中文关键词黑色岩系农田土壤农作物重金属赋存形态 英文关键词black shaleagricultural soilscropsheavy metalsspeciation

作者	单位	E-mail
刘意章	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081	liuyizhang@mail.gyig.ac.cn
肖唐付	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081 广州大学环境科学与工程学院, 广州 510006	tfxiao@gzhu.edu.cn
熊燕	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081 贵阳学院生物与环境工程学院, 贵阳 550005
宁增平	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081
双燕	重庆地质矿产研究院外生成矿与矿山环境重庆市重点实验室, 重庆 400042
李航	重庆地质矿产研究院外生成矿与矿山环境重庆市重点实验室, 重庆 400042
马良	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081 中国科学院大学, 北京 100049
陈海燕	中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳 550081 中国科学院大学, 北京 100049

中文摘要 为探明高地质背景区农田土壤与农作物系统中重金属富集与转运特征，通过对采自重庆黑色岩系高镉地质背景区的土壤和农作物样品进行分析，并与其他典型黑色页岩区域进行对比研究.发现研究区部分农田土壤pH极低；Cd、Cr、Ni和Zn显著富集.土壤样品Cd的超标率为100%，其次为Cr和Ni，91.3%的土壤样品Cd污染级别为严重污染及以上.土壤Zn、Cu、Cr和Ni的残渣态占比为80%以上，Cd和Pb较低；弱酸提取态Cd占比27.0%±6.4%，Zn和Ni次之.黑色岩系母质风化导致研究区土壤重金属富集，Cd是区域内的特征污染元素，其生物有效性较高，并易于在农作物中富集.Cd的转运系数高于其他元素，农作物中Cd的富集和污染程度最高，特别是叶类蔬菜，平均Cd含量（干重）高达11.5 mg·kg^-1，不适于种植和食用；部分农作物Cr超标，存在一定风险.因此，有必要对研究区农田土壤进行污染等级划分，实行科学管控，并进行农作物种植结构调整，以保障当地人群健康. 英文摘要 In order to investigate the accumulation and transfer of heavy metals in agricultural soils and crops in an area with a high geochemical background of cadmium, soil and crop samples from a black shale outcropped area in Chongqing were collected and analyzed, and the results were then compared with those from other representative black shale outcropped areas. The results showed that some soil samples had a very low pH, and the metals Cd, Cr, Ni, and Zn were enriched. Cadmium concentrations in soil samples exceeded the safety limit, followed by Cr and Ni. Overall, 91.3% of soil samples were heavily to extremely polluted by Cd. The residual fractions accounted for more than 80% of the total metals, except for Cd and Pb. The weak acid soluble fraction of Cd accounted for 27.0%±6.4% of the total Cd, followed by Zn and Ni. The results demonstrate that weathering of black shales can result in elevated heavy metals in soils, and Cd is the primary contaminant in local soils. The high bioavailability of Cd and the high acidity of soils induced the enrichment of Cd in local crops. Cadmium has a higher transfer factor than other metals, and the crops were seriously polluted by Cd, particularly the leaf vegetables, which presented a high concentration of 11.5 mg·kg^-1 based on dry weight, and thus, these vegetables are not suitable for cultivating as food stuff. In addition, the risks from Cr should be of concern as well. Therefore, it is recommended that countermeasures be carried out to address the pollution situation, for example, by classifying the pollution levels of agricultural soils and adjusting the planting structures accordingly to reduce the health risks to local inhabitants.

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