorption of the electron-donor NH3 and CO molecules has been observed in measurements combining PL with FTIR surface spectroscopy. It has been found that the O2 molecule acts in two ways: as a reversibly adsorbed electron-acceptor molecule and as an irreversibly adsorbed molecule that heals natural oxygen vacancy defects in the near-surface region.


论文标题Low Pt Loading High Catalytic Performance of PtFeNi/Carbon Nanotubes Catalysts for CO Preferential Oxidation in Excess Hydrogen I

作者Limin Chen, Ding Ma, Zhen Zhang, Yuanyuan Guo, Daiqi Ye, Bichun Huang

期刊名称Catalysis Letters

期卷2012, 142(8), 975-983

简单介绍The commercial carbon nanotubes (CNTs-o) and purified carbon nanotubes (CNTs-p) have been utilized to prepare Pt(FeNi)/CNTs catalysts for CO preferential oxidation (PROX) in H2 rich stream. The 3 wt%Pt0.41 %Fe 0.35 %Ni/CNTs-p catalyst after activation at 500 °C in H2 can almost completely remove CO at 6 °C in feed gas containing 1 % CO, 0.5 % O2 (volume ratio) and H2 balance. CNTs-o supported 3 wt% Pt can also remove CO almost completely at room temperature, after activation at 500 °C in the feed gas. And this catalyst can keep high activity, high selectivity and high stability for PROX of CO at room temperature. These catalysts are the most effective catalysts for PROX of CO with much lower Pt loading until so far. H-TPR, XRD, HRTEM and reaction results indicate that the Fe and/or Ni precursors have been reduced to metallic state after activation in H2 which can be oxidized to coordinatively unsaturated FeOx and/or NiOx active species after exposure to feed gas. XPS data point out that over oxidation of Fe and Pt species will deactivate the catalysts seriously. The high catalytic performance is mainly due to the promotion effects of in situ formed coordinatively unsaturated FeOx and/or NiOx species and the unique properties of CNTs.


论文标题Synergistic Effect of a Carbon Black Supported PtAg Non-Alloy Bimetal Nanocatalyst for CO Preferential Oxidation in Excess Hydrogen

作者Limin Chen, Ding Ma, Zhen Zhang, Yuanyuan Guo, Daiqi Ye, Bichun Huang

期刊名称ChemCatChem

期卷2012, 4(12), 1960-1967

简单介绍Carbon black (CB) supported PtAg non-alloy bimetal catalysts were prepared by incipient wetness impregnation and evaluated for CO preferential oxidation in excess H2 (PROX). PtAg/CB catalysts exhibited an evident synergistic effect. The catalyst support selection is crucial to the synergistic effect. X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning TEM energy dispersive X-ray analysis (STEM-EDX) characterization indicates no alloy was formed over the PtAg/CB catalyst after activation in H2 at 500？°C for 2？h. However, temperature-programmed reduction (TPR) and XRD data evidenced strong interactions between platinum and silver, as a result of their simultaneous reduction and high temperature activation. The Pt[BOND]Ag interactions result in high catalytic performance and the synergistic effects. This is another example of model catalyst research translating to real world catalysis. PtAg non-alloy catalysts may also be effective in eliminating or alleviating catalyst poisoning by CO-like intermediates in direct liquid fuel cells.


论文标题Electric Charge of Single Au Atoms Adsorbed on TiO2(110) and Associated Band Bending

作者Zhen Zhang, Wenjie Tang, Matthew Neurock, John T. Yates, Jr.

