基本信息
陈金铸 男 博导 广州能源研究所
电子邮件：chenjz@ms.giec.ac.cn
电话/传真：(+86)-**
通信地址：广州市 天河区 五山 能源路2号
邮政编码：510640


研究领域能源化工, 绿色化学, 多相催化
生物质催化转化, 生物质基化学品, 生物质基材料
二氧化碳资源化?
个人简历简历：
陈金铸，男，1978年生。中国科学院广州能源研究所研究员、博士生导师，中国科学院引进海外杰出人才(中国科学院“百人计划”)。主要从事与新能源和可再生能源相关的能源催化与绿色化学的研究，包括生物质能利用和二氧化碳资源化。2000年大学本科毕业于安徽大学，2005年博士毕业于中国科学院大连化学物理研究所，2005－2007年在美国亚力桑那大学(University of Arizona)做博士后，2007－2008年在美国伊利诺伊大学(University of Illinois, UIUC)做博士后，2008－2010年在美国布鲁克海文国家实验室(Brookhaven National Laboratory)任研究助理。2010年起担任中国科学院广州能源研究所研究员、博士生导师，并入选中国科学院“百人计划”。主持国家自然科学基金、中国科学院“百人计划”、广东省自然科学基金等，承担国家973计划、国家863计划等，参与美国能源部(DOE)、美国国家科学基金会(NSF)、美国国家卫生院(NIH)等项目。已在J. Am. Chem. Soc.，ACS Catal.，ChemSusChem，Green Chem.，J. Mater. Chem. A，ACS Sustainable Chem. & Eng.等国际期刊上发表SCI 收录论文54篇，申请中国发明专利15项，参加国际学术报告10次。曾荣获2004年度中国科学院院长优秀奖，2012年度中国科学院广州分院、广东省科学院“优秀青年科技工作者”。2008年起担任美国化学会和美国Sigma Xi 协会会员。目前是30家国际核心刊物Angew. Chem. Int. Ed.，Energy & Environ. Sci.，Chem. Commun.等的评审专家。

学习工作经历：
1) 2010/04－至今, 中国科学院广州能源研究所, 研究员, 博士生导师, 中国科学院引进海外杰出人才(中国科学院"百人计划")
2) 2008/01－2010/04 美国布鲁克海文国家实验室(Brookhaven National Laboratory), 博士后
3) 2007/04－2008/01 美国伊利诺伊大学(University of Illinois, UIUC), 博士后
4) 2005/12－2007/04 美国亚利桑那大学(University of Arizona), 博士后
5) 2005/07－2005/12 中国科学院大连化学物理研究所, 研究助理
6) 2000/09－2005/07 中国科学院大连化学物理研究所, 博士学位
7) 1996/09－2000/07 安徽大学, 学士学位

相关简介：
陈金铸研究员 广州能源所个人主页
发表论文54) Aibing Chen, Tiancong Zhao, Hui Gao, Limin Chen, Jinzhu Chen*, Yifeng Yu. “Titanate Nanotube-Promoted Chemical Fixation of Carbon Dioxide to Cyclic Carbonate: A Combined Experimental and Computational Study.” Catalysis Science & Technology, 2015, DOI: 10.1039/C5CY01024A. Article first published online: Aug. 20, 2015.

53) Hui Gao, Jinzhu Chen*. “Hydrogenation of Biomass-Derived Levulinic Acid to γ-Valerolactone Catalyzed by PNP-Ir Pincer Complexes: A Computational Study.” Journal of Organometallic Chemistry, 2015, 797, 165-170.

52) Yuanyuan Guo, Jinzhu Chen*. “Bicomponent Assembly of VO2 and Polyaniline-Functionalized CNT for Selective Oxidation of Biomass-Based 5-Hydroxymethylfurfural to 2,5-Diformylfuran.” ChemPlusChem, 2015, DOI: 10.1002/cplu.**. Article first published online: Aug. 19, 2015.

51) Jun Zhang, Jinzhu Chen*, Yuanyuan Guo, Limin Chen. “Effective Upgrade of Levulinic Acid into γ-Valerolactone over an Inexpensive and Magnetic Catalyst Derived from Hydrotalcite Precursor.” ACS Sustainable Chemistry & Engineering, 2015, 3(8), 1708-1714.

50) Guangyue Xu, Jianhua Guo, Ying Zhang*, Yao Fu, Jinzhu Chen, Longlong Ma, Qingxiang Guo. “Selective Hydrogenation of Phenol to Cyclohexanone over Pd–HAP Catalyst in Aqueous Media.” ChemCatChem, 2015, 7(16), 2485-2492.

49) Aibing Chen, Yunzhao Zhang, Jinzhu Chen*, Limin Chen, Yifeng Yu. “Metalloporphyrin-Based Organic Polymer for Carbon Dioxide Fixation to Cyclic Carbonate.” Journal of Materials Chemistry A, 2015, 3(18), 9807-9816.

