姓名： 夏纪宝 性别： 男
学科类别： 职务：
学历： 博士 职称： 研究员
电话： 传真：
电子邮件： jibaoxia@licp.cas.cn
通讯地址： 苏州市工业园区，金鸡湖大道99号, NW8


简　　历：
2015/5-至今 中国科学院兰州化学物理研究所苏州研究院，研究员，博士生导师
2015/3-至今 中国科学院兰州化学物理研究所，研究员，博士生导师
2010/8-2015/3 美国得州大学西南医学中心，博士后，导师：Chuo Chen 教授
2005/9-2010/7 中国科学院上海有机化学研究所，博士，导师：游书力 研究员
2001/9-2005/7 山东师范大学，学士

研究方向：
碳一(C1)分子和低碳烯烃转化，惰性化学键活化转化，羰基合成与催化转化

获奖及荣誉：
2020 Thieme Chemistry Journals Award
2015 中科院“人才计划”

承担科研项目：
中科院“人才计划”项目 (择优支持) 2015/12-2018/11, 项目负责人
国家自然科学基金面上项目 (**) 2016/01-2017/12, 项目负责人
江苏自然科学基金面上项目 (BK**) 2016/7-2019/6, 项目负责人
国家自然科学基金面上项目 (**) 2018/01-2021/12, 项目负责人

