1.
Introduction
Polymer-assisted deposition (PAD), which was first reported in 2004[1], provides a generalized strategy toward growing metal compounds with a desired chemical composition at low cost. Compared with other commonly used deposition methods such as physical vapor deposition (PVD)[2–4], and chemical vapor deposition (CVD)[4–7], PAD employs metal ions coordinated to polymers as the precursor. In PAD, the polymer has four notable features: (1) The formation of covalent complexes between the metal cations and the lone pair on the nitrogen atoms of the polymer enables the growth of thick or crack-free thin films. (2) The polymer precursor solution is highly stable in air for months. Additionally, the polymer maintains a homogeneous distribution of metal ions in the solution. Various metal–polymer solutions can be mixed at desired ratios. (3) The viscosity of the solution can be adjusted by simple removing water under vacuum or diluting with deionized water. (4) The polymer solution can be coated onto different substrates by using many methods, including spin, dip, spray, and inkjet coatings. More importantly, the conformal coating of porous materials[8–11] can be realized. In the past decades, metal oxides, metal nitrides, metal carbides, and two-dimensional (2D) layered materials have been successfully prepared by PAD as shown in Figs. 1 and 2.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-1.jpg'" class="figure_img" id="Figure1"/>
Download
Larger image
PowerPoint slide
Figure1.
(Color online) Timeline showing key development by polymer-assisted deposition. Metal oxides; metal nitrides; metal carbides; glassy-graphene; MoS2; MoS2/glassy-graphene heterostructure.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-2.jpg'" class="figure_img" id="Figure2"/>
Download
Larger image
PowerPoint slide
Figure2.
(Color online) Application of as-grown thin films by PAD.
The discovery of single-layer graphene via mechanical exfoliation in 2004[12] revealed that not only fabrication of stable, single-atom thick 2D materials from van der Waals solids is possible, but these materials exhibit extraordinary physical properties[13–15]. Their novel properties inspire many fundamental studies[16–19] and technological advancements[4, 20] for a wide range of applications including electronics, photonics, piezoelectrics, and spintronics. Mechanical exfoliation[19, 20] is a popular method for prototyping devices based on 2D materials. The main drawback of this method is that the size and productivity of materials and devices prepared are very limited. Another commonly used method for synthesizing high-quality 2D materials is chemical vapor deposition (CVD), which, however, is still not so cost-effective for syntheses of 2D materials. In contrast, PAD is a bottom-up, cost-effective, and precisely controlled method for large-scale production of 2D materials. In this review, we summarize the recent development of PAD particularly on syntheses of 2D materials. First, we introduce the principles and processing steps of PAD. Second, 2D materials, including graphene, MoS2, and MoS2/glassy-graphene heterostructures, are provided to illustrate the power of PAD and provide readers with the opportunity to assess the method. Last, we present the future prospects and challenges in this research field. This review provides a novel technique for preparing 2D materials and may inspire new applications of 2D materials.
2.
Polymer-assisted deposition
2.1
Development of polymer-assisted deposition
The past 15 years have witnessed rapid developments in the preparation of epitaxial thin films by using PAD. Thus far, PAD has been successfully used to grow metal-oxides[21–24], metal-nitrides[11, 25–32], metal-carbides[33–35], single element materials (e.g., carbon films[9], Ge films[36], and glassy graphene[37, 38]), and TMD (MoS2[16, 39, 40]) as shown in Figs. 1 and 2. In the past, we built ZnO nanostructures[22–24]and MoS2[16] thin films.