48) Jinzhu Chen*, Ruliang Liu, Yuanyuan Guo, Limin Chen, Hui Gao. “Selective Hydrogenation of Biomass-Based 5-Hydroxymethylfurfural over Catalyst of Palladium Immobilized on Amine-Functionalized Metal–Organic Frameworks.” ACS Catalysis, 2015, 5(2), 722-733.

47) Jinzhu Chen*, Jiawei Zhong, Yuanyuan Guo, Limin Chen. “Ruthenium Complex Immobilized on Poly(4-vinylpyridine)-Functionalized Carbon-Nanotube for Selective Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran.” RSC Advances, 2015, 5(8), 5933-5940.

46) Hui Gao, Limin Chen, Jinzhu Chen*, Yuanyuan Guo, Daiqi Ye. “A Computational Study on the Hydrogenation of CO2 Catalyzed by a Tetraphos-Ligated Cobalt Complex: Monohydride vs. Dihydride.” Catalysis Science & Technology, 2015, 5(2), 1006-1013.

45) Jing Huang, Jinzhu Chen*, Hui Gao, Limin Chen. “Kinetic Aspects for the Reduction of CO2 and CS2 with Mixed-Ligand Ruthenium (II) Hydride Complexes Containing Phosphine and Bipyridine.” Inorganic Chemistry, 2014, 53(18), 9570-9580.

44) Jinzhu Chen*, Yuanyuan Guo, Jiayi Chen, Lu Song, Limin Chen. “One-step Approach for 2,5-Diformylfuran from Fructose by Proton- and Vanadium-Containing Graphitic Carbon Nitride.” ChemCatChem, 2014, 6(11), 3174-3181.

43) Shengpei Wang, Jinzhu Chen*, Limin Chen. “Selective Conversion of Cellulose into Ethylene Glycol over Metal–Organic Framework-Derived Multifunctional Catalysts.” Catalysis Letters, 2014, 144(10), 1728-1734.

42) Jiawei Zhong, Jinzhu Chen*, Limin Chen. “Selective Hydrogenation of Phenol and Related Derivatives.” Catalysis Science & Technology, 2014, 4(10), 3555-3569. (综述 Minireview).

41) Ruliang Liu, Jinzhu Chen*, Limin Chen. Yuanyuan Guo, Jiawei Zhong. “One-Step Approach to 2,5-Diformylfuran from Fructose by Using a Bifunctional and Recyclable Acidic Polyoxometalate Catalyst.” ChemPlusChem, 2014, 79(10), 1448-1454.

40) Jinzhu Chen*, Ruliang Liu, Hui Gao, Limin Chen, Daiqi Ye. “Amine-Functionalized Metal-Organic Frameworks for the Transesterification of Triglycerides.” Journal of Materials Chemistry A, 2014, 2(20), 7205-7213.

39) Maria E. Carroll, Jinzhu Chen, Danielle E. Gray, James C. Lansing, Thomas B. Rauchfuss*, David Schilter, Phillip I. Volkers, Scott R. Wilson. “Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates.” Organometallics, 2014, 33(4), 858-867.

38) Jinzhu Chen*, Kegui Li, Limin Chen, Ruliang Liu, Xing Huang, Daiqi Ye. “Conversion of Fructose into 5-Hydroxymethylfurfural Catalyzed by Recyclable Sulfonic Acid–Functionalized Metal–Organic Frameworks.” Green Chemistry, 2014, 16(5), 2490-2499.

37) Wei Zhang, Jinzhu Chen*, Ruliang Liu, Shengpei Wang, Limin Chen, Kegui Li. “Hydrodeoxygenation of Lignin-Derived Phenolic Monomers and Dimers to Alkane Fuels over Bifunctional Zeolite-Supported Metal Catalysts.” ACS Sustainable Chemistry & Engineering, 2014, 2(4), 683-691.

36) Yasuo Matsubara*, Sean E. Hightower, Jinzhu Chen, David C. Grills, Dmitry E. Polyansky, James T. Muckerman, Koji Tanaka, Etsuko Fujita*. “Reactivity of a fac-ReCl(a-diimine)(CO)3 Complex with an NAD+ Model Ligand toward CO2 Reduction.” Chemical Communications, 2014, 50(6), 728-730.

35) Jinzhu Chen*, Guoying Zhao, Limin Chen. “Efficient Productions of 5-Hydroxymethylfurfural and Alkyl Levulinate from Biomass Carbohydrate Using Ionic Liquid-Based Polyoxometalate Salts.” RSC Advances, 2014, 4(8), 4194-4202.

34) Young Jun Seo, Lisa Muench, Alicia Reid, Jinzhu Chen, Yeona Kang, Jacob M. Hooker*, Nora D. Volkow, Joanna S. Fowler, Sung Won Kim*. “Radionuclide labeling and Evaluation of Candidate Radioligands for PET Imaging of Histone Deacetylase in the Brain.” Bioorganic & Medicinal Chemistry Letters, 2013, 23(24), 6700-6705.

