基本情况?
姓名：陈小明
性别：男
籍贯：暂未填写
职位：教授，博士生导师，现任生物无机与合成化学教育部重点实验室主任。2009年当选中国科学院院士
联系方式?
电话：+86-
传真：暂未填写
邮箱：cxm@mail.sysu.edu.cn
通讯地址：广州市新港西路中山大学化学与化学工程学院
邮编：510275
个人网站：http://ce.sysu.edu.cn/cxm/
教育经历
1983年获中山大学理学学士学位；
1986年获中山大学理学硕士学位；
1992年获香港中文大学哲学博士学位。
工作经历?
主要工作简历：
1986年至1989年在中山医科大学生物化学教研室工作，历任助教、讲师
1992年7月起在中山大学化学与化学工程学院工作
1993年12月晋升副教授，1995年1月晋升教授
2006年至今，生物无机与合成化学教育部重点实验室主任
主要学术兼职：
先后兼任生物无机与合成化学教育部重点实验室主任、中大化学院院长、中国晶体学会副理事长、中国科学院化学部常委及副主任、国家学位委员会化学学科评议组成员、国家基金委化学部专家咨询委员会成员、国际分子筛协会金属有机框架材料（MOF）委员会成员等职务等。
讲授课程?
主要讲授《现代无机化学》和《单晶结构分析》等本科生、研究生课程；指导博士后、博士生、硕士生以及国内访问****的科研工作。
科研方向?
功能配位化学与晶体工程研究，特别是配位聚合物、金属有机框架材料等的设计与合成、结构与功能（吸附与分离、催化、光电磁、传感）研究，以及含能分子晶体研究。?
科研项目
暂无资料
获奖情况
2007年??国家自然科学奖二等奖（第一完成人）：配合物控制合成与晶体工程方法基础研究
2008年??汤森路透卓越研究奖?(Thomson?Reuters?? Research Fronts Award)
2012年??发展中国家科学院TWAS化学奖
2012年??广东省科学技术奖一等奖(第一完成人): “微孔与磁性配位聚合物研究”
2014年??汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2015年??汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2016年??汤森路透高被引用科学家?(Thomson?Reuters Highly Cited Researcher)
2017年??科睿唯安高被引用科学家?(Clarivate?Highly Cited Researcher)
2017年??广东省科学技术奖突出贡献奖
论著一览
编写教材：?
《单晶结构分析原理与实践》（与蔡继文博士合作），科学出版社，2003年9月第一版，2007年8月第二版。?
陈小明在国际刊物发表的部分论文目录：
Selected Publications of Xiao-Ming Chen:
?1.?Polynuclear Cu^II₁₂-M^III₆?(M = Y, Nd or Gd) complexes encapsulating a ClO₄^–?anion:
[Cu₁₂M₆(OH)₂₄(pyb)₁₂(H₂O)₁₈(ClO₄)](ClO₄)₁₇·nH₂O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601. PDF
2.?Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N. Angew. Chem. Int. Ed. 1999, 38, 2237-2240. PDF
3.?Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence Cu^I-Cu^II complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031. PDF
4.?A novel, highly electrical conducting, single-component molecular material, [Ag₂(ophen)₂] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M.,?J. Am. Chem. Soc. 2003, 125, 6882-6883.?PDF
5.?(Review Article)?Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202. PDF
6.?Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ?formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M.,?Angew. Chem. Int. Ed.?2004, 43, 206-209.
7.?A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc.?2004, 126, 13218-13219. PDF
8.?(Review Article)?Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev.?2005, 249, 545–565. PDF
9.?Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M.,?J.?Am. Chem. Soc. 2005, 127, 5495-5506. PDF
10.?Spin-canting and metamagnetism observed in a unique 3D homometallic?molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun,?X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed.?2005, 44, 3079-3082. PDF
11.?Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J.?Am. Chem. Soc. 2005,?127, 14162-14163. PDF
12.?Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559.?PDF
13.?Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314.?PDF
14.?(Review Article)?Solvothermal?in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L., Acc. Chem. Res.?2007, 40, 162-170. PDF
15.?A dynamic porous magnet?exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.;?Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater.?2007, 19, 1494–1498.?PDF
16.?A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed.?2007, 46, 6076-6080. (Highlighted in Nature China)?PDF
17.?Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739.?PDF
18.?Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater.?2008, 20, 1534–1538.?PDF
19.?Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.;?Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017; PDF
20.?Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2009,?131, 5516–5521.?(Highlighted in Nature China)?Link.
