基本情况姓名：赵存元
性别：男
出生年月：1962-09
籍贯：甘肃正宁
职位：教授，博士生导师
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联系方式电话：+86-
传真：暂未填写
邮箱：ceszhcy@mail.sysu.edu.cn
通讯地址：广东省广州市中山大学化学与化学工程学院
邮编：510275
个人网站：暂未填写
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教育经历1997年11月毕业于南京大学配位化学研究所，理论无机化学专业，获理学博士学位。
1987年7月毕业于西北师范大学化学化工学院，物理化学专业，获理学硕士学位。
1984年7月毕业于西北师范大学化学化工学院，获理学学士学位。
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工作经历2004.09 - 至今：中山大学化学与化学工程学院，教授；博士生导师。
2002.02-2004.09：香港大学化学系，博士后。
2000.09-2002.02：美国戴维斯加州大学，博士后。
1999.09-2000.09：香港科技大学化学系，博士后。
1996.12-1999.09：西北师范大学化学化工学院，副教授。
1987.07-1996.12：西北师范大学化学化工学院，助教、讲师。
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讲授课程本科生课程：结构化学， 现代化学实验与技术。
研究生课程：应用量子化学。
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科研方向1. 有机金属化合物与重要有机化学反应和中间体的结构、反应性、催化机理和新型催化体系设计的理论化学研究，包括金属类卡宾化合物、金属氮宾的反应性能、环丙烷化反应及其不对称催化选择性机理的理论研究。
2. 碳、硼氮纳米材料导电性质的分子设计研究。
3. 金属团簇基态和激发态的结构、性质及基于金属团簇光电磁等物理化学性质的分子设计研究。
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科研项目1. 卤甲基金属卡宾体引发不对称环丙烷化立体选择机理的理论研究,国家自然科学基金（**），28.0万元，2007.1-2009.12，项目负责人
2. 新型碳、硼氮纳米管导电材料的分子设计研究，广东省自然科学基金，(031584)，5.0万元，2007.9-2009.8，项目负责人
3. 教育部回国留学人员科研启动基金，3.0万元，2006.1-2007.12，项目负责人
4. 中山大学“****”第二层次科研启动基金，20.0万，2004.9-2006.12，项目负责人
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获奖情况暂无资料
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论著一览1. Z. Guo, Z.F. Ke, D.L. Phillips,?C. Y. Zhao, Organometallics, 27, 181 (2008), Intrinsic Reaction Coordinate Analysis of the Activation of CH4 by Molybdenum Atoms: A Density Functional Theory Study of the Crossing Seams of the Potential Energy Surfaces.
2. Z. Guo,?C. Y. Zhao, D.L. Phillips, E.G. Robertsonc, D. McNaughtonc,?J. Phys. Chem. A, 2008, accepted, An Experimental and Theoretical Study of NSCl Decomposition in the Presence of Trace Amounts of Water.
3. 李志伟，赵存元，陈六平，物理化学学报，24, 755 (2008), As5-? , [As5M]-、[As5MAs5] 2- (M=Ti, Zr, Hf)的结构和芳香性
4. Z.W. Li,?C. Y. Zhao, L.P. Chen,?THEOCHEM, 854, 46 (2008), Structure and aromaticity of Bi5- , Bi5M (M = Li, Na, K) and Bi5M+ (M = Be, Mg, Ca) clusters.
5. Z. Guo, X.F. Lin,?C. Y. Zhao, D.L. Phillips,?THEOCHEM, 848, 119 (2008), Density functional theory study of water-assisted deprotonation of the C8 intermediate in the reaction of the 2-fluorenylnitrenium ion with guanosine to form a C8 adduct.
6. Z.F. Ke, Y. B. Zhou, H. Gao,?C. Y. Zhao, D.L. Phillips,?Chem. Eur. J., 13, 6724 (2007), On the Mechanism and Stereochemistry of Chiral Lithium Carbenoid Promoted Cyclopropanation Reactions.
7. Z.F. Ke,?C. Y. Zhao, D.L. Phillips,?J. Org. Chem. 72, 848(2007), Methylene Transfer or Carbometalation? A Theoretical Study to Determine the Mechanism of Lithium Carbenoid Promoted Cyclopropanation Reactions in Aggregation and Solvation States.