33) Gabriel B. Hall, Jinzhu Chen, Charles A. Mebi, Noriko Okumura, Matthew T. Swenson, Stephanie E. Ossowski, Uzma I. Zakai, Gary S. Nichol, Dennis L. Lichtenberger*, Dennis H. Evans*, Richard S. Glass*. “Redox Chemistry of Non-Innocent Quinones Annulated to 2Fe2S Cores.” Organometallics, 2013, 32 (21), 6605-6612.

32) Aibing Chen, Yonglei Li, Jinzhu Chen*, Guoying Zhao, Longlong Ma, Yifeng Yu. “Selective Hydrogenation of Phenol and Derivatives over Polymer-Functionalized Carbon-Nanofiber-Supported Palladium Using Sodium Formate as the Hydrogen Source.” ChemPlusChem, 2013, 78(11), 1370-1378.

31) Ruliang Liu, Jinzhu Chen*, Xing Huang, Limin Chen, Longlong Ma, Xinjun Li. “Conversion of Fructose into 5-Hydroxymethylfurfural and Alkyl Levulinates Catalyzed by Sulfonic Acid-Functionalized Carbon Materials.” Green Chemistry, 2013, 15(10), 2895-2903.

30) Jinzhu Chen*, Shengpei Wang, Jing Huang, Limin Chen*, Longlong Ma, Xing Huang. “Conversion of Cellulose and Cellobiose into Sorbitol Catalyzed by Ruthenium Supported on a Polyoxometalate/Metal-Organic Framework Hybrid.” ChemSusChem, 2013, 6(8), 1545-1555.

29) Jinzhu Chen*, Jing Huang, Limin Chen, Longlong Ma*, Tiejun Wang, Uzma I. Zakai. “Hydrodeoxygenation of Phenol and Derivatives over an Ionic-Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.” ChemCatChem, 2013, 5(6), 1598-1605.

28) Jinzhu Chen*, Wei Zhang, Limin Chen, Longlong Ma*, Hui Gao, Tiejun Wang. “Direct Selective Hydrogenation of Phenol and Derivatives over Polyaniline-Functionalized Carbon-Nanotube-Supported Palladium.” ChemPlusChem, 2013, 78(2), 142-148. (封面论文 Cover page and cover profile)

27) Aibing Chen, Guoying Zhao, Jinzhu Chen*, Limin Chen, Yifeng Yu. "Selective Hydrogenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Palladium Catalyst in Aqueous Media.” RSC Advances, 2013, 3(13), 4171-4175.

26) Hui Gao, Jing Huang, Limin Chen, Ruliang Liu, Jinzhu Chen*. “Synthesis, Characterization and Computational Study of Heterobimetallic CoFe Complexes for Mimicking Hydrogenase.” RSC Advances, 2013, 3(11), 3557-3565.

25) Jinzhu Chen, Aaron K. Vannucci, Charles A. Mebi, Noriko Okumura, Susan C. Borowski, L. Tori Lockett, Matthew Swenson, Dennis L. Lichtenberger, Dennis H. Evans, Richard S. Glass* .“Catalysis of Electrochemical Reduction of Weak Acids to Produce H2: Role of O-H…S Hydrogen Bonding.” Phosphorus, Sulfur, and Silicon and the Related Elements, 2011, 186(5), 1288-1292.

24) Zhaohui Liu, Jinzhu Chen, Yuyuan Zhang, Liangpeng Wu, Xinjun Li*. “The Effect of Sandwiched Ag in the Wall of TiO2 Nanotube on the Photo-Catalytic Performance.” Materials Chemistry and Physics, 2011, 128(1-2), 1-5.

23) Jing Wang, Yanhe Han, Manzhi Feng, Jinzhu Chen, Xinjun Li*, Shanqing Zhang. “Preparation and Photoelectrochemical Characterization of WO3/TiO2 Nanotube Array Electrodes.” Journal of Materials Science, 2011, 46(2), 416-421.

22) Yuyuan Zhang, Xinjun Li*, Manzhi Feng, Fengling Zhou, Jinzhu Chen. "Photoelectrochemical Performance of TiO2-Nanotube-Array Film Modified by Decoration of TiO2 via Liquid Phase Deposition.” Surface & Coatings Technology, 2010, 205(7), 2572-2577.

21) Jinzhu Chen, Aaron K. Vannucci, Charles A. Mebi, Noriko Okumura, Susan C. Borowski, Matthew Swenson, L. Tori Lockett, Dennis H. Evans*, Richard S. Glass*, Dennis L. Lichtenberger*. “Synthesis of Diiron Hydrogenase Mimics Bearing Hydroquinone and Related Ligands. Electrochemical and Computational Studies of the Mechanism of Hydrogen Production and the Role of O-H…S Hydrogen Bonding.” Organometallics, 2010, 29(21), 5330-5340.