期刊名称 Journal of Physical Chemistry C

期卷2011, 115(48), 23848-23853

简单介绍The influence of charge transfer from single Au atoms to TiO2(110) on the photostimulated desorption (PSD) of 18O2 has been studied using a measurement of the rate of hole transport which mediates PSD. Band bending effects observed experimentally and theoretically by density functional theory indicate that Auδ+ atoms are present. The presence of atomically dispersed Au on the TiO2(110) surface with a constant coverage of preadsorbed 18O2 depresses the photoinduced hole transport rate from the bulk to the TiO2 surface and decreases the 18O2 PSD yield. This indicates that single Au atoms donate a fraction of an electron to the surface, causing downward band bending. DFT calculations show that ～0.2 electron transfers from single Au atoms to the O2/TiO2(110) surface and the valence and conduction bands bend ～0.6 eV downward. With increasing Au coverage, the positive charge per Au atom decreases due to the formation of small Au clusters.


论文标题Interaction of CO with oxygen adatoms on TiO2(110)

作者Junseok Lee, Zhen Zhang, Xingyi Deng, Dan C. Sorescu, C. Matranga, John T. Yates, Jr.

期刊名称 Journal of Physical Chemistry C

期卷2011, 115(10), 4163-4167

简单介绍The interaction between CO and O adsorbed on TiO2(110) has been investigated using scanning tunneling microscopy (STM), electron stimulated desorption (ESD), temperature programmed desorption (TPD), and density functional theory (DFT). Coadsorption of CO and O produces CO？O and CO？O？CO surface complexes via weak attractive interaction as revealed by STM and DFT. The effect of the adsorbates interaction can also be observed in two ensemble-averaged techniques, ESD and TPD, strongly supporting the STM and DFT results. The CO molecules adsorbed near chemisorbed O cause a ～70% decrease in the O+ ion yield in ESD. The interaction between CO and O is considered to be electrostatic in nature due to the charge rearrangement upon chemisorption.


论文标题Electron-Mediated CO Oxidation on the TiO2(110) Surface during Electronic Excitation

作者Zhen Zhang, John T. Yates, Jr.

期刊名称Journal of the American Chemical Society

期卷2010, 132 (37), 12804-12807

简单介绍The role of electrons and holes in the electronically excited oxidation of adsorbed CO on TiO2(110) has been investigated by tuning the surface electron and hole availability by the adsorption of Cl2 or O2. The presence of an electron acceptor (Cl2 or O2) on the TiO2(110) surface causes upward band bending, increasing the excited hole availability and decreasing the excited electron availability in the near surface region. This enhances O2 desorption and depresses CO2 production during electronic excitation. This result gives clear evidence for the first time that the electronically excited CO oxidation reaction is caused by an electron-mediated process in contrast to O2 desorption which is mediated by holes.


论文标题Effect of Adsorbed Donor and Acceptor Molecules on Electron Stimulated Desorption: O2/TiO2(110)

作者Zhen Zhang, John T. Yates, Jr.

期刊名称Journal of Physical Chemistry Letters

期卷2010, 1 (14), 2185-2188

简单介绍The role of band bending on the efficiency of charge transfer across the TiO2(110) single crystal surface has been measured in ultrahigh vacuum, in the absence of a wide range of surface site inhomogeneities, surface impurities and solvent effects, and particle size effects. The adsorption of the Cl2 (electron acceptor) molecule and the O2 (electron acceptor) molecule have been found to enhance hole transport from TiO2 to 18O2 molecules adsorbed on oxygen vacancy sites, increasing the rate of electron stimulated desorption (ESD) of 18O2. This confirms that O2-ESD is hole mediated. Conversely, adsorption of CH3OH, a donor molecule, reduces the transfer rate for holes to the adsorbed O2, reducing its rate of ESD to near zero. The maximum effect of donor and acceptor molecules occurs near 1 monolayer coverage.


论文标题Direct observation of surface-mediated electron-hole pair recombination in TiO2(110)

作者Zhen Zhang, John T. Yates, Jr.

