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浙江省合成革行业挥发性有机物污染特征及排放系数

本站小编 Free考研考试/2021-12-31

中文关键词合成革挥发性有机物 (VOCs)排放系数排放特征物料衡算 英文关键词synthetic leathervolatile organic compounds(VOCs)emission coefficientemission characteristicsmaterial balance
作者单位E-mail
徐佳琦浙江工业大学环境学院, 杭州 3100142532580121@qq.com
王浙明浙江省环境保护科学设计研究院, 杭州 310007
宋爽浙江工业大学环境学院, 杭州 310014
徐志荣浙江省环境保护科学设计研究院, 杭州 310007zhirong.x@gmail.com
姚轶浙江省环境保护科学设计研究院, 杭州 310007
中文摘要 以2015年浙江省175家合成革企业调研数据为基础,分析当前浙江省合成革行业挥发性有机物(VOCs)污染治理情况,通过研究筛选出161家重点企业,分析合成革行业污染基本排放特征并计算其VOCs排放系数.结果表明,绝大部分企业对废气采取治理措施,但聚氨酯(PU)后处理工艺没有废气收集和处理设施;绝大部分企业使用的是溶剂型原辅材料,废气中VOCs的主要污染因子为二甲基甲酰胺(DMF)、甲苯、乙酸甲酯、丙酮、乙酸乙酯和丁酮等物质;全省合成革行业的VOCs排放系数均值为0.168 kg·m-2.其中聚氨酯平均排放系数0.170 kg·m-2,聚氯乙烯(PVC)排放系数为0.142 kg·m-2;聚氨酯湿法工艺排放系数均值为0.191 kg·m-2,聚氨酯干法工艺VOCs排放系数均值为0.179 kg·m-2,聚氨酯后处理工艺VOCs排放系数均值为0.120 kg·m-2. 英文摘要 Based on the survey of 175 synthetic leather enterprises in Zhejiang Province, China, in 2014, this paper analyzes the control of volatile organic compounds (VOCs) and, ultimately, screened 161 key enterprises for further research. The results showed that most enterprises take measures to control waste gas; however, there is a distinct problem with the efficiency of exhaust gas collection. The industry used Solvent-based materials. The main VOC pollutants were DMF, toluene, methyl acetate, acetone, ethylacetate, and butanone. The VOC emission coefficient of the synthetic leather industry in Zhejiang was 0.168 kg·m-2. The industry includes polyurethane and polyvinyl chloride processes, for which VOC emission coefficients were 0.170 kg·m-2 and 0.142 kg·m-2, respectively. In addition, the emission coefficient of polyurethane wet processes was 0.191 kg·m-2 and that of dry processes was 0.179 kg·m-2. The emission coefficient for VOCs in post-treatment processes was 0.120 kg·m-2.

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