Metal oxides have received considerable attention because of their potential applications in nuclear targets[41–47], spintronic devices[22–24, 48–53], and self-cleaning glasses[54] due to their versatile properties, including ferroelectricity, ferromagnetism, piezoelectricity, semiconductivity, and superconductivity. Many simple oxides, such as Eu2O3[41–44], ZnO[21–24], TiO2[1, 54–58], and VO2[59–64] have been prepared by using PAD. Polymers can prevent metal ions from engaging in unwanted chemical reactions; thus, the growth of complex metal-oxide films through PAD is controllable and reproducible. Many complex metal-oxide thin films, such as Ba1–xSrxTiO3[50, 52, 65–67], CuAlO2[68], mixed-valence perovskite[66], BiVO4[69], LiMn2O4[70], NiCo2O4[71], Gd-CeO2[72], CuScO2[73], CaCu3Ti4O12[74, 75], Re2NiMnO6[76], Co-NdNiO3[77], CuSc1–xSnxO2[78], Sm0.2Ce0.8O1.9–x[79], and Y3Fe5O12[80], have been grown by using PAD.
Metal nitrides are used in many fields due to their hardness, electronic properties[11, 25–28, 32], superconductivity[26, 29–31], and magnetic properties[26, 31]. However, large mismatches exist in either the lattice parameters or the thermal expansion coefficients between the film and the substrate, contributing to great challenges in growth of epitaxial nitride films. In 2008, epitaxial GaN[25] thin films were deposited on (0001) sapphire substrates by PAD for the first time. PAD has also been used for growing binary nitride films, such as NbN[26], TiN[28], AlN[28, 32], MoN[29–31], and UN2[81]. Complex metal nitride films, including Ti1–xAlxN[28], BaZrN2[11], BaHfN2[11], and SrTiN2[27], have been deposited by using PAD.
Transition-metal carbides exhibit high melting point, high electrical conductivity[33, 35, 82], excellent mechanical properties[33–35], and good chemical resistance[81]. These properties make them desirable for applications in wear coatings, passivation layers, turbine engines, and aircraft. The growth of single elements (e.g., C[9] and Ge[36]) and carbides (e.g., TiC, NbC, VC, TaC, and UC2)[33–35, 82, 83] has also been realized by using PAD.
Two-dimensional layered materials, such as graphene and MoS2, are another type of materials prepared by PAD. In the past few years, glassy graphene[37], and MoS2[16, 39, 40] thin films have been successfully obtained by PAD. In addition, 2D layered materials have been fabricated into various electronic devices.
2.2
Principles and processing steps of PAD
In the PAD process, metal ions are coordinated to the polymer as the precursor. Covalent complexes are formed between the metal cations and the lone pair on the nitrogen atoms of the polymer. Thus, the oligomerization reaction will not occur unless certain conditions are satisfied. Hence, the solutions are stable for months. At approximately 450 to 500 °C, the polyethyleneimine (PEI) polymer undergoes thermal depolymerization back to NH2CH=CH2. The ethylenediaminetetra-acetic acid (EDTA) decomposes to acetic acid, formic acid, and ethylenediamine even in inert or H2 atmospheres.
The main processing steps involve the preparation of the metal-precursor solution, ultrafiltration, coating, and annealing. Fig. 3 illustrates the typical PAD steps for the growth of thin films. We will describe the unique chemistry and basic steps of PAD in the following part.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-3.jpg'" class="figure_img" id="Figure3"/>
Download
Larger image
PowerPoint slide
Figure3.
(Color online) Schematic illustration of the main processing steps used to grow thin films by PAD.
2.2.1
Preparation of metal-polymer solution
Table 1 summarizes over 45 different elements that can be coordinated with polymers to form a stable polymer precursor solution. In PAD, the polymer in the solution binds to the metal ions via electrostatic attraction, hydrogen bonding, and/or covalent bonding. The first-row transition metals, using nitrates, acetates or chlorides, bind easily to the simple PEI polymer. Other hard-to-bind metals, such as Sn2+ and Ti2+, need the PEI to be functionalized with carboxylic acids to provide a stable coordination environment. The third method for binding metals utilizes the ability of protonated PEI to coordinate anionic metal complexes. For instance, EDTA could form stable complexes with almost all metals, and then the complexes successfully bind to the PEI.
 |
Table1.
Elements in the magenta boxes coordinated with polymer to form a stable complex. The elements shown in red font were bound with the polymer in the previous reports.
