姓 名： 廖赛虎
职 称： 教授 (博士生导师)
学 历： 博士
办公室: 嘉锡楼503
电 话： +86-
专 业： 有机化学，高分子化学
电子邮箱： shliao at fzu.edu.cn
研究方向： 有机催化，光催化有机合成，光催化聚合

教育工作经历
教育背景：
2001-2005：华中科技大学化学系，学士
2005-2007：华中科技大学化学系，硕士，导师：龚跃法教授
2007-2011：德国马克斯-普朗克煤炭研究所，博士，导师：Prof. Dr. Benjamin List
工作经历：
2011-2013：中科院上海有机化学研究所，助理研究员，导师：唐勇研究员
2013-2016：德国马普煤炭研究所，博士后，导师：Prof. Dr. Benjamin List
2016-2019：福州大学，“闽江****”****
2017.09-至今：福州大学，教授

教学简介
有机化学

科研简介
主要从事有机催化、光催化有机合成、高分子合成等方面工作，先后参与及主持多个科研项目。迄今为止，已在 Acc. Chem. Res., Nat. Commun., J. Am. Chem. Soc., Angew. CHem. Int. Ed. 等国际著名学术期刊上发表论文四十余篇；研究工作受到国际同行积极评价，多篇论文被"NatureChemistry"、"Synform"、"SynFacts"等杂志作为亮点评述。参与编写外文书籍2部，申请中国专利5项，国际专利1项并已获多项授权，另撰写SynFacts评论文章40余篇。2016年入选福建省“闽江****”****， 2017年入选海外高层次人才项目，2018年入选高校青年拔尖人才后备项目以及福建省“****”。
目前主要研究领域：有机催化，光催化有机合成，光催化高分子合成，手性聚合物等。

