基本情况
叶保辉(YeBao-Hui),男,1964年11月出生于海南文昌,1994年获中山大学博士学位,现任无机化学研究所教授,博士生导师。
联系方式
·广州市新港西路135号中山大学化学与化学工程学院
·电话:+86-020-84112469
·邮件:cesybh@mail.sysu.edu.cn
教育经历
·1994年毕业于中山大学,获博士学位;
·1994年10月至1997年10月在香港科技大学作博士后;
·1997年10月到中山大学化学与化学工程学院工作,期间获日本学术振兴会(JSPS)资助,在日本九州大学(KyushuUniversity)作博士后特别研究员(1999,7-2001,6)
工作经历
暂无资料
讲授课程
曾讲授《无机化学》、《应用无机化学》、《无机化学实验》、《配位化学》等本科生、研究生课程。
科研方向
研究方向:功能配合物和超分子化学。主要研究兴趣:(1)结构新颖的框架、笼状配合物设计和合成及在催化和分离方面的应用;(2)钌、稀土配合物在传感器和光学材料方面的应用。
科研项目
1.仿生水解酶的模研究(广东省自然科学基金,编号021423398)
2.手性配合物的识别及组装(教育部,编号31240415001)
3.金属卟啉分子筛类杂化材料的合成及性质研究(广东省自然科学基金资助,编号031581)
4.新型金属卟啉多孔聚合物的合成及性质研究(国家自然科学资助,编号20371052)
获奖情况
1.1996年“混配配合物的生物功能、作用机制及其应用探索”1996年获广东省自然科学一等奖。(第三完成人)
2.1998年“金属酶体系的结构、机制和模拟研究”获国家教育部科技进步二等奖(基础类)。(第三完成人)
3.200年“金属酶模型化合物的结构、生物功能、作用机制之间规律性”获中国高校自然科学二等奖。(第四完成人)
论著一览
1.TemplateTrappingandCrystalStructureoftheMagicNumber(H2O)21ClusterintheTetrahedralHoleofaNanoscaleGlobalIonPackedinaFace-CenteredCubicPatternMan-LiCao,Jin-JiWu,Hao-JunMo,Bao-HuiYe*,J.Am.Chem.Soc.2009,131,3458-3459.2.CharacterizationofaDinuclearMnV=OComplexandItsEfficientEvolutionofO2inthePresenceofWaterY.Shimazaki,T.Nagano,H.Takesue,Bao-HuiYe,F.Tani,Y.Naruta,Angew.Chem.Int.Ed.2004,43,98-100.3.Metal-organicMolecularArchitectureswith2,2’-Bipyridyl-likeandCarboxylateLigandsBao-HuiYe,Ming-LiangTong,Xiao-MingChen*,Coord.Chem.Rev.2005,249,545-565.4.SpontaneousChiralResolutionofmer-[CoII(N,N,O-L3)2]EnantiomersMediatedbyp-pInteractionsJin-JiWu,Man-LiCao,Bao-HuiYe*,Chem.Commun.,2010,46,3687-3689.5.InterlockingofMolecularRhombiintoa2DPolyrotaxaneNetworkviap-pInteractions.CrystalStructureof[Cu2(bpa)2(phen)2(H2O)2].2H2O(bpa2-=biphenyl-4,4’-dicarboxylate,phen=1,10-phenanthroline)Gao-FengLiu,Bao-HuiYe,Y.-H.Liu,Xiao-MingChen*,Chem.Commun.2002,1442-1443.6.NovelDimanganese(II)Complexeswith(m-H2O)(m-OAc)2Bridges.ModelforDimanganeseEnzymesBao-HuiYe,T.Mak,I.D.WilliamsandXiao-YuanLi*,Chem.Commun.1997,1813-1814.7.FormationofaNovelTetranuclearIron(III)Complexwitham4-PO4Bridgefrom4-NitrophenylPhosphateBao-HuiYe,Xiao-YuanLi*,FengXueandT.C.W.Mak,Chem.Commun.1997,2407-2408.8.Ruthenium(II)2,2′-BibenzimidazoleComplexasaSecond-SphereReceptorforAnionsInteractionandColorimeterYingCui,Yan-LiNiu,Man-LiCao,KeWang,Hao-JunMo,Yong-RuiZhong,andBao-HuiYe*,Inorg.Chem.2008,47,5616-56249.AssemblyofaCubicNanocageCo8L12andaHydrogen-Bonded3DNbONetBasedonthe[(HCO3)2]2-SynthonandWaterMan-LiCao,Hong-GuoHao,Wei-XiongZhang,andBao-HuiYe*,Inorg.Chem,2008,47