20) Jinzhu Chen, David J. Szalda, Etsuko Fujita, Carol Creutz*. “Iron(II) and Ruthenium(II) Complexes Containing P, N, and H Ligands: Structure, Spectroscopy, Electrochemistry, and Reactivity.” Inorganic Chemistry, 2010, 49(20), 9380-9391.

19) Yuyuan Zhang, Jinzhu Chen, Xinjun Li*. “Preparation and Photocatalytic Performance of Anatase/Rutile Mixed-Phase TiO2 Nanotubes.” Catalysis Letters, 2010, 139(3-4), 129-133.

18) Weiqiang Tan, Zhengkun Yu*, Bing Liu, Kaikai Wu, Zishuang Liu, Jinzhu Chen. “Synthesis and Structural Characterization of (CH2)n-Bridged Indenyl-Pyrazoles and Their Cyclopentadienyl Nickel(II) Complexes.” Journal of Organometallic Chemistry, 2009, 694(2), 199-206.

17) Weiqiang Tan, Zhengkun Yu*, Wei He, Liandi Wang, Jie Sun, Jinzhu Chen. "A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl-(CH2)2-Bridged Bis(pyrazole).” Organometallics, 2008, 27(19), 4833-4836.

16) Phillip I. Volkers, Christine A. Boyke, Jinzhu Chen, Thomas B. Rauchfuss*, C. Matthew Whaley, Scoff R. Wilson, Haijun Yao. “Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources.” Inorganic Chemistry, 2008, 47(15), 7002-7008.

15) Greg A. N. Felton, Aaron K. Vannucci, Jinzhu Chen, L. Tori Lockett, Noriko Okumura, Benjamin J. Petro, Uzma I. Zakai, Dennis H. Evans*, Richard S. Glass*, Dennis L. Lichtenberger*. “Hydrogen Generation from Weak Acids: Electrochemical and Computational Studies of a Diiron Hydrogenase Mimic.” Journal of the American Chemical Society, 2007, 129(41), 12521-12530.

14) Zhengkun Yu*, Fanlong Zeng, Xiaojiao Sun, Haixia Deng, Jinhua Dong, Jinzhu Chen, HM Wang, CX. Pei, “Two pseudo-N3 Ligands and the Catalytic Activity of Their Ruthenium(II) Complexes in Transfer Hydrogenation and Hydrogenation of Ketones.” Journal of Organometallic Chemistry, 2007, 692(11), 2306-2313.

13) Zhaoyan Zheng, Jinzhu Chen, Ning Luo, Zhengkun Yu*, Xiuwen Han. “Efficient Demetalation of Fischer Alkoxy- and Amino-Biscarbene Complexes of Chromium via CO-Promoted Sulfuration and Selenylation.” Organometallics, 2006, 25(22), 5301-5310.

12) Zhaoyan Zheng, Jinzhu Chen, Zhengkun Yu*, Xiuwen Han. “Oxidative Demetalation of Fischer Alkoxy Carbene Complexes with Stoichiometric Pyridine N-oxide and NaBH4-Promoted Demetalation of Fischer Iminocarbene Complexes with Sulfur and Selenium.” Journal of Organometallic Chemistry, 2006, 691(17), 3679-3692.

11) Xiaodan Zhao, Zhengkun Yu*, Fanlong Zeng, Jinzhu Chen, Xiaowei Wu, Sizhong Wu, Wenjing Xiao, Zhaoyan Zheng. “Highly Efficient Route to Diselenides from the Reactions of Imines and Selenium in the Presence of Carbon Monoxide and Water.” Advanced Synthesis & Catalysis, 2005, 347(6), 877-882.

10) Jinzhu Chen, Zhengkun Yu*, Zhaoyan Zheng, Kaichun Gu, Sizhong Wu, Fanlong Zeng, Weiqiang Tan, Xiaowei Wu, Wenjing Xiao. “Chemoselective Stepwise Demetalation of Unusually Stable Fischer Biscarbene Complexes by Domino [4+2]/[2+2] Cycloaddition of 2-Isopropenyl-2-oxazoline to 1-Alkynyl Fischer Carbene Complexes of Chromium and Tungsten.” Organometallics, 2005, 24(2), 302-308.

9) Kaichun Gu, Jinzhu Chen, Zhaoyan Zheng, Sizhong Wu, Xiaowei Wu, Xiuwen Han, Zhengkun Yu*. “Synthesis and Structural Characterization of (Pyrazolyl)alkenyl Fischer Carbene Complexes of Chromium and Tungsten.” Polyhedron, 2005, 24(1), 173-180.