Table options
-->
Download as CSV
|
In Table 2, we summarize 40 different elements that bind well to the polymer. These metal-polymer solutions have been reported in previous works. Interestingly, one metal elemental may be bound with different polymers (PEI or PEI-EDTA).
| Element | Metal precursor | Polymer | Element | Metal precursor | Polymer |
| Li[70] | LiNO3 | PEI + EDTA | Ru[49] | RuCl3 | PAA |
| C[37] | C6H12O6 | PEI | Ag[84] | AgNO3 | PEI + C6H8O7 |
| Al[68] | Al(NO3)3 | PEI + HF | In[85] | In(NO3)3 | PEI |
| Ca[45] | Ca(OH)2 | PEI | Sn[86] | SnCl2 | PEIC |
| Sc[73] | Sc(NO3)3 | PEI + EDTA | Ba[65] | Ba(NO3)2 | PEI + EDTA |
| Ti[1] | Ti(cat)3(NH4)2 | PEI | Hf[42] | HfCl4 | PEI |
| V [10] | VOSO4 | PEI + EDTA | Ta[33] | TaCl5 | PEI + HF |
| Mn[45] | MnCl2 | PEI + EDTA | W[87] | (NH4)2WO4 | PEI |
| Fe[88] | FeCl3 | PEI | Bi[10] | Bi(NO3)3 | PEI + EDTA |
| Co[88] | CoCl2 | PEI | La[45] | La(NO3)3 | PEI + EDTA |
| Ni[51] | Ni(NO3)2 | PEI + EDTA | Ce[72] | Ce(NO3)3 | PEI + EDTA |
| Cu[68] | Cu(NO3)2 | PEI | Pr[76] | Pr(NO3)3 | PEI + EDTA |
| Zn[22] | Zn(NO3)2 | PEI | Nd[76] | Nd(NO3)3 | PEI + EDTA |
| Ga[25] | GaCl5 | PEI | Sm[76] | Sm(NO3)3 | PEI + EDTA |
| Ge[36] | GeO2 | PEI + EDTA | Eu[42] | EuCl3 | PEI |
| Sr[1] | Sr(NO3)2 | PEI + EDTA | Gd[72] | Gd(NO3)3 | PEI + EDTA |
| Y[10] | Y(NO3)3 | PEI + EDTA | Tm[42] | TmCl3 | PEI |
| Zr[55] | ZrO(NO3)2 | PEI + EDTA | U[89] | UO2(oAc)2 | PEI |
| Nb[26] | NbCl5 | PEI + HF | Np[46] | 239Np solution | PEI + EDTA |
| Mo[16] | (NH4)6Mo7O24 | PEI + EDTA | Pu[46] | 239Pu solution | PEI + EDTA |
Table2.
Summary of various metal elements binded by polymers.
Table options
-->
Download as CSV
| Element | Metal precursor | Polymer | Element | Metal precursor | Polymer |
| Li[70] | LiNO3 | PEI + EDTA | Ru[49] | RuCl3 | PAA |
| C[37] | C6H12O6 | PEI | Ag[84] | AgNO3 | PEI + C6H8O7 |
| Al[68] | Al(NO3)3 | PEI + HF | In[85] | In(NO3)3 | PEI |
| Ca[45] | Ca(OH)2 | PEI | Sn[86] | SnCl2 | PEIC |
| Sc[73] | Sc(NO3)3 | PEI + EDTA | Ba[65] | Ba(NO3)2 | PEI + EDTA |
| Ti[1] | Ti(cat)3(NH4)2 | PEI | Hf[42] | HfCl4 | PEI |
| V [10] | VOSO4 | PEI + EDTA | Ta[33] | TaCl5 | PEI + HF |
| Mn[45] | MnCl2 | PEI + EDTA | W[87] | (NH4)2WO4 | PEI |
| Fe[88] | FeCl3 | PEI | Bi[10] | Bi(NO3)3 | PEI + EDTA |
| Co[88] | CoCl2 | PEI | La[45] | La(NO3)3 | PEI + EDTA |
| Ni[51] | Ni(NO3)2 | PEI + EDTA | Ce[72] | Ce(NO3)3 | PEI + EDTA |
| Cu[68] | Cu(NO3)2 | PEI | Pr[76] | Pr(NO3)3 | PEI + EDTA |
| Zn[22] | Zn(NO3)2 | PEI | Nd[76] | Nd(NO3)3 | PEI + EDTA |
| Ga[25] | GaCl5 | PEI | Sm[76] | Sm(NO3)3 | PEI + EDTA |
| Ge[36] | GeO2 | PEI + EDTA | Eu[42] | EuCl3 | PEI |
| Sr[1] | Sr(NO3)2 | PEI + EDTA | Gd[72] | Gd(NO3)3 | PEI + EDTA |
| Y[10] | Y(NO3)3 | PEI + EDTA | Tm[42] | TmCl3 | PEI |
| Zr[55] | ZrO(NO3)2 | PEI + EDTA | U[89] | UO2(oAc)2 | PEI |
| Nb[26] | NbCl5 | PEI + HF | Np[46] | 239Np solution | PEI + EDTA |
| Mo[16] | (NH4)6Mo7O24 | PEI + EDTA | Pu[46] | 239Pu solution | PEI + EDTA |
2.2.2
Ultrafiltration
