基本信息
黄汉民 男 博导 兰州化学物理研究所
电子邮件：hmhuang@licp.cas.cn
通信地址：甘肃省兰州市天水中路18号
邮政编码：730000


研究领域主要从事过渡金属催化的新型有机合成反应的研究工作，包括设计合成一些新型的手性配体及其过渡金属络合物催化剂、过渡金属催化的C-H、C-N等惰性键的选择性活化和成键、以及多组分参与的不对称串联反应的设计和构建等。在此基础上专注于反应机理的研究，从而能够更深入的了解金属催化的反应，获得更多的规律性认识。


招生信息招收有机合成、金属有机化学等方面的博士、硕士研究生。
教育及工作经历2003年毕业于中国科学院大连化学物理研究所，获得有机化学专业博士学位，2004年至2008年在日本名古屋大学从事博士后研究，期间获得JSPS博士后基金支持。2008年4月到中国科学院兰州化学物理研究所从事独立研究工作。2008年入选中科院“百人计划”，2009年获得择优支持。

学历-- 研究生


学位-- 博士

科研成果

发表论文发表的学术论文

1. Yinjun Xie, Yingwei Zhao, Bo Qian, Lei Yang, Chungu Xia, and Hanmin Huang*, Enantioselective N-H Functionalization of Indole with α,β-Unsaturated γ-Lactams Catalyzed by Br?nsted Acids, Angew. Chem. Int. Ed. 2011, 50, 5682-5686.
2. Qiming Zhu, Dengjian Shi, Chungu Xia, Hanmin Huang*, Ruthenium Catalysts Containing Rigid Chiral Diamines and Achiral Diphosphanes for Highly Enantioselective Hydrogenation of Aromatic Ketones, Chem. Eur. J. 2011, 17, 7760-7763.
3. Yingwei Zhao, Jianping Shao, Hanmin Huang*, Chungu Xia*, Readily Available and Recoverable Chiral Ionic Phosphite Ligands for the Highly Enantioselective Hydrogenation of Functionalized Olefins, Tetrahedron: Asymmetry 2011, 22, (doi:10.1016/j.tetasy.2011.04.011), in press.
4. Bo Qian, Pan Xie, Yinjun Xie, and Hanmin Huang*, Iron-Catalyzed Direct Alkenylation of 2-Substituted Azaarenes with N-Sulfonyl Aldimines via C-H Bond Activation, Org. Lett. 2011, 13, 2580-2583.
5. Shengmei Guo, Bo Qian, Yinjun Xie, Chungu Xia, and Hanmin Huang*, Copper-Catalyzed Oxidative Amination of Benzoxazoles via C-H and C-N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources, Org. Lett. 2011, 13, 522-525.
6. Bo Qian, Shengmei Guo, Chungu Xia, and Hanmin Huang*, Lewis Acid-Catalyzed C-H Functionalization for Synthesis of Isoindolinones and Isoindolines, Adv. Synth. Catal. 2010, 352, 3195-3200.
7. Bo Qian, Shengmei Guo, Jianping Shao, Qiming Zhu, Lei Yang, Chungu Xia, and Hanmin Huang*, Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C-H Bond Activation, J. Am. Chem. Soc. 2010, 132, 3650-3651.
8. Shengmei Guo, Yinjun Xie, Xinquan Hu, Chungu Xia, and Hanmin Huang*, Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters, Angew. Chem. Int. Ed. 2010, 49, 2728-2731.
9. Lei Yang, Qiming Zhu, Shengmei Guo, Bo Qian, Chungu Xia, and Hanmin Huang*, Chiral Bronsted Acid Directed Iron-Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with β-Aryl α’-Hydroxy Enones, Chem. Eur. J. 2010, 16, 1638-1645.
10. Qiming Zhu, Hanmin Huang*, Dengjian Shi, Zhiqiang Shen, and Chungu Xia, An Efficient Synthesis of Chiral Diamines with Rigid Backbones: Application in Enantioselective Michael Addition of Malonates to Nitroalkenes, Org. Lett. 2009, 11, 4536.
11. Yinjun Xie, Hanmin Huang,* Weimin Mo, Xiangqun Fan, Zhiqiang Shen, Zhenlu Shen, Nan Sun, Baoxiang Hua, Xinquan Hu “Design and Synthesis of New Chiral Pyridine-Phosphite Ligands for the Copper-Catalyzed Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones” Tetrahedron: Asymmetry 2009, 20, 1425-1432.
12. Hanmin Huang, Tomoko Okuno, Kazuomi Tsuda, Masahiro Yoshimura, Masato Kitamura* “Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin-Lions-type sp2N/sp3N hybrid Ligands R-BINAN-R？-Py” J. Am. Chem. Soc.2006, 128, 8716-8717.
13. Hanmin Huang, Xiongcai Liu, Jun Deng, Min Qiu, Zhuo Zheng* “Rhodium-Catalyzed enantioselective Hydrogenation of β-Phthalimide Acrylates to Synthesis of β2-Amino Acids” Org. Lett. 2006, 8, 3359-3362.