8) Jinzhu Chen, Gang Ling, Zhengkun Yu*, Sizhong Wu, Xiaodan Zhao, Xiaowei Wu, Shiwei Lu*. “N-Aryl Amides from Selenium-Catalyzed Reactions of Nitroaromatics and Amides in the Presence of Carbon Monoxide and Mixed Organic Bases.” Advanced Synthesis & Catalysis, 2004, 346(11), 1267-1270.

7) Jinzhu Chen, Shiwei Lu*. “Synthesis of Substituted Pyridyl Ureas by Selenium Dioxide- Catalyzed Carbonylation.” Applied Catalysis A-General, 2004, 261(2), 199-203.

6) Jinzhu Chen, Gang Ling, Shiwei Lu*. “Synthesis of New Unsymmetric N,N’-Dipyridylurea Derivatives by Selenium and Selenium Dioxide-Catalyzed Reductive Carbonylation of Substituted Nitropyridines.” Tetrahedron, 2003, 59(41), 8251-8256.

5) Jinzhu Chen, Gang Ling, Shiwei Lu*. “Synthesis of N-Phenyl-N’-pyrimidylurea Derivatives by Selenium- or Selenium Dioxide-Catalyzed Reductive Carbonylation of Nitroaromatics.” European Journal of Organic Chemistry, 2003, 17, 3446-3452.

4) Jinzhu Chen, Aidong Peng, Shiwei Lu*. “Some Progress in the Selenium-Catalyzed Carbonylation Reaction.” Journal of the Graduate School of the Chinese Academy of Sciences, 2003, 20(1), 73-84.

3) Gang Ling, Jinzhu Chen, Shiwei Lu*. “Selenium-Catalyzed Carbonylation of Substituted Nitrobenzenes with Aminomethylpyrimidines as Co-Reagents to Synthesize N-Phenyl-N’-methylpyrimidylurea Derivatives.” Journal of Molecular Catalysis A-Chemical, 2003, 202(1-2), 23-29.

2) Gang Ling, Jinzhu Chen, Shiwei Lu*. “Synthesis of Substituted Heterocyclic Ureas by Selenium-Catalysed Carbonylation Using Carbon Monoxide.” Journal of Chemical Research-Synopses, 2003, 7, 442-444.

1) Gang Ling, Jinzhu Chen, Shiwei Lu*. “Synthesis of Benzoxazolinone by Selenium-Catalyzed Carbonylation with Carbon Monoxide.” Chinese Journal of Catalysis, 2003, 24(1), 5-6.
科研项目1) 2006/01－2008/12, 国家自然科学基金(青年科学基金项目), “多亚甲基桥联的环戊二烯基－吡唑基混合配体的金属配合物的合成与结构研究” (**), 项目负责人, 24万;

2) 2012/01－2015/12, 国家自然科学基金(面上项目), “光合作用碳反应的模拟－水加速CO2还原的机理研究” (**), 项目负责人, 60万;

3) 2015/01－2018/12, 国家自然科学基金(面上项目), “生物质基呋喃二甲醛的绿色合成” (**), 项目负责人, 82万;

4) 2010/04－2013/04, 中国科学院“百人计划”启动, “金属氢化物水相催化还原CO2制备燃料的研究”, 项目负责人, 100万;

5) 2011/04－2014/04, 中国科学院“百人计划”择优支持, “可再生能源高效催化转化实验平台的构建”, 项目负责人, 260万;

6) 2013/01－2014/12, 教育部留学回国人员科研启动基金, “木质素制备烷烃燃料反应中双功能催化剂协同效应可控构筑的研究”, 项目负责人, 3万;

7) 2011/10－2013/10, 广东省自然科学基金(面上项目), “基于木质素高效转化制备烷烃燃料新型催化剂的研究” (S**74), 项目负责人, 5万;

8) 2013/10－2015/10, 广东省自然科学基金(面上项目), “双功能催化剂催化纤维素转化的研究” (S**86), 项目负责人, 5万;

9) 2012/01－2013/12, 广州市科技计划, “基于生物油高效转化制备车用烷烃燃料新型催化剂的研究” (12C**), 项目负责人, 10万;

10) 2011/12－2012/12, 南开大学元素有机化学国家重点实验室开放基金, “光合作用碳反应模拟－水加速金属氢化物还原CO2机理研究” (201105), 项目负责人, 3万;

11) 2012/01－2016/12, 国家重点基础研究发展计划(国家973计划), “草本能源植物培育及化学催化为先进液体燃料的基础研究” (2012CB215300), 项目参与, 主持89万/总经费2787万;

12) 2012/01－2015/12, 国家高技术研究发展计划(国家863计划), “生物质水相催化合成生物航空燃油” (2012AA101806), 项目参与, 821万;

13) 2011/01－2012/12, 中国科学院广州能源研究所所长基金重大项目培育专项, “太阳能光解水直接分离制氢技术及实验系统装置” (Y107A31001), 项目参与, 40万;