21.?(Review Article)?Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M., Chem. Soc. Rev.?2009, 38, 2385–2396. Link
22.?A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.;?Chen, X.-M.,?Angew. Chem. Int. Ed.?2009, 48, 5287-5290.?Link.
23.?Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2010,?132, 6654–6656. Link
24.?Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M.,?Adv. Mater.?2011, 22, 1268–1271. PDF
25.?A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Chem. Sci.?2011, 2, 2214-2218. Link.
26.?Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.;?Zhang, J.-P.; Chen, X.-M.,?Nature Commun. 2012, 3, 642. DOI: 10.1038/ncomms1654. Link
27.?(Review Article)?Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M., Chem. Rev.?2012, 112, 1001–1033. Link
28.?Strong and dynamic CO₂?sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2012,?134,?17380-17383. Link
29.?A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M., Chem. Sci.?2013, 4, 351–356. Link
30.?Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M., Chem. Sci.?2013, 4, 1539-1546. Link
31.?Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.;?Chen, X.-M., Nature Commun. 2013, 4, 2534. DOI: 10.1038 /ncomms3534. Link
32.?A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.;^?Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed.?2013, 52, 13429-13433. Link
33.?(Invited Review)?Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M., Chem. Soc. Rev. 2014, 43, 5789-5814. DOI: 10.1039/C4CS00129J. Link
34.?Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M., Adv. Funct. Mater. 2014,?24, 5866–5872. DOI: 10.1002/adfm.. Link
35.?Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen, Chem. Sci. 2014,?5, 4755. DOI:?10.1039/C4SC01505C. Link
36.?Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting;?Zhang, Wei-Xiong; Chen, Xiao-Ming; Angew. Chem. Int. Ed.?2015, 54, 914 –918. DOI: 10.1002/anie.. Link
37.?Monodentate?hydroxide as a super strong yet reversible active site for CO₂?capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting;?Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen,?Energy Environ. Sci.?2015, 8, 1011-1016. DOI: 10.1039/C4EE02717E. Link
38.?Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.;?Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M., Nature Comm.?2015, 6, 6350. doi:10.1038/ncomms7350. Link
39.?Tuning fluorocarbon?adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci.?2015, 6, 2516-2521. DOI: 10.1039/C4SC03985H. Link
40.?Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6,?6917. DOI: doi: 10.1038/ncomms7917. Link
41.?(Invited Review)?Metal cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen, Coord. Chem. Rev.?2015, 293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009. Link?
42.?Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna,?Rajamani; Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2015, 137, 7217–7223.?Link
43.?Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6,?8348. DOI: 10.1038/ncomms9348. Link
44.?Efficient purification of ethene by ethane-trapping metal-organic framework?
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8697. doi:10.1038/ncomms9697. Link
45.?(Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed.?2016, 55, 4674–4678. DOI: 10.1002/anie.. Link
46.?An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei;?Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming, J. Am. Chem. Soc.?2016, 138, 8336–8339. DOI: 10.1021/jacs.6b03125. Link
47.?Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming; Adv. Mater., 2016, 28, 5886–5890. DOI: 10.1002/adma.. Link
48.?(Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO₂
Kai-Jie Chen, David G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko, Angew. Chem. Int. Ed.?2016, 55, ?10268–10272. DOI: 10.1002/anie.. Link
49.?Putting ultrahigh concentration of amine groups into a metal–organic framework for CO₂?capture at low pressures
Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong;?Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci.?2016, 7, 6528-6533. DOI:? 10.1039/C6SC00836D. Link
50.?Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed.?2016, 55, 6021–16025. ?DOI: 10.1002/anie.. Link
51.?Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc.?2017, 139,?1778–1781. DOI: 10.1021/jacs.6b12353. Link
52.?A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan;?He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming, J. Am. Chem. Soc.?2017, 139,?139, 5285–5288. DOI: 10.1021/jacs.7b00165. Link
53.?A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming,?J. Am. Chem. Soc. 2017, 139,?6369–6375. DOI: 10.1021/jacs.7b01334. Link
54.?Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Science, 2017, 356, 1193-1196. DOI: 10.1126/science.aam7232. Link
55.?A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi; Zhang, Wei-Xiong; ?Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139,?8086–8089. DOI: 10.1021/jacs.7b02981. Link
56.?Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci.?2017, 8,?7560–7565. DOI: 10.1039/c7sc03067c. Link
57.?Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO₂?reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng; J. Am. Chem. Soc. 2018, 140,?38–41. Link
58.?Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long;?Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming,?Zhang, Jie-Peng;?Adv. Mater. ?2018, 30,?**.??adma.. Link
59.?Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu,?Xia; Du, Zi-Yi;?He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2018, 10.1002/anie.. Link
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