期刊名称Journal of Physical Chemistry C

期卷2010, 114 (7), 3098-3101

简单介绍The kinetics of surface and bulk electron？hole pair recombination have been measured separately on TiO2(110) in ultrahigh vacuum under well-controlled surface conditions for the first time. Using 100 eV incident electrons, excitation of electron？hole pairs occurs within ～6 ？ of the surface, and the rate of stimulated desorption of O2 was measured as a means of determining the charge carrier recombination kinetics, which are found to be mediated by the surface and to be first-order in charge carrier concentration. Comparison with a previous O2 photodesorption experiment, where excitation by 3.4 eV photons was used for electron？hole pair generation in a deeper region below the surface (～100 ？), shows that bulk recombination in TiO2 occurs by second-order kinetics in charge carrier concentration.


论文标题Unraveling the Diffusion of Bulk Ti Interstitials in Rutile TiO2(110) by Monitoring Their Reaction with O Adatoms

作者Zhen Zhang, Junseok Lee, John T. Yates, Jr., Ralf Bechstein, Estephania Lira, Jonas O. Hansen, Stefan Wendt, Flemming Besenbacher

期刊名称Journal of Physical Chemistry C

期卷2010, 114 (7), 3059-3062

简单介绍The diffusion of interstitial Ti3+ species (Tii3+) in rutile TiO2(110) from the bulk to the surface has been studied utilizing two experimental techniques. Electron-stimulated desorption of O+ ions was employed to kinetically monitor the reaction between oxygen adatoms with Tii3+ species at temperatures between 360 and 400 K. Scanning tunneling microscopy was also used to measure the Tii3+ diffusion rate. Both methods yield a rate constant kTii3+ = 5 × 10？4 s？1 at 393 K. The activation energy as measured by the rate dependence on temperature is ～1.0 eV.


论文标题Controlled Transformation of the Structures of Surface Fe (FeO) and Subsurface Fe on Pt(111)

作者Teng Ma, Qiang Fu, Yi Cui, Zhen Zhang, Zhen Wang, Dali Tan, Xinhe Bao

期刊名称Chinese Journal of Catalysis

期卷2010, 31 (1), 24-32

简单介绍Monolayer Fe films on Pt(111) and their derived structures under different environments were investigated by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). The growth of monolayer Fe films was seen at 487 K. The surface composition and structure of the Fe/Pt(111) surface were monitored by XPS and STM during stepwise annealing under vacuum. Surface Fe was driven into the subsurface region during annealing above 800 K. This resulted in a Pt-skin surface of Pt/Fe/Pt(111). Oxidation of the Pt-skin structure in O2 produced a FeO surface structure, FeO/Pt(111). This was transformed into a surface Fe structure by mild reduction in H2 (600 K) and into subsurface Fe by further severe reduction (800 K). The transformation of surface Fe (FeO) and subsurface Fe in Pt(111) was reversible in cycled oxidation and reduction treatments. The results demonstrated the controlled preparation of various Fe-Pt surfaces. This can be important for the design of high-performance and low-cost catalysts.


论文标题IR Spectroscopic Measurement of Diffusion Kinetics of Chemisorbed Pyridine through TiO2 Particles

作者Isabel Xiaoye Green, Corneliu Buda, Zhen Zhang, Matthew Neurock, John T. Yates, Jr.

期刊名称Journal of Physical Chemistry C

期卷2010, 114 (39), 16649-16659

简单介绍The chemisorption and surface diffusion/desorption of pyridine from TiO2 powder (P25) have been measured as a function of temperature using transmission IR spectroscopy. Two classes of diffusion have been measured with activation energies of 36 kJ/mol (fast) and 90 kJ/mol (slow). By comparing density functional theory (DFT) calculations of bonding energies on TiO2 rutile (110) and anatase (101), the dominant crystal planes expected in P25 TiO2, it is found that fast diffusion would be expected on the rutile phase and that much slower diffusion would be expected on the anatase phase. In addition, the presence of oxygen defect sites will produce more strongly bound pyridine than either of the model crystal planes selected for investigation. To both types of TiO2 surfaces, pyridine bonding occurs to coordinatively unsaturated Ti cation sites through the N lone pair of the pyridine molecule. More than 85% of the molecules exhibit slow surface diffusion, and this is attributed to diffusion on the dominant anatase crystallites as well as to diffusion on defective sites. Diffusing molecules exhibit a ν19b ring-breathing mode, with the rapidly diffusing molecules exhibiting a mode frequency of ～1438 cm？1 and the slowly diffusing species exhibiting a mode frequency of ～1445 cm？1. Electron stimulated desorption ion angular distribution (ESDIAD) studies of the C？D bond directions for pyridine-d5 on the rutile TiO2(110)-1 × 1 surface show that the ring plane is rotated by 37 ± 1° with respect to the [001] azimuth on the crystal surface, in good agreement with the 39° rotational angle calculated by DFT. Several ring-breathing modes of pyridine are slightly broadened on rutile sites compared to anatase sites, and this may be due to more freedom for librational vibrations of the more weakly bound pyridine molecules.