14) 2011/01－2012/12, 中国科学院可再生能源与天然气水合物重点实验室开放课题, “功能化离子液体中CO2的催化转化制备燃料的研究” (Y007K11001), 项目参与, 2万;

15) 2012/01－2014/12, 国际科学基金(International Foundation for Science, IFS), “Catalytic Conversion of Biomass-Derived Carbohydrates to High-quality Liquid Bio-Fuels in Novel Bifunctional Catalytic System” (F/5203-1), 项目监管(郭御卷), 1万美金;

16) 2012/07－2013/06, 国家自然科学基金(外国青年学者研究基金项目), “Catalytic Conversion of Biomass-derived Carbohydrates to High-quality Liquid Bio-fuels in Bifunctional Catalytic System” (**), 项目监管(Uzma I. Zakai), 20万;

17) 2014/01－2016/12, 国家自然科学基金(青年科学基金项目), “氢化酶活性位的模拟：钴、铁催化剂分子设计及产氢机理” (**), 项目监管(高辉), 25万;

18) 2015/01－2017/12, 国家自然科学基金(青年科学基金项目), “Ru内嵌含氮多级孔炭@介孔ZrO2包覆型催化剂上呋喃类化合物水相加氢反应的研究” (**), 项目监管(黄形), 25万;

19) 2013/10－2015/10, 广东省自然科学基金(博士启动项目), “二氧化碳储氢：新型钴、铁催化剂分子设计及机理研究” (S**28), 项目监管(高辉), 3万;

20) 2013/10－2015/10, 广东省自然科学基金(博士启动项目), “包覆型双功能催化剂的制备及其费托反应性能研究” (S**15), 项目监管(黄形), 3万;

21) 2015/01－2018/01, 广东省自然科学基金(博士启动项目), “生物质基木薯渣高值化转化制备山梨醇高效催化体系的构建” (S2014A**), 项目监管(张军), 10万;

22) 2011/07－2014/06, 中国科学院广州能源研究所所长创新基金, “化学模拟氢化酶活性位催化制备氢能源的反应机理研究” (Y107RG1001), 项目监管(高辉), 10万;

23) 2012/07－2015/06, 中国科学院广州能源研究所所长创新基金, “金属有机骨架材料用于生物质基合成气的催化转化研究” (Y207RB1001), 项目监管(黄形), 10万;

24) 2012/01－2013/12, 中国科学院可再生能源与天然气水合物重点实验室基金, “双功能催化体系中木质素单体高效转化制备烷烃的研究” (Y207J11001), 项目监管(黄晶), 5万;

25) 2015/01－2016/12, 中国科学院可再生能源重点实验室基金, “木薯渣生物质高效转化制备六碳糖醇的基础研究” (Y507JA1001), 项目监管(张军), 5万;

26) 2013/01－2014/12, 广东省大气环境与污染控制重点实验室开放基金, “二氧化碳能源化技术应用于储氢体系中高效催化剂的研究”, 项目监管(高辉), 3万;

27) 2012/01－2014/12, 广东省大气环境与污染控制重点实验室开放基金, “Cu-Zn-Al-Zr@HZSM-5核壳结构催化剂上CO2加氢合成异构烷烃的研究”, 项目监管(黄形), 2万;

28) 2005/12－2007/04, 美国国家科学基金会(NSF), “Coupling redox processes to drive chemical reactivity: new catalysts for hydrogen production” (NSF CHE **), 项目参与;

29) 2007/04－2008/01, 美国国家卫生院(NIH), “Understanding how nature works with hydrogen: modeling the hydrogenases and related enzymes” (RO1 GM61153-01), 项目参与;

30) 2008/01－2010/04, 美国能源部(DOE), “New developments in “artificial photosynthesis”: catalyzing oxygen production from water.” “Fuel production from CO2 in water by hydride transfer reactions using earth-abundant metal catalysts” (DE-AC02-98CH10886), 项目参与.
团队骨干高辉 博士
1. 教育背景/工作简历
2011/07－至今, 中国科学院广州能源研究所, 助理研究员
2006/09－2011/06, 中山大学, 博士学位
2002/09－2006/06, 山西大学, 学士学位

2. 期刊论文
10) Hui Gao, Zhuofeng Ke, Nathan J. DeYonker, Juping Wang, Huiying Xu, Zong-Wan Mao, David Lee Phillips*, Cunyuan Zhao*. “Dinuclear Zn(II) Complex Catalyzed Phosphodiester Cleavage Proceeds Via a Concerted Mechanism: A Density Functional Theory Study.” Journal of the American Chemical Society, 2011, 133(9), 2904-2915.

9) Hui Gao, Jing Huang, Limin Chen, Ruliang Liu, Jinzhu Chen*. “Synthesis, Characterization and Computational Study of Heterobimetallic CoFe Complexes for Mimicking Hydrogenase.” RSC Advances, 2013, 3(11), 3557-3565.