8. R. Fang, Z.F. Ke; Y. Shen,?C. Y. Zhao; D.L. Phillips,?J. Org. Chem., 72, 5139 (2007), Concurrent Cyclopropanation by Carbenes and Carbanions? A Density Functional Theory Study on the Reaction Pathways.
9. X.F. Lin,?C. Y. Zhao, C.-M. Che, Z.F. Ke, D.L. Phillips,?Chem. Asian. J., 2, 1101 (2007), A DFT Study on the Mechanism of Rh2II,II –Catalyzed Intramolecular Amidation of carbamates (封面论文) .
10.Z.H. Li, Z.F. Ke,?C. Y. Zhao, Z.Y. Geng, Y.C. Wang, D.L. Phillips,?Organometallics, 25, 37
35 (2006), A Density Functional Theory Study of Aluminum Carbenoid (CH3)2AlCH2X (X = Cl, Br, I) Promoted Cyclopropanation Reactions Compared to IMCH2I (M = Li, Sm, Zn) Carbenoids.
11.Z.W. Li,?C. Y. Zhao, L.P. Chen,?THEOCHEM, 807, 17 (2007), Structure and arom aticity of Sb5? and Sb5M (M=Li, Na, and K) clusters.
12.Z.W. Li,?C. Y. Zhao, L.P. Chen,?THEOCHEM, 809, 45 (2007), Spectroscopic properties of aromatic heterocyclic systems: XAl3 (X=Si, Ge, Sn, Pb) and their anions and cations.
13. Z.W. Li,?C. Y. Zhao, L.P. Chen,?THEOCHEM, 810, 1 (2007), Sandwich complexes of the P42- aromatic ring with the first row transition metal.
14. Z.W. Li,?C. Y. Zhao, L.P. Chen,?J. Theo. Comp. Chem., 2, 363 (2007), Theoretical study of sandwich complexes [Fe(η4-E4)2]2- (E=N, P, As, Sb, and Bi) .
15. 李志伟，赵存元，陈六平，化学进展，18, 1599 (2006)， 芳香性团簇的结构和光谱性质的理论研究进展
16. 周玉炳，柯卓锋，赵存元，化学学报，20, 2071 (2006)， Ru(II)催化有机叠氮与炔反应机理的理论研究
17.?C. Y. Zhao, X,F. Lin, W.M. Kwok, X.G. Guan, Y. Du, D.Q. W.K. Fa Hung and D. Lee Phillips,?Chem. Eur. J., 11, 1093 (2005), Water-Catalyzed Dehalogenation Reactions of the Isomer of CBr4 and its Reaction Products and a Comparison to Analogous Reactions of the Isomers of Di- and Trihalomethane.s
18. D. L. Phillips,?C. Y. Zhao, D. Wang,，J. Phys. Chem. A., 109, 9053 (2005). A Theoretical Study of the Mechanism of the Water Catalyzed HCl Elimination Reactions of CHXCl(OH) (X=H, Cl) and HClCO in the Gas Phase and in Aqueous Solution.
19. X.F. Lin,?C. Y. Zhao, D. L. Phillips,?J. Org. Chem., 70, 9279 (2005), Modeling SN2 Reactions in Methanol Solution by ab Initio Calculation of Nucleophile Solvent-Substrate Clusters.
20. R. Fang, Z.Y. Geng, Y.C. Wang,?C.Y. Zhao, L.Z. Yang, X.H. Zhang Phys.?Chem. Lett. 414, 174(2005), Theoretical study of the insertion reaction of CH3O-H by singlet alkylidenecarbenes.
21. X. Q.Guan, X.F. Lin, D. Yong, Y.L. Li, W. M. Kwok,?C. Y. Zhao, D.Q. Wang, D. L. Phillips,?J. Phys. Chem. A, 109, 1247 (2005), Ultraviolet photolysis of CH2I2 in methanol: O-H insertion and HI elimination reactions to form a dimethoxymethane product.
22. X.F. Lin, X. Q.Guan, W. M. Kwok,?C. Y. Zhao, D. Yong, Y.L. Li, D. L. Phillips,?J. Phys. Chem. A, 109, 981 (2005), Water-catalyzed O-H Insertion/HI elimination reactions of isodihalomethanes (CH2X-I, where X = Cl, Br, I) with water and the dehalogenation of dihalomethanes in water-solvated environment.s
23. X.F. Lin,?C. Y. Zhao, D. L. Phillips,?MOLECULAR SIMULATION 31, 483 (2005) An ab initio study of the reactions of CH2X-X (X = Cl, Br, I) isopolyhalomethanes with nCH3OH.