论文标题Electron-stimulated positive-ion desorption caused by charge transfer from adsorbate to substrate oxygen adsorbed on TiO2(110)

作者Junseok Lee, Zhen Zhang, John T. Yates, Jr.

期刊名称Physical Review B

期卷2009, 79 (8), 081408

简单介绍The electron-stimulated desorption of O+ from atomic oxygen (Ot) species on the TiO2(110) surface has been investigated. Adsorbed Ot species, produced by O2 dissociation, desorb as O+ ions by hole production in the Ti(3p) level of lattice Ti4+ ions. A factor of 600 increase in the O+ desorption cross section for the Ot species is observed compared to lattice O. Very efficient charge transfer from the Ot species to the Ti(3d) level, accompanied by a low reneutralization rate for the O+ ions at the Ti sites, is postulated to be responsible for the greatly enhanced O+ ion yield.


论文标题Size-dependent surface reactions of Ag nanoparticles supported on highly oriented pyrolytic graphite (HOPG)

作者Hui Zhang, Qiang Fu, Yunxi Yao, Zhen Zhang, Teng Ma, Dali Tan, Xinhe Bao

期刊名称Langmuir

期卷2008, 24, 10874-10878

简单介绍Various sizes of Ag particles were grown on highly oriented pyrolytic graphite (HOPG) surfaces, which had previously been modified with nanopits to act as anchoring sites. Surface reactions of O2, CHCl3, and CCl4 on the Ag particles and bulk Ag(111) surfaces were studied by X-ray photoelectron spectroscopy (XPS), and it has been shown that size dependence of O2 and CHCl3 reactions on Ag differs from that of CCl4. Weak reactions of O2 and CHCl3 were observed on the bulk Ag(111) surfaces, while strong reactions occur on Ag particles with medium Ag coverage, suggesting that the reactions are controlled by the number of surface defect sites. On the contrary, the dissociation of CCl4 is mainly determined by the exposed Ag facet area, mainly Ag(111) facet, and strong dissociation reaction happens on the bulk Ag(111) surface. The results suggest that the size effects, which are often discussed in heterogeneous catalysis, are strongly dependent on the reaction mechanism.


论文标题Modulation of surface reactivity via electron confinement in metal quantum well films: O2 adsorption on Pb/Si(111)

作者Zhen Zhang, Yanfeng Zhang, Qiang Fu, Hui Zhang, Yunxi Yao, Teng Ma, Dali Tan, Qikun Xue, Xinhe Bao

期刊名称Journal of Chemical Physics

期卷2008, 129, 014704

简单介绍Pb quantum well films with atomic-scale uniformity in thickness over macroscopic areas were prepared on Si(111)-7×7 surfaces. As a probe molecule, O2 was used to explore the effect of electron confinement in the metal films on the surface reactivity. X-ray photoelectron spectroscopy results showed clear oscillations of oxygen adsorption and Pb oxidation with the thickness of the Pb films. The higher reactivity to O2 on the films with 23 and 25 ML Pb has been attributed to their highest occupied quantum well states being close to the Fermi level (EF) and the high density of the electron states at EF (DOS-EF), as evidenced by the corresponding ultraviolet photoelectron spectroscopy. A dominant role of DOS-EF was suggested to explain the quantum modulation of surface reactivity in metal quantum well films.