8) Xuepeng Zhang, Hui Gao, Huiying Xu, Jianqiao Xu, Hui Chao, Cunyuan Zhao*. “A Density Functional Theory Study of the Hydrolysis Mechanism of Phosphodiester Catalyzed by a Mononuclear Zn(II) Complex.” Journal of Molecular Catalysis A: Chemical, 2013, 368, 53-60.

7) Hanlu Wang, Nathan J. DeYonker, Hui Gao, Caiping Tan, Xiting Zhang, Liangnian Ji, Cunyuan Zhao*, Zongwan Mao*. “Aquation and Dimerization of OsmiumII Anticancer Complexes: A Density Functional Theory Study.” RSC Advances, 2012, 2(2), 436-446.

6) Jinzhu Chen*, Wei Zhang, Limin Chen, Longlong Ma*, Hui Gao, Tiejun Wang. “Direct Selective Hydrogenation of Phenol and Derivatives over Polyaniline-Functionalized Carbon-Nanotube-Supported Palladium.” ChemPlusChem, 2013, 78(2), 142-148. (Cover Page and Cover Profile)

5) Hanlu Wang, Nathan J. DeYonker, Hui Gao, Liangnian Ji, Cunyuan Zhao*, Zongwan Mao*. “Mechanism of Aquation and Nucleobase Binding of Ruthenium (II) and Osmium (II) Arene Complexes: A Systematic Comparison DFT Study.” Journal of Organometallic Chemistry, 2012, 704, 17-28.

4) Hanlu Wang, Nathan J. DeYonker, Hui Gao, David Lee Phillips, Cunyuan Zhao*, Liangnian Ji, Zongwan Mao*. “Predicting the interactions of organometallic ruthenium ethylenediamine complexes with mononucleotides: insights from density functional theory.” RSC Advances, 2012, 2(20), 7849-7859.

3) Yuemeng Ji, Fenglei Cao, Hui Gao, Xiangzhi Li, Cunyuan Zhao*, Cheng-Yong Su, Jing-Yao Liu, Ze-Sheng Li. “On the Kinetic Mechanism of the Hydrogen Abstraction Reactions of the Hydroxyl Radical with CH3CF2Cl and CH3CFCl2: A Dual Level Direct Dynamics Study.” Journal of Computational Chemistry, 2010, 31(3), 510-519.

2) Juping Wang, Huiying Xu, Hui Gao, Cheng-Yong Su, David Lee Phillips*, Cunyuan Zhao*. “DFT Study on the Mechanism of Amides to Aldehydes Using Cp2Zr(H)Cl.” Organometallics, 2010, 29(1), 42-51.

1) Zhuofeng Ke, Yubing Zhou, Hui Gao, Cunyuan Zhao*, David Lee Phillips. “On the Mechanism and Stereochemistry of Chiral Lithium Carbenoid Promoted Cyclopropanation Reactions.” Chemistry-A European Journal, 2007, 13(23), 6724-6731.

3. 科研项目
1) 2014/01－2016/12, 国家自然科学基金(青年科学基金项目), “氢化酶活性位的模拟：钴、铁催化剂分子设计及产氢机理” (**), 项目负责人, 25万;

2) 2013/10－2015/10, 广东省自然科学基金(博士启动项目), “二氧化碳储氢：新型钴、铁催化剂分子设计及机理研究” (S**28), 项目负责人, 3万;

3) 2011/07－2014/06, 中国科学院广州能源研究所所长创新基金, “化学模拟氢化酶活性位催化制备氢能源的反应机理研究” (Y107R9), 项目负责人, 10万;

4) 2013/01－2014/12, 广东省大气环境与污染控制重点实验室开放基金, “二氧化碳能源化技术应用于储氢体系中高效催化剂的研究”, 项目负责人, 3万.

张军 博士
1. 教育背景/工作简历
2014/07－至今, 中国科学院广州能源研究所, 助理研究员
2009/09－2014/06, 华南理工大学, 轻工与食品学院, 制浆造纸国家重点实验室, 博士学位
2005/09－2009/06, 河南工业大学, 粮油食品学院, 学士学位

2. 期刊论文
16) Jun Zhang, ShuBin Wu, Bo Li, and HongDan Zhang. Advances in the Catalytic Production of Valuable Levulinic Acid Derivatives. ChemCatChem, 2012, 4, 1230–1237.

15) Jun Zhang, Ji-biao Li, Shu-Bin Wu, and Ying Liu. Advances in the Catalytic Production and Utilization of Sorbitol. Industrial & Engineering Chemistry Research, 2013, 52, 11799?11815.

14) Jun Zhang, Shaohua Xu, Shubin Wu, Ying Liu. Hydrogenation of fructose over magnetic catalyst derived from hydrotalcite precursor. Chemical Engineering Science, 2013, 99, 171–176.