The metal-polymer solution passes through a filter or membrane to remove cations and anions that are not coordinated polymers, as shown in Fig. 3(b). In the ultrafiltration process, Amicon? ultra centrifugal filtration units and a centrifugal apparatus are used for filtration in our experiments.
2.2.3
Coating
After ultrafiltration, the polymer solution is coated onto different conformation substrates via various methods, including spin, dip, spray, and inkjet. Therefore, the substrate need not to be flat, such as AnodiscTM membranes[10, 55], the grating coupler[56], carbon nanotubes (CNT), and quartz fibers[9, 35]. Furthermore, conformal coating and nanostructured materials may be realized successfully by PAD. This feature makes PAD attractive for use to grow the thin films, form the conformal coating, and synthesize the nanostructured materials.
2.2.4
Thermal de-polymerization and crystallization
To depolymerize the polymer and enable the crystallization of the film, the coated substrate is then treated in a controlled environment at the desired temperature. The water is driven out at moderate temperature (approximately 120 °C). Furthermore, the PAD process involves high -temperature (approximately 500 °C) exposure in a controlled environment to remove the polymer. The PEI and EDTA in the precursor film do not undergo combustion, but rather thermal depolymerization back to NH2CH = CH2, acetic acid, formic acid, and ethylenediamine. Notably, this non-combustive process can lead to reduced carbon contamination in the synthesized thin films.
The thin films may be single-crystal, polycrystalline, or amorphous, depending on the annealing temperature and substrate used. Importantly, the composition of as-grown materials is determined by the metal precursor, temperature, and atmospheric environment. For example: (1) the thermal treatment of the precursor film containing Ti ions in a reducing atmosphere, such as argon mixed with hydrogen, will result in pure Ti. (2) the precursor film will be converted to TiO2 if the thermal treatment is performed in pure oxygen[1, 11, 43, 90, 91]; (3) the same precursor film will be transformed to TiN, if the thermal treatment is carried out in an ammonia atmosphere[42]; and (4) the precursor film will be converted to TiC if the thermal treatment is carried out in a gas mixture of ethylene and forming gas (Ar with H2)[33, 35]. Furthermore, high-quality epitaxial films have been grown using PAD by using a lattice matched substrate and optimal temperature profiles.
3.
Large-scale 2D materials by PAD
3.1
Transparent carbon films and glassy graphene thin films
Transparent conducting films are highly important to electronic, flexible, and transparent devices. Graphene has potential applications in solar cells, touch panels, wearable electronics, and flexible displays[37, 38]. To prepare graphene or carbon thin films, various precursors have been used as carbon sources. In addition, graphitic carbon and glassy graphene have been successfully fabricated via PAD[9, 37]. Furthermore, previous experimental results show that it is possible to fabricate large-scale heterostructures.