论文标题Preparation and characterization of atomically flat and ordered silica films on a Pd(100) surface

作者Zhen Zhang, Zhiquan Jiang, Yunxi Yao, Dali Tan, Qiang Fu, Xinhe Bao

期刊名称Thin Solid Films

期卷2008, 516, 3741-3746



论文标题Enhanced methanol dissociation on nanostructured 2D Al overlayers

作者Zhen Zhang, Qiang Fu, Hui Zhang, Yong Li, Yunxi Yao, Dali Tan, Xinhe Bao

期刊名称Journal of Physical Chemistry C

期卷2007, 111, 13524-13530



论文标题Oxygen adsorption on Ag/Si(111)-7×7 surfaces

作者Zhen Zhang, Jian Jiao, Zhiquan Jiang, Dali Tan, Qiang Fu, Xinhe Bao, Xi Liu, Jinfeng Jia, Qikun Xue

期刊名称The Journal of Vacuum Science and Technology A

期卷2008, 26, 62-67



论文标题Preferential occupation of molybdenum on the thin alumina film: Characterization by CO titration

作者Zhiquan Jiang, Weixin Huang, Hong Zhao, Zhen Zhang, Dali Tan, Xinhe Bao

期刊名称Catalysis Today

期卷2008, 131, 28-34



论文标题Structure control of Pt-Sn bimetallic catalysts supported on highly oriented pyrolytic graphite(HOPG)

作者Yunxi Yao, Qiang Fu, Zhen Zhang, Hui Zhang, Teng Ma, Dali Tan, Xinhe Bao

期刊名称Applied Surface Science

期卷2008, 254 (13), 3808-3812



论文标题Molybdenum deposition on the thin alumina film: A combinatorial investigation by HREELS, XPS and UPS

作者Jiang, Weixin Huang, Zhen Zhang, Hong Zhao, Dali Tan, Xinhe Bao

期刊名称Chemical Physics Letters

期卷2007, 439 (4-6), 313-317



论文标题Dispersion and site-blocking effect of molybdenum oxide for CO chemisorption on the Pt(110) substrate

作者Zhiquan Jiang, Weixin Huang, Hong Zhao, Zhen Zhang, Dali Tan, Xinhe Bao

期刊名称Journal of Molecular Catalysis A

期卷2007, 268 (1-2), 213-220



论文标题Thermal decomposition of Mo(CO)6 on thin Al2O3 film: A combinatorial investigation by XPS and UPS

作者Zhiquan Jiang, Weixin Huang, Zhen Zhang, Hong Zhao, Dali Tan and Xinhe Bao

期刊名称Surface Science

期卷2007, 601 (3), 844-851



论文标题铂纳米团簇在修饰的HOPG表面的生长及性能表征

作者张辉、张镇、姚运喜、谭大力、包信和

期刊名称电子显微学报

期卷2006， 25（4）, 287-292



论文标题Multiple coordination of CO on molybdenum nanoparticles: Evidence for intermediate Mox(CO)y species by XPS and UPS

作者Zhiquan Jiang, Weixin Huang, Zhen Zhang, Hong Zhao, Dali Tan, Xinhe Bao

期刊名称Journal of Physical Chemistry B

期卷2006, 110 (51), 26105-26113



论文标题利用多孔阳极氧化铝研究载体孔洞尺寸对负载银粒子团聚的影响

作者赵红、姜志全、张镇、翟润生、包信和

期刊名称催化学报

期卷2006， 27（5）， 381-385



出版物

出版物名称Defects on TiO2 – Key Pathways to Important Surface Processes (Book Chapters)

作者Zhen Zhang and John T. Yates, Jr.

出版时间,完成时间2015

出版社Springer

简单介绍in Defects on Oxide Surfaces, p81-121, Edited by Jacques Jupille and Geoff Thornton, Springer, 2015