Author(s): Zhang, JY (Zhang, Junying); Ma, PP (Ma, Peipei); Shi, TJ (Shi, Taijing); Shao, XH (Shao, Xiaohong)
Source: THIN SOLID FILMS Volume: 698 Article Number: 137852 DOI: 10.1016/j.tsf.2020.137852 Published: MAR 31 2020
Abstract: BiFeO3 films and Nd-Cr co-doped BiFeO(3 )films were prepared by sol-gel method followed by spinning process on fluorine-doped fin oxide glass substrates. By testing the ultraviolet-visible absorption spectra, it was found that Nd-Cr co-doping will increase the light absorption rate of the film and reduce the optical band gap. The reduced bandgap can facilitate the transport of carriers. After Nd-Cr co-doping, the leakage current of the film is effectively reduced, which is near four orders of magnitude lower than the leakage current density of the pristine BiFeO3 film. The reduction of leakage current will enhance the ferroelectric polarization. The enhancement of ferroelectric polarization is more favorable for the separation of photogenerated carriers. Compared with the pristine BiFeO3 film, the short circuit photocurrent density, open circuit photovoltage and power conversion efficiency of Nd-Cr co-doped BiFeO3 film are all clearly improved. The Nd-Cr co-doped BiFeO3 films exhibited largely enhanced photovoltaic property, which favored the practical application of BiFeO3 -based films in photovoltaic devices.
Accession Number: WOS:000521128800017
ISSN: 0040-6090
Full Text: https://www.sciencedirect.com/science/article/pii/S0040609020300675?via%3Dihub