Cao et al.[9]. utilized PEI as a carbon source for depositing transparent carbon film on different quartz substrates. In this work, Cu ions are first introduced to grow the graphitic carbon. Further, introducing Cu ions could not only improve the decomposition temperature of PEI, but also help the graphitization of the carbon thin film. Finally, the Cu nanoparticles are removed by immersing the film into FeCl3 solutions and etching Cu to keep the carbon film unbroken. The partially graphitized transparent carbon film is deposited by the PAD of the Cu2+ coordinated PEI.
As shown in Figs. 4 and 5, glucose (C6H12O6) was utilized by Dai et al.[37] as a carbon source for depositing ultra-smooth glassy graphene thin films.
onerror="this.onerror=null;this.src='/fileBDTXB/journal/article/jos/2019/6/http://www.jos.ac.cn/article/id/PIC/19030027-4.jpg'" class="figure_img" id="Figure4"/>
Download
Larger image
PowerPoint slide
Figure4.
(Color online) Evolution from glassy carbon to glassy-graphene and graphene[37].
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-5.jpg'" class="figure_img" id="Figure5"/>
Download
Larger image
PowerPoint slide
Figure5.
(Color online) Preparation of glassy graphene-based circuits and the flexibility test[37].
The three types of carbon-based thin films are deposited by PAD under different catalysis conditions, as shown in Fig. 4. (1) The glassy carbon film, which is partially crystallized and disordered, is grown in Figs. 4(a)–4(c). (2) Glassy graphene, an intermediate state between glassy carbon and graphene, is obtained at 850 °C as shown in Fig. 4(d). TEM studies in Fig. 4(f) show twisted lattice planes. The bent and curved lattice plane is one of the distinguishing features of glassy graphene. (3) When the annealing temperature is increased to 1000 °C, graphene evolves from glassy graphene. From the HRTEM lattice image and the six reflex spots in the SAED, we could confirm the high-quality of graphene in Fig. 4(i). Based on the above analysis, the structural evolution of the three types of material is described in Fig. 4(j). In addition, glassy carbon is partially crystallized and disordered as shown in Fig. 4(c); the glassy graphene in Fig. 4(f) shows a high crystal quality but has twisted, bent lattice planes; and the graphene in Fig. 4(i) has perfect lattices.
Fig. 5(a) indicates that a circuit pattern is obtained after the laser writing and rinsing process. The glassy graphene circuits may be easily transferred to any substrate after annealing, as shown in Fig. 5(b), such as a flexible or rigid substrate. In Fig. 5(c), the sheet resistance is mediated with the bending radius. In addition, the vibration is anisotropic. After repeated bending or twisting, the resistance does not show any obvious changes as shown in Fig. 5(d). In this work, graphene FET is also fabricated to explore its potential application.
For the first time, an ultra-smooth glassy graphene thin film is grown by PAD at the inch scale. The thin film exhibits excellent conductivity, transparency, flexibility, and mechanical and chemical stability. Most importantly, as-deposited thin films are imprinted in flexible and transparent devices.
3.2
Highly scalable synthesis of MoS2 thin films
Two-dimensional semiconductors MoS2 are attracting a wide range of research interest due to their potential applications. MoS2 thin films are also prepared through PAD. Furthermore, as-deposited thin films are fabricated into a photodetector with a broad spectral response and excellent performance.
Zhu et al.[40] reported growing thickness-controlled MoS2 films by using PAD for the first time. In the PAD process, (NH4)6Mo7O24·4H2O and pure sulfur serve as Mo and S sources, respectively. The thickness of the films adjusted by the precursor concentration can be readily changed from 50 to 2.5 nm.
Figs. 6(a)–6(d) shows that the thin film is smooth, continuous, homogeneous, and dense. The thickness and root-mean-square (RMS) surface roughness of the MoS2 thin film are approximately 90 and 10.7 nm, respectively. The HRTEM image and the SAED pattern suggest that the film has high crystallinity.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-6.jpg'" class="figure_img" id="Figure6"/>
Download
Larger image
PowerPoint slide
Figure6.