24. W. M. Kwok,?C. Y. Zhao, Y-L Li, X., Guan, D. Q. Wang, D. L. Phillips,?J. Am. Chem. Soc., 126, 3119 (2004), 水催化异溴仿(CHBr3)脱卤反应及其产物，Water-Catalyzed Dehalogenation Reactions of Isobromoform and Its Reaction Products
25.?C. Y. Zhao, K. Balasubramanian,?J. Chem. Phys., 22，10501 (2004), Spectroscopic Properties of Novel Aromatic Metal Clusters: NaM4 (M=Al, Ga, I) and their cations and anions.
26. D. Wang,?C. Y. Zhao, and D. L. Phillips,?Organometallics, 23, 1953 (2004), Theoretical Study of Divalent Lanthanide (Sm and Yb) Complexes with A Triazacyclononane– Functionalized Tetramethyly-clopentadienyl Ligand.
27. D. Wang,?C. Y. Zhao, and D. L. Phillips,?J. Org. Chem., 69, 5512 (2004), Samarium(III) Carbenoid as a Competing Reactive Species in Samarium-Promoted Cyclopropanation Reactions.
28. X.F. Lin,?C. Y. Zhao, D. L. Phillips, Phys.?Chem. Lett. 397, 488(2004), Ab initio investigation of the O-Y (Y = CH3, H) insertion/HI elimination reactions of CH2I-I with CH3OH and H2O: comparison of methanol and water catalyzed reactions.
29.?C. Y. Zhao, D. Wang, and D. L. Phillips,?J. Am. Chem. Soc., 125, 15200 (2003), 钐类卡宾化合物与乙烯环丙烷反应机理及溶剂效应的理论研究，Theoretical Study of Samarium (II) Carbenoid (ISmCH2I) Promoted Cyclopropanation Reactions with Ethylene and the Effect of THF Solvent on the Reaction Pathways.
30.?C. Y. Zhao, D. Wang, and D. L. Phillips,?J. Theo. Comp. Chem., 2, 357 (2003), Density Functional Theory Study of Selected Mono Zinc and Gem-Dizinc Radical Carbenoid Cyclopropanation Reactions: Observation of an Efficient Radical Zinc carbenoid Cyclopropanation Reaction and the Influence of the Leaving Group on Ring closure.
31.?C. Y. Zhao, D. Wang, and D. L. Phillips,?J. Am. Chem. Soc., 124, 12903 (2002), 高活性偕二锌及单锌类卡宾化合物与乙烯环丙烷反应性能的密度泛函研究，A Density Functional Theory Investigation of the Remarkable Reactivity of Geminal Dizinc Carbenoids (RZn)2CHI (R=Et or I) as Cyclopropanation Reagents with Olefins Compared to Mono Zinc Carbenoids RZnCHI2, EtCHIZnR (R=Et or I).
32.?C. Y. Zhao?and K. Balasubramanian,?J. Chem. Phys., 116, 10287 (2002), 铅六聚体及其离子的结构及光谱性质，Geometries and Spectroscopic Properties of Lead Hexamer and its ions (Pb6, Pb6+and Pb6-).
33.?C. Y. Zhao?and K. Balasubramanian,?J. Chem. Phys., 116, 3690 (2002), 硅五、六聚体及其离子的结构及光谱性质，Geometries and Spectroscopic Properties of Silicon Clusters (Si5, Si5+ , Si5- ,Si6, Si6+ , and Si6-).
34.?C. Y. Zhao?and K. Balasubramanian,?J. Chem. Phys., 115, 3121(2001), 锗、锡六聚体及其离子的结构及光谱性质，Geometries and Spectroscopic Properties of Germanium and Tin Hexamers (Ge6, Ge6+, Ge6- ,Sn6, Sn6+ , and Sn6-).