13) Jun Zhang, Shubin Wu, Ying Liu. Direct Conversion of Cellulose into Sorbitol over a Magnetic Catalyst in an Extremely Low Concentration Acid System. Energy & Fuel, 2014, 36, 2018–2026.

12) Jun Zhang, Shubin Wu, Ying Liu, Bo Li. Hydrogenation of glucose over reduced Ni/Cu/Al hydrotalcite precursors. Catalysis Communications, 2013, 35, 23–26.

11) Jun Zhang, Shubin Wu, Bo Li, Hongdan Zhang. Direct conversion of cellobiose into sorbitol and catalyst deactivation mechanism. Catalysis Communications, 2012, 29, 180–184.

10) Jun Zhang, Jibiao Li, Shubin Wu, Ying Liu. Efficient conversion of maltose into sorbitol over magnetic catalyst in extremely low acid. BioResources, 2013, 8 (3), 4676–4686.

9) Jun Zhang, ShuBin Wu, HongDan Zhang, Bo Li. Conversion of glucose over SO42-/ZrO2-TiO2 catalysts in an extremely low acid system. BioResources, 2012, 7(3), 3984–3998.

8) Jun Zhang, Lu Lin, Junhua Zhang, Jianbin Shi. Efficient conversion of D-glucose into D-sorbitol over MCM-41 supported Ru catalyst prepared by a formaldehyde reduction process [J]. Carbohydrate Research, 2011, 346, 1327–1332.

7) J. ZHANG, H.-D. ZHANG, S.-B. WU, and B. LI. Conversion of high fructose corn syrup into 5-hydroxymethylfurfural in aqueous solution over sulfated titanium dioxide. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2014, 36, 2018–2026.

6) Jun Zhang, Shubin Wu, Bo Li. Catalytic performance of SO42-/TiO2 for the conversion of high fructose corn syrup. Advanced Materials Research, 2013, 666, 131–142.

5) 张军, 武书彬, 李擘, 万小芳. 木质纤维素转化制备山梨醇的研究进展. 食品安全质量检测学报, 2012, 3(5), 383–386.

4) 张军, 林鹿. Ru/MCM-41催化葡萄糖加氢制备山梨醇的研究. 食品工业科技, 2011, 12, 409–411.

3) 张军, 林鹿. MCM-41分子筛催化D-葡萄糖酸制备D-葡萄糖酸-δ-内酯的研究. 现代食品科技, 2011, 27(1), 60–62.

2) 张军, 林鹿. MCM-41分子筛催化木糖制备糠醛的研究. 化学反应工程与工艺, 2010, 26(5), 458–461.

1) Zhang Jun, Wu Shubin. One-step conversion of cellulose to sorbitol under acid conditions over Ru/C catalyst. 2012 4th International Conference on Pulping, Papermaking and Biotechnology, Nanjing, 902–905.

3. 科研项目
4) 国家自然科学基金 "木质素在亚临界水热环境下的解聚途径及产物调控机制研究(**)", 项目参与.

3) 国家重点基础研究发展计划(国家973计划) “生物质大分子热解构与重组规律研究( 2013CB228101)”, 项目参与.

2) 国家高技术研究发展计划(国家863计划) “生物质水相催化合成生物航空燃油(2012AA101806)”, 项目参与.

1) 国家高技术研究发展计划(国家863计划) “木质纤维经乙酰丙酸脱羧酯化转化合成能源乙醇技术研究与开发(2007AA05Z408)”, 项目参与.

郭园园
1. 教育背景/工作简历
2013/07－至今, 中国科学院广州能源研究所
2010/09－2013/07, 华南理工大学, 硕士学位
2006/09－2010/07, 河南城建学院, 学士学位

2. 期刊论文
3) Yuanyuan Guo, Limin Chen*, Ding Ma, Daiqi Ye, Bichun Huang. "Promotion Effect of the Adsorbed Water/OH on the Catalytic Performance of Ag/Activated Carbon Catalysts for CO Preferential Oxidation in Excess H2." Journal of Energy Chemistry, 2013, 22(4), 591-598.

2) Limin Chen*, Ding Ma, Zheng Zhang, Yuanyuan Guo, Daiqi Ye, Bichun Huang. "Synergistic Effect of Carbon Black Supported PtAg Non-alloy Bimetal Nanocatalyst for CO Preferential Oxidation in Excess Hydrogen." ChemCatChem, 2012, 4(12), 1960-1967.

1) Limin Chen*, Ding Ma, Zheng Zhang, Yuanyuan Guo, Daiqi Ye, Bichun Huang. "Low Pt Loading High Catalytic Performance of PtFeNi/Carbon Nanotubes Catalysts for CO Preferential Oxidation in Excess of Hydrogen I: Promotion Effects of Fe and/or Ni." Catalysis Letters, 2012, 142(8), 975-983.