中文关键词:硅氢化反应催化过渡金属 英文关键词:Hydrosilylationreactionn, Catalysis, Transitionmetal 基金项目:

作者	单位	E-mail
宋国强	上虞京新药业有限公司 浙江省绍兴市上虞区 312369	maison_song@126.com
霍利岭	河北师范大学汇华学院
李竞草	上虞京新药业有限公司 浙江省绍兴市上虞区 312369	jingcaoli769@163.com

摘要点击次数:112 全文下载次数:0 中文摘要: 过渡金属催化C-H键活化的硅氢化反应在材料科学和合成化学领域里具有重要意义。有机硅化合物在纺织、橡胶、机械、日化等材料领域有广泛应用,此外,它还是重要的有机合成中间体,作为亲核试剂应用到Hiyama偶联反应,反应具有经济、高效、环境友好等特点。近些年来,很多课题组在该领域进行研究,并取得了一定的成果_^[1]。我们将从过渡金属催化芳基/烷基C-H键活化的硅氢化反应出发,介绍近些年在此领域的研究进展。 英文摘要: Transition metal catalyzed hydrogenation of C-H bond is of great significance in the fields of materials science and synthetic chemistry. Silicone compounds are widely used in textile, rubber, machinery, daily chemical and other materials. In addition, they are also important organic synthesis intermediates. As nucleophile, they are applied to Hiyama coupling reaction, and the reaction has the characteristics of economy, high efficiency and environment friendly. In recent years, many research groups have carried out researches in this field and achieved certain results. We will introduce the recent progress in this field, starting from the hydrogenation reaction of aryl/alkyl C-H bond activation catalyzed by transition metals. 查看全文查看/发表评论下载PDF阅读器 相关附件：版权转让声明书 -->