35. Charles Edwin Webster, Michael B. Hall, D. A. Singleton, M.J. Szymanski,?C. Y. Zhao, Guochen Jia and Zhenyang Lin,?J. Am. Chem. Soc., 123, 9822 (2001), Minimum Energy Structure of Hydridotris(pyrazolyl)borato Iridium(V) Tetrahydride Is Not a C3v Capped Octahedron.
36. Zhitao Xu,?C. Y. Zhao?and Zhenyang Lin,?J. Chem. Soc.?Perkin Trans. II, 2319-2323 (2000), A New Approach to the Distortion of the Tetrahedral Geometry at E in the E(ZXY2)4 Compounds.
37.?C. Y. Zhao, Wenshan Duan, Yong Zhang, Xiao-Zeng You,J. Chem. Res., 156-157, 耦合常数与键角的关系， Correlation of Coupling Constants JCH and Bond Force Angles in Strained Organic Molecules.
38. Yong Zhang,?C. Y. Zhao, Wei-Hai Fang, Zu-Hong Lu, J. Mol. Struc.?THEOCHEM, 454 (1), 31-40 (1998), High accuracy studies on the ground state and transition state of SiC2.
39.?C. Y. Zhao, Yong Zhang, Xiao-Zeng You,J. Phys. Chem. A, 101, 5174-5182 (1997), 有机张力分子弯键特征和张力评价的理论研究， Theoretical Evaluation of Bent Bond, Strain and Bonding Behavior of Strained Organic Molecules.
40. Yong Zhang,?C. Y. Zhao, Xiao-Zeng You,?J. Phys. Chem. A, 101, 2879-2885 (1997), A Systematic Study On Structures And Bondings of the Charge-Transfer Complexes of Ammonia With HX, XY And X2 (X And Y Are Halogens).
41. Yong Zhang,?C. Y. Zhao, Wei-Hai Fang, Xiao-Zeng You,?Theor. Chem. Acc., 96, 129-134 (1997), A Molecular Design View on the First Hyperpolarizability of Salicyli-deneaniline Derivatives.
42. Tian Yu-peng, Duan Chun-ying,?C. Y. Zhao, Lu Zhong-lin and You Xiao-zeng,?Inorg. Chem., 36, 1247-1252 (1997), Synthesis, Crystal Structure and Second-order Optical Nonlinearity of the bis(2-chlorobenzaldehyde Thiosemicarbazone)Cadmium Halide (CdL2X2) (X=Br, I).
43. Yong Zhang,?C. Y. Zhao, Xiao-Zeng You, Chin.?Chem. Lett., 8, 323 (1997), Theoretical Study on the Structures, Vibrational Spectra, and the nature of the Intermediate Hydrogen Bond of Schiff Bases.
44.?C. Y. Zhao, Yong Zhang, Wei-Hai Fang, Xiao-Zeng You,?J. Mol. Struct.?(Theochem), 367, 73-82 (1996), A Theoretical Study On The Hyperpolarizabilities Of Dicyanovinyl And Tricyanovinyl Substituted Benzenes, Stilbenes, Styrenes And Azobenzenes.
45.?C. Y. Zhao,Yong Zhang, Wei-Hai Fang, Xiao-Zeng You, Chin.?J. Chem., 14, 393 (1996), Semiempirical Prediction of the Hyperpolarizabilities for Cyanovinyl-substituted Donor-Acceptor Molecules.
46.?赵存元，萧泰，许先芳，游效曾，17, 769 (1996)， 含环有机分子耦合常数与键角的关系，高等学校化学学报.
47.?赵存元，邱文元，许先芳等，高等学校化学学报, 16, 1587 (1995)，有机张力分子弯键特征的理论研究.
48.?赵存元，王永成，邱文元，韦统师, 科学通报, 36, 331-333 (1992)， 多面体碳烷的结构与张力特性研究.
49.?赵存元，王永成，韦统师，化学学报, 50, 228-332 (1992)，宝塔烷电子结构与张力的ab initio研究.
50.?C. Y. Zhao, Tongshi Wei, Chin. Sci. Bull., 37, 1529-1532 (1992), Studies on Structures and Strain Behaviors of Polyhedranes (CH)n .
51.?赵存元，韦统师，邱文元，化学学报，49, 546-552 (1991)，小螺桨烷的弯键研究.
52.?赵存元，韦统师，邱文元，高等学校化学学报，12, 932-934 (1991)，小螺桨烷C-C中心键的量子化学研究.
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