代表论著：
28. Zhang, Z.-B.; Yang Y.; Yu, Z.-X.; Xia, J.-B. Lewis Base-Catalyzed Amino-Acylation of Arylallenes via C–N Bond Cleavage: Reaction Development and Mechanistic Studies. ACS Catal. 2020, 10, 5419-5429. [HTML]
27. Li, Y.-L.; Li W.-D.; Gu, Z.-Y.; Chen, J.; Xia, J.-B. Photoredox Ni-catalyzed Branch-Selective Reductive Coupling of Aldehydes with 1,3-Dienes. ACS Catal. 2020, 10, 1528-1534. [HTML]
26. Li, W.-D.; Zhu, D.-Y.; Li, G.; Chen, J.; Xia, J.-B. Iron-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2. Adv. Synth. Catal. 2019, 361, 5098-5104. [HTML] VIP Paper, Front Cover
25. Yuan, S.-W.; Han, H.; Li, Y.-L.; Wu, X.; Bao, X.; Gu, Z.-Y.; Xia, J.-B. Intermolecular C–H Amidation of (Hetero)arenes to Produce Amides through Rhodium-Catalyzed Carbonylation of Nitrene Intermediate. Angew. Chem. Int. Ed. 2019, 58, 8887-8892. [HTML]
·Highlighted in Chin. J. Org. Chem. 2019, 39, 2681.
24. Han, H.; Fang, L.; Chen, J.; Yang, S.-D.; Xia, J.-B. Tetramethylguanidine (TMG)-Catalyzed Reductive Spirocyclization of Tryptamine Derivatives with Formic Acid as a C1 Synthon. Tetrahedron Lett. 2019, 60, 1487-1489. [HTML]
23. Han, H.; Zhang, T.; Yang, S.-D.; Lan, Y.; Xia, J.-B. Palladium-Catalyzed Enantioselective C–H Aminocarbonylation: Synthesis of Chiral Isoquinolinones. Org. Lett. 2019, 21, 1749-1754. [HTML]
22. Han, H.; Yang, S.-D.; Xia, J.-B. Pd/Cu Cocatalyzed Oxidative Tandem C–H Aminocarbonylation and Dehydrogenation of Tryptamines: Synthesis of Carbolinones. J. Org. Chem. 2019, 84, 3357-3369. [HTML]
21. Zhang, Z.-B.; Ji, C.-L.; Yang, C.; Chen, J.; Hong, X.; Xia, J.-B. Nickel-Catalyzed Kumada Coupling of Boc-Activated Aromatic Amines via Nondirected Selective Aryl C？N Bond Cleavage. Org. Lett. 2019, 21, 1226-1231. [HTML]
·Highlighted by P. Knochel and S. Graβl in Synfacts 2019, 15, 526.
20. Li, G.; Chen, Y.; Xia, J.-B. Progress on Transition-Metal-Catalyzed Cross-coupling Reactions of Ammonium Salts via C–N Bond Cleavage. Chin. J. Org. Chem. 2018, 38, 1949-1962. [HTML]
19. Li, G.; Chen, J.; Zhu, D.-Y.; Chen, Y.; Xia, J.-B. DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane. Adv. Synth. Catal. 2018, 360, 2364-2369. [HTML]
18. Zhu, D.-Y.; Li, W.-D.; Yang, C.; Chen. J.; Xia, J.-B. Transition-Metal-Free Reductive Deoxygenative Olefination with CO2. Org. Lett. 2018, 20, 3282-3285. [HTML]
17. Zhu, D.-Y.; Fang, L.; Han, H.; Wang Y.; Xia, J.-B. Reductive CO2 Fixation via Tandem C–C and C–N Bond Formation: Synthesis of Spiro-indolepyrrolidines. Org. Lett. 2017, 19, 4259-4262. [HTML]
16. Zhu, D.-Y.; Chen, P.; Xia, J.-B. Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C–H Activation. ChemCatChem, 2016, 8, 68-73. [HTML]
Publications from Graduate and Postdoctoral Studies:
15. Han, L.; Xia, J.-B.; You, L.; Chen, C. Ketone-catalyzed photochemical C(sp3)–H chlorination. Tetrahedron 2017, 73, 3696-3701.
14. Xia, J.-B.; Zhu, C.; Chen, C. Visible Light-Promoted Metal-Free sp3-C–H Fluorination Chem. Commun. 2014, 50, 11701-11704.
13. Xia, J.-B.; Ma, Y.; Chen, C. Vanadium-Catalyzed C(sp3)–H Fluorination Reactions. Org. Chem. Front. 2014, 1, 468-472.
·One of three hot articles in April, 2014.
·One of top ten most-read articles from April to June, 2014.
12. Zhu, C.; Xia, J.-B.; Chen, C. A Simple Method for the Electrophilic Cyanation of Secondary Amines. Org. Lett. 2014, 16, 247-250.
11. Zhu, C.; Xia, J.-B.; Chen, C. Vanadium-Catalyzed Oxidative Strecker Reaction: α-C–H Cyanation of para-Methoxyphenyl (PMP)-Protected Primary Amines. Tetrahedron Lett. 2014, 55, 232-234.
10. Xia, J.-B.; Zhu, C.; Chen, C. Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination. J. Am. Chem. Soc. 2013, 135, 17494-17500.
·Highlighted in Synfacts 2014, 10, 85; Org. Chem. Front. 2014, 1, 434-438.
9. Xia, J.-B.; Cormier, K. W.; Chen, C. A Highly Selective Vanadium Catalyst for Benzylic C–H Oxidation. Chem. Sci. 2012, 3, 2240-2245.
·One of top ten most accessed articles in April, 2012.
8. Liu, W.-B.; Xia, J.-B.; You, S.-L. Iridium-Catalyzed Asymmetric Allylic Substitutions Top. Organomet. Chem. 2012, 38, 155-208.
7. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L. Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptanes and 3-Azabicyclo[3.2.0]heptanes via Ir-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction. Chem. Eur. J. 2010, 16, 6442-6446.
·Highlighted in Synfacts 2010, 8, 909.
6. Xia, J.-B.; Zhuo, C.-X.; You, S.-L. Synthesis of Cyclopropane-containing Building Blocks via Ir-Catalyzed Enantioselective Allylic Substitution Reaction. Chin. J. Chem. 2010, 28, 1525-1528.
·Invited paper for celebrating the 60th Anniversary of SIOC.
5. You, S.-L.; Xia, J.-B. Palladium-Catalyzed Aryl–Aryl Bond Formation through Double C–H Activation. Top. Curr. Chem. 2010, 292, 165-194.
4. Xia, J.-B.; You, S.-L. Synthesis of 3-Haloindolizines by Copper(II) Halides Mediated Direct Functionalization of Indolizines. Org. Lett. 2009, 11, 1187-1190.
3. Xia, J.-B.; Wang, X.-Q.; You, S.-L. Synthesis of Biindolizines through Highly Regioselective Palladium-Catalyzed C–H Functionalization. J. Org. Chem. 2009, 74, 456-458.
2. Wang, X.-Q.; Xia, J.-B.; Dai, X.-Y.; You, S.-L. Preparation of Ferrocenyl Imidazolines using Bis(triphenyl)oxodiphosphonium Trifluoromethansulfonate. Sci. China Chem. 2009, 52, 1331-1336.
·Invited paper for the 90th Anniversary of Nankai University.
1. Xia, J.-B.; You, S.-L. Carbon–Carbon Bond Formation through Double sp2 C–H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives. Organometallics 2007, 26, 4869-4871.
·One of the most-accessed articles in July-September 2007.
Book Chapters
2. Xia, J.-B.; You, S.-L. C–C Bond Formation via Double C–H Bond Activation. in Science of Synthesis, Yu, J.-Q., Ed, Thieme: Stuttgart, 2015 115-136.
1. Xia, J.-B.; Jamison, T. F.; You, S.-L. Monodentate Chiral Ferrocenyl Ligands. in Chiral Ferrocenes in Asymmetric Catalysis, Dai, L.-X., Hou, X.-L., Eds, WILEY-VCH: Weinheim, 2010, pp. 55-71.

社会任职：


个人网页：
https://www.x-mol.com/groups/jibaoxia