(Color online) Thickness-dependent bandgap tunable MoS2 thin films for optoelectronics[40].
In addition, the optical band gap energies for the films with different thicknesses are estimated by the UV–vis absorption spectra. The PL responses are the intensity decay and red-shifted in thicker films in Fig. 6(g). The A1g peak shows a blue-shift, which is consistent with the previous report. Notably, the thickness is mediated by the concentration of the Mo precursor.
To explore their photoresponse properties, MoS2 films are fabricated into photoconductors, and then characterized under simulated AM 1.2 illumination. Interestingly, the ratio of conductivity under illumination to dark conductivity is near 3, and the average response time is approximately 0.3 s, as shown in Table 3.
| Method | Precursor gas | Temperature (°C) | Crystalization | Conformal | Size | Mobility (cm2/(V·s)) | Response time | Ion/Ioff ratio |
| CVD | Ar | 1000 | Single-crystal | No | ~cm2 | 9.6 | – | 105[92] |
| Ar | 850 | Single-crystal | No | – | 50 | – | 106[92] | |
| ALD | H2S; Ar | 60 | Amorphous | Yes | – | 0.23 | – | 102[93] |
| PAD | Ar + H2 | 850 | Polycrystalline | Yes | ~cm2 | – | 0.3 ms | 3[40] |
| Ar + H2 | 700 | Polycrystalline | Yes | 6-inch | – | 1.0 ms | 104[39] | |
| Ar + H2 | 550 | Amorphous | Yes | ~cm2 | – | – | –[16] |
Table3.
Comparison of three different methods to synthesize MoS2 and MoS2 field-effect transistor structures.
Table options
-->
Download as CSV
| Method | Precursor gas | Temperature (°C) | Crystalization | Conformal | Size | Mobility (cm2/(V·s)) | Response time | Ion/Ioff ratio |
| CVD | Ar | 1000 | Single-crystal | No | ~cm2 | 9.6 | – | 105[92] |
| Ar | 850 | Single-crystal | No | – | 50 | – | 106[92] | |
| ALD | H2S; Ar | 60 | Amorphous | Yes | – | 0.23 | – | 102[93] |
| PAD | Ar + H2 | 850 | Polycrystalline | Yes | ~cm2 | – | 0.3 ms | 3[40] |
| Ar + H2 | 700 | Polycrystalline | Yes | 6-inch | – | 1.0 ms | 104[39] | |
| Ar + H2 | 550 | Amorphous | Yes | ~cm2 | – | – | –[16] |
Yang et al.[39] developed a highly scalable coating process using PAD without sulfurization. The anhydrous ammonium tetrathiomolybdate (ATM) is converted into MoS3 (120–260 °C) or 2H-MoS2 (> 400 °C). The color difference with various thicknesses is shown in Fig. 7.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-7.jpg'" class="figure_img" id="Figure7"/>
Download
Larger image
PowerPoint slide
Figure7.
(Color online) Wafer-scale synthesis of MoS2 thin films via polymer-assisted deposition[39].
Large-scale and controllable thickness is the main characteristic of MoS2 thin films from PAD. Given that most of as-grown thin films are polycrystalline and have many defects, the photodetector fabricated by as-deposited MoS2 thin films did not exhibit excellent properties, as shown in Table 3.
Ren et al.[16] employed MoS2 thin films to study the dynamic propagation of web telephone-cord buckles, as shown in Fig. 8(a). Parts (b)–(g) of Fig. 8 show a point load applied by a probe that can initiate several branches of telephone-cord buckles. Subsequently, each cord front will branch into two new daughter cords after a certain distance of propagation, forming web buckles with many node positions. Furthermore, the 3D features of web buckles are probed by atomic force microscopy. Interestingly, the buckled semiconducting films have potential applications as diffusive reflection coatings, capillary microchannels, and hydrogen evolution reaction electrodes.
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-8.jpg'" class="figure_img" id="Figure8"/>
Download
Larger image
PowerPoint slide
Figure8.
(Color online) Formation of large-area web buckles[16].