,8126-813310.ACopper(II)Ion-SelectiveON-OFFTypeFluoroionophoreBasedonZincPorphyrin-DipyridylaminoYan-QinWeng,FanYue,Yong-RuiZhongandBao-HuiYe*,Inorg.Chem.2007,46,7749-7755.11.AnionSelectiveInteractionandColorimeterbyAnOpticalMetalloreceptorBasedonRuthenium(II)2,2’-Biimidazole.HydrogenBondingandProtonTransfer.YingCui,Hao-JunMo,Jin-CanChen,Yan-LiNiu,Yong-RuiZhong,Kang-ChengZheng,andBao-HuiYe*,Inorg.Chem,2007,46,6427-643612.InSituSolvothermalGenerationof1,2,4-TriazolatesandRelatedCompoundsfromOrganonitrilesandHydrazineHydrate:AMechanismStudyLinCheng,Wei-XiongZhang,Bao-HuiYe*,Jian-BinLin,Xiao-MingChen*,Inorg.Chem.2007,46,1135-1143.13.Pillared-layerMicroporousMetal-organicFrameworksConstructedbyRobustHydrogenBonds.Synthesis,Characterization,MagneticandAdsorptionPropertiesof2,2’-BiimidazoleandCarboxylateComplexes.Bing-BingDing,Yan-QinWeng,Zong-WanMao,C.-K.Lam,Xiao-MingChen,Bao-HuiYe*,Inorg.Chem.2005,44,8836-8845.14.FormationofOne-dimensionalMetal-waterChainContainingCyclicWaterHexamers,Bao-HuiYe*,Bing-BingDing,Yan-QinWeng,Xiao-MingChen,Inorg.Chem.2004,43,6866-6868.15.SynthesisandStructuralCharacterizationofDi-andTetranuclearZincComplexeswithPhenolateandCarboxylateBridges.Correlationsbetween13CNMRChemicalShiftsandCarboxylateBindingModesBao-HuiYe*,Xiao-YuanLi,I.D.Williams,Xiao-MingChen,Inorg.Chem.2002,41,6426-6431.16.TheFirstTwoAqua-bridgedDimagnesium(II)complexes:StructuralModelsforActiveSitesinDimetallicHydrolasesBao-HuiYe,T.Mak,I.D.WillamsandXiao-YuanLi*,J.Chem.Soc.DaltonTrans.1998,1935-1936.17.MononuclearNickelComplexesAssembledintoTwo-dimensionalNetworksviaHydrogenBondsandp-pStackinginteractionsBao-HuiYe*,Xiao-MingChen,Gen-QiangXueandLiang-NianJi,J.Chem.Soc.DaltonTrans.1998,2827-2827.18.Mono-andBinuclearRuthenium(II)ComplexesContainingaNewAsymmetricLigand3-Pyrazyl-as-triazino[5,6-f]1,10-phenanthroline:Synthesis,CharacterizationandDNA-bindingPropertiesXiao-HuaZou,Bao-HuiYe*,HongLi,Jing-GangLiu,YaXiongandLiang-NianJi,J.Chem.Soc.DaltonTrans.1999,1423-1428.19.ANovelMethodfortheSynthesisofRegiospcicicallySulfonatedPorphyrinMonomersandDimmers,Bao-HuiYe*,Y.Naruta,Tetrahedron2003,59,3593-3601.20.SynthesesandCharacterizationofAqua-bridgedDimetallicComplexes,M2(m-H2O)(m-OAc)2(Im)4(OAc)2(M=Mg2+,Mn2+andNi2+).StructuralModelsfortheActiveSitesofDimetallicHydrolasesBao-HuiYe*,I.D.Williams,X.-Y.Li,J.Inorg.Biochem.2002,92,128-136.相关成果获专利情况
1.1994年“黑曲酶发酵生产葡萄糖酸锌”获中国专利局发明专利,1996年3月27日公开,公开号:CN119213A。