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Physical Properties of [A(6)Cl][Fe24Se26](A = K, Rb) with Self-Similar Structure*

本站小编 Free考研/2020-04-17

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Physical Properties of [A(6)Cl][Fe24Se26](A = K, Rb) with Self-Similar Structure*
文献类型:期刊
通讯作者:Lei, HC (reprint author), Renmin Univ China, Dept Phys, Beijing 100872, Peoples R China.
期刊名称:CHINESE PHYSICS LETTERS影响因子和分区
年:2020
卷:37
期:1
ISSN:0256-307X
关键词:74; 50; +r; 75; 20; Ck; 75; 30; -m; 75; 30; Cr
所属部门:物理学系
摘要:We have successfully synthesized two novel compounds [A(6)Cl][Fe24Se26] (A = K, Rb). The key structural units of them are FeSe octamers, consisting of edge-shared FeSe4 tetrahedra. Two kinds of FeSe octamer layers with different connection configurations stack along the c axis, forming a three-dimensional (3D) TiAl3-type structure. Interestingly, the 3D structural topology of these ocatmers in one unit cell is similar to the local atomic arrangement of themselves, i.e., self-similarity in struct ...More
We have successfully synthesized two novel compounds [A(6)Cl][Fe24Se26] (A = K, Rb). The key structural units of them are FeSe octamers, consisting of edge-shared FeSe4 tetrahedra. Two kinds of FeSe octamer layers with different connection configurations stack along the c axis, forming a three-dimensional (3D) TiAl3-type structure. Interestingly, the 3D structural topology of these ocatmers in one unit cell is similar to the local atomic arrangement of themselves, i.e., self-similarity in structure. Physical property characterizations indicate that both the compounds exhibit insulating antiferromagnetism with Neel temperatures T-N similar to 110 K and 75 K for [K6Cl][Fe24Se26] and [Rb6Cl][Fe24Se26]. ...Hide

DOI:10.1088/0256-307X/37/1/017401
百度学术:Physical Properties of [A(6)Cl][Fe24Se26](A = K, Rb) with Self-Similar Structure*
语言:外文
基金:National Key R&D Program of China [2016YFA0300504]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [11574394, 11774423, 11822412]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities; Research Funds of Renmin University of China (RUC) [15XNLQ07, 18XNLG14, 19XNLG17]
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