3.3
MoS2/glassy-graphene heterostructures as transparent photodetectors
Based on the previous experiment results[37, 40], MoS2/glassy-graphene heterostructures on quartz substrates have been successfully prepared using a vertically layer-stacking approach. The heterostructures synthesis procedure is illustrated. (1) The MoS2/SiO2/Si nanosheet is spin coated with polymethyl-methacrylate (PMMA). (2) The PMMA/MoS2 layer is separated from the SiO2/Si substrate. (3) A g-graphene/quartz nanosheet is patterned by O2 plasma etching. (4) The PMMA/MoS2 is transferred onto the g-graphene/quartz, followed by the removal of PMMA and cleaning. As seen in Fig. 9(b), the heterostructures exhibit good transparency. The schematic of the transparent photodetector based on the MGH/quartz is shown in Fig. 9(c).
onerror="this.onerror=null;this.src='http://www.jos.ac.cn/fileBDTXB/journal/article/jos/2019/6/PIC/19030027-9.jpg'" class="figure_img" id="Figure9"/>
Download
Larger image
PowerPoint slide
Figure9.
(Color online) Schematic of MGH preparation and 3D view of the transparent photodetector, photoresponsivity and time-resolved photoresponse of photodetectors under different illuminations[38].
In summary, the heterostructures are synthesized by a layer-by-layer transfer technique, and their application as transparent photodetectors are reported for the first time[38].
4.
Prospective and challenges
Compared with the experimental methods, such as chemical vapor deposition (CVD) and atomic layer deposition (ALD), polymer-assisted deposition (PAD) has the advantages of low cost, large scale, easy doping and conformal coatings.
Some novel 2D semiconductors and various functional thin films have been successfully deposited by PAD, but it still remains several challenges on the synthesis of mono-layer thin films. Most of current MoS2 thin films synthesized by PAD still have few layers and are polycrystalline with many defects. The growth of large-scale mono-layer thin films may be difficult to realize by PAD, thereby affecting the transport performance of the corresponding devices. In the future, if large single crystals can be realized by PAD, their device applications will be fully extended to mass production.
The other challenge is the preparation of 2D materials with doping by PAD. Doping, which is the intentional introduction of impurities into a parent material, plays a significant role in functionalizing 2D materials. For example, the wolfram and selenium chemical doping of MoS2 is an effective way of engineering the optical bandgap[94], and Nb-, Co-, and Mn-doped MoS2 few layers exhibit excellent transport properties[95]. Magnetic atoms, such as Mn, Fe, Co, and Ni, doped 2D TMDs, are promising as 2D diluted magnetic semiconductors, and have been predicted to exhibit ferromagnetic behavior at room temperature[96–98]. Thus far, most studies on doping of 2D materials have been intensively focused on the methods of mechanical exfoliation, CVD, and solvothermal methods, but few on PAD. The development of doping 2D semiconductors with novel properties by PAD is a promising research direction because they have various potential applications in optoelectronic, spintronics[100], hydrodeoxygenation reaction[99], and hydrogen evolution reaction[94].
As a characteristic of PAD, conformal coatings have been grown on non-planar surfaces such as quartz fibers[9, 35] in the past. Yi et al.[35] reported the synthesis of carbon nanotube/TiC hybrid fibers with improved mechanical strength and electrical conductivity. In this work, a dense and more compact fiber was formed. The transparent carbon film[9] was easily coated onto flexible quartz fiber by dip coating. The carbon thin film wrapped the quartz fiber tightly and uniformly, suggesting the excellent combination between carbon film and the quartz fiber.
Acknowledgments
L.Z. acknowledges support from the National Natural Science Foundation of China (Grant No.11774279), the Young Talent Support Plan of Xi’an Jiaotong University, and the Instrument Analysis Center of Xi’an Jiaotong University. K.L. acknowledges the support from National Key R&D Program of China (No. 2018YFA0208400), National Natural Science Foundation of China (Nos. 51602173 and 11774191), and Fok Ying-Tong Education Foundation (No. 161042).
