关键词: 电子轨迹/
氢分子离子/
强激光脉冲/
电离增强
English Abstract
Internuclear-distance-dependent ionization of H2+ in strong laser field in a classical perspective
Yu Zu-Qing,Yang Wei-Ji,
He Feng
1.Key Laboratory for Laser Plasma(Ministry of Education), Collaborative Innovation Center of IFSA(CICIFSA), Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China
Fund Project:Project supported by the National Natural Science Foundation of China (Grant Nos. 11322438, 11574205).Received Date:06 June 2016
Accepted Date:27 June 2016
Published Online:05 October 2016
Abstract:Ionizations of atoms and molecules in strong laser fields are fundamental processes of ultrafast physics. Compared with atom ionization, molecular ionization is very complex due to the existence of multi Coulomb centers. As a simplest molecule, H2+ has been widely used to explore new phenomena of molecules in strong laser fields. One of the notable processes in H2+ ionization is charge resonance enhanced ionization (CREI), in which the ionization rate is enhanced substantially when the internuclear distances are around 6 a.u. and 10 a.u. CREI has been extensively studied by numerically simulating the time-dependent Schrödinger equation. While quantum calculations provide accurate ionization rates, the mechanism governing the CREI is not revealed in such ab-initio calculations. On the contrary, the calculations based on the classical trajectories Monte-Carlo assembly may offer an intuitive picture for CREI though some quantum information is not included. In this paper, we revisit the CREI of H2+ in a strong infrared laser field by Monte-Carlo simulation. By initializing ten-thousand classical points whose initial positions and velocities satisfy the field-free Hamiltonian of H2+, we solve the classical Newtonian equation and obtain the trajectories of all particles, from which one may analyze the particle velocities, energies, etc. We count the ionization events by diagnosing the particle energy after the laser interaction. If the sum of the kinetic energy and potential energy is larger than 0, we set it as an ionization event. The ionization rate is calculated by collecting all ionization events and normalizing it with the total particle number involved in the calculation. By setting the internuclear distances to be different values, we obtain the ionization rate as a function of internuclear distance. Our simulation shows that the ionization probability is greatly enhanced when the internuclear distance is about 5 to 6 a.u. by employing a 1064 nm, 4×1013 W/cm2, five cycles laser pulse. By tracing the particle trajectory, we find that the electron usually gains the energy from the laser field by circulating one nucleus, then passes through the interatomic barrier and moves around the other nucleus before being ionized. By looking into the relationship between the ionization probability and the laser-distorted Coulomb potential at different internuclear distances, we find that the ionization probability is maximum when the energy difference between the ground state and the interatomic Coulomb barrier, or between the ground state and the saddle value of the laser-distorted potential, is minimum. The classical calculation of the ionization of H2+ interacting with intense laser field reproduces the qualitative features of the corresponding quantum-mechanical calculation. It offers an intuitive physical picture of the tunneling ionization of molecules through investigating the classical trajectories and provides a new perspective to inspect the intriguing phenomena in quantum systems.
Keywords: electron trajectory/
H2+/
strong laser pulse/
enhanced ionization