社会兼职
有机合成与功能福建省高校重点实验室主任

科研项目
1. 福建省****
2. 高校青年拔尖人才后备人才
3. 海外高层次人才项目
4. 国家自然科学基金项目青年基金

5.“闽江****”****科研启动基金

代表性论文
2020:
8.Qiang Ma, Jinshuai Song, Xun Zhang, Yu Jiang, Li Ji, Saihu Liao,* Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight,Nat. Commun.2020, accepted, DOI: 10.21203/rs.3.rs-89454/v1PDF
7. Xingliang Nie, Tianxiao Xu, Jinshuai Song, Anandkumar Devaraj, Bolun Zhang, Yong Chen, Saihu Liao,* Radical Fluorosulfonylation: Accessing Alkenyl Sulfonyl Fluorides from Alkenes,Angew. Chem. Int. Ed.2020, DOI: 10.1002/anie..PDF
6.Tianpeng Cao, Tianxiao Xu, Ruting Xu, Xianli Shu, Saihu Liao,* Decarboxylative thiolation of redox-active esters to free thiols and further diversification,Nat. Commun.2020,11:5340.PDF
5.Xianli Shu, Ruting Xu, Qiang Ma and Saihu Liao,* Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters,Org. Chem. Front.2020,7, 2003–2007.PDF
4. Xun Zhang, Siping Hu, Qiang Ma, and Saihu Liao,* Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules,Polym. Chem.2020,11, 3709–3715.PDF
3. Tianxiao Xu, Tianpeng Cao, Mingcheng Yang, Ruting Xu, Xingliang Nie, and Saihu Liao,* Decarboxylative Thiolation of Redox-Active Esters to Thioesters by Merging Photoredox and Copper Catalysis,Org. Lett.2020,22, 3692–3695PDF
2. Tianxiao Xu, Tianpeng Cao, Qingyuan Feng, Shenlin Huang,* and Saihu Liao,* Metal-free dehydrosulfurization of thioamides to nitriles under visible light,Chem. Commun.,2020,DOI:10.1039/d0cc01380c.PDF
1.Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, Qinggang Wang, and Saihu Liao,* Imidodiphosphorimidate (IDPi) as an Efficient Organocatalyst for Controlled/Living Ring-Opening Polymerization of Lactones,Eur. Polym. J.2020,123: 109449.PDF
2019:
6. Qiang Ma, Xun Zhang, Li Ji, Saihu Liao,* BINOLs as Visible Light Photocatalyst for Metal-Free Atom Transfer Radical Polymerization,Polym. Chem.2019,10, 6662-6668.PDF
5. Mingcheng Yang, Tianpeng Cao, Tianxiao Xu, Saihu Liao,* Visible-Light-Induced Deaminative Thioesterification of Amino Acid Derived Katritzky Salts via Electron Donor–Acceptor Complex Formation,Org. Lett.2019,21, 8673–8678.
4. Rongbiao Wei, Liang Ge, Hongli Bao, Saihu Liao,* Yajun Li,* Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides,Synthesis,2019,51, 4645–4649.
3. Ruting Xu, Tianxiao Xu, Mingcheng Yang, Tianpeng Cao, Saihu Liao,* A Rapid Access to Aliphatic Sulfonyl Fluorides,Nat. Commun.2019,10, 3752.
2. Li Ji, Jia-Shuai Liu, Xiao-Yan Wang, Jun-Fang Li, Zhou Chen, Saihu Liao,* Xiu-Li Sun,* Yong Tang, An Efficient and Mild Route to Highly Fluorinated Polyolefins via Copolymerization of Ethylene and 5-Perfluoroalkylnorbornenes,Polym. Chem.2019,10, 3604–3609
1. Zhu Cao, Jian-Bo Zhu, Lijia Wang,* Saihu Liao,* Yong Tang, A Synthesis of Multifunctionalized Indoles from [3 + 2] Annulation of 2?Bromocyclopropenes with Anilines,Org. Lett.2019,21, 4097–4100.
2018
1. Hai-Xian Gong, Zhu Cao, Saihu Liao, Mei-Jin Lin*, Photoexcited Perylene Diimide Radical Anions for the Reduction of Aryl Halides: A Bay-substituent Effects,Org. Chem. Front.2018,5, 2296–2302.
Selected publications before 2017:
10. Saihu Liao, Markus Leutzsch, Mattia Riccardo Monaco, Benjamin List*, Catalytic Enantioselective Conversion of Epoxides to Thiiranes,J. Am. Chem. Soc.2016,138, 5230–5233. (Highlighted by Nature Chemistry and SynFacts)
9. Saihu Liao, Xiu-Li Sun, Yong Tang*, Sidearm Strategy for Catalyst Design Based on Bisoxazolines in the Remote Control of Enantioselection and Related,Acc. Chem. Res.2014,47, 2260–2272.
8. Pan Wang, Wen-Jie Tao, Xiu-Li Sun, Saihu Liao* and Yong Tang*, A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis,J. Am. Chem. Soc.2013,135, 16849–16852. (Highlighted by SynFacts)
7. Jian-Bo Zhu, Peng Wang, Saihu Liao*, and Yong Tang*, Ylide Hydrolysis in Tandem Reactions: A Highly Z/E-Selective Access to 3-Alkylidene Dihydrobenzofurans and Related Analogues,Org. Lett.2013,15, 3054–3057.
6. Jian-Bo Zhu, Peng Wang, Saihu Liao* and Yong Tang*, PPh3-mediated Intramolecular Conjugation of Alkyl Halides with Electron-deficient Olefins: Facile Synthesis of Chromans and Relevant Analogues,Chem. Commun.2013,49, 4570–4572.
5. Saihu Liao, Peng Wang, Yong Tang, “Covalent Activations: Ylides” in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications, P. Dalko, Ed., Wiley-VCH & Sons: Weinheim, Germany, 2013. (Book Chapter)
4. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation,Adv. Syn. Catal.2012,354, 2363–2367.
3. Benjamin List and Saihu Liao, “The Proline-Catalyzed Mannich Reaction and the Advent of Enamine Catalysis”, in Organic Chemistry–Breakthroughs and Perspectives,K. Ding, L.-X. Dai, Eds., Wiley-VCH: Weinheim, Germany, 2012. (Book Chapter)
2. Saihu Liao, Ilija ?ori?, Qinggang Wang, and Benjamin List*, Activation of H2O2 by Chiral Confined Br?nsted Acids: A Highly Enantioselective Catalytic Sulfoxidation,J. Am. Chem. Soc.2012,134, 10765–10768. (Highlighted by SynFacts)
1. Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidationof Alkenes with Manganese(III)-Salen Phosphate Complexes,Angew. Chem. Int. Ed.2010,49, 628–631. (“Hot Paper”, highlighted by SynFacts)

获奖情况
2018年入选福建省“****”
2018年入选福建省高校青年拔尖人才(领军人才后备)项目
2017年入选国家海外高层次人才青年项目
2016年入选福建省“闽江****”****