14. Hanmin Huang, Xiongcai Liu, Huilin Chen, Zhuo Zheng* Monophosphite Ligands Derived from Carbohydrates and H8-BINOL: Highly Enantioselective Rh-Catalyzed Asymmetric Hydrogenations, Tetrahedron: Asymmetry 2005, 16, 693-697.
15. Hanmin Huang, Xiongcai Liu, Song Chen, Huilin Chen, Zhuo Zheng*, Carbohydrate-Drived Monophosphite ligands for Rh-Catalyzed Enantioselective Hydrogenation of α- and β-Dehydroamino Acid Esters, Tetrahedron: Asymmetry 2004, 15, 2011-2019.
16. Hanmin Huang, Zhuo Zheng,* Huili Luo, Changmin Bai, Xinquan Hu, Huilin Chen, A Novel Class of P-O Monophosphite Ligands Derived from d-Mannitol: Broad Applications in Highly Enantioselective Rh-Catalyzed Hydrogenations, J. Org. Chem. 2004, 69, 2355-2361.
17. Hanmin Huang, Huilin Chen, Xinquan Hu, Changmin Bai, Zhuo Zheng, Structure Probing of D-Fructose Derived Ligands for Asymmetric Addition of Diethylzinc to Aldehydes, Tetrahedron: Asymmetry 2003, 14, 297-304.
18. Hanmin Huang, Zhuo Zheng,* Huilin Chen, Changmin Bai, Junwei Wang, Readily available new pyridyl alcohols derived from D-glucose as ligands for the enantioselective addition of diethylzinc to aldehydes, Tetrahedron-Asymmetry 2003, 14, 1285-1289.
19. Hanmin Huang, Zhuo Zheng,* Huili Luo, Changmin Bai, Xinquan Hu, Huilin Chen*, Chiral Monophosphites Derived from Carbohydrate: Conformational Effect in Catalytic Asymmetric Hydrogenation, Org. Lett. 2003, 5, 4137-4139.
20. Masahiro Yoshimura, Toshimitsu Muraoka, Hiroshi Nakatsuka, Hanmin Huang, and Masato Kitamura* Synthesis of 3,3？-Diaryl-Substituted 2,2？-Diamino-1,1？-binaphthyl and Its Derivatives, J. Org. Chem. 2010, 75, 4315-4318.
21. 邵建平，黄汉民*, 孙楠，莫为民，胡信全“FeCl3催化Et2Zn与芳香醛的加成反应研究” 分子催化，2009，23(6)，488-492.
22. 朱其明，黄汉民*, 夏春谷，“手性环状二胺催化的不对称Diels-Alder反应”分子催化，2011，25, 6-10.
23. Huang Hanmin, Huang Wei, Chen Huilin, Han Xiuwen, Zheng Zhuo*, Study on the synthesis and absolute configurations of novel chiral ligands derived from D-glucose by 2D NMR. Chinese Journal of Magnetic Resonance, 2003, 20, 271-275.
24. Hanmin Huang，Zhuo Zheng，Huilin Chen，Chiral organic catalysts and their applications in catalytic asymmetric reaction, Chinese Journal of Molecular Catalysis，2003, 17, 389-399.
25. Xiongcai Liu, Hanmin Huang, Zhuo Zheng. Synthesis of monodentate phosphite ligands derived from carbohydrates and H8-BINOL and their application in Rh-catalyzed asymmetric hydrogenation of ？-dehydroamino acids. Chinese Journal of Molecular Catalysis, 2005, 19(5), 388-393.
26. Guangxing Li*, Hanmin Huang, Fumin Mei. A novel synthesis of substituted phenylpyruvic acid by double carbonylation using cobalt pyridine-2-carboxylate catalyst. Synthetic Communications, 2000, 30, 3585-3588.
27. Guangxing Li*, Hanmin Huang. Double carbonylation of benzyl chloride to substituted phenylpyruvic acid catalyzed by cobalt pyridine-2-carboxylate. Chemical Journal of Chinese Universities, 2000, 21, 286-288.
28. Guangxing Li*, Hanmin Huang, Huaqiang Cai. Carbonylation of benzyl chloride to phenylacetic acid catalyzed by cobalt pyridine-2-carboxylate, Chinese Journal of fuel Chemistry and Technology，2000, 28, 284-286.
29. Guangxing Li*, Lin Li, Hanmin Huang, et al. One pot formation of catalytic and double carbonylation of benzyl chloride, J. Mol. Cata. (A-Chemical), 2003, 193(1-2), 97-102.
30. Guangxing Li*, Hanmin Huang, Junyi Wang. Application of carbonyl cobalt in catalytic carbonylation, (Chinese) Hubei Hua Gong, 1999, 3, 5-10.


专利成果1. 黄汉民*，钱波，郭生梅，夏春谷，一种含氮杂环胺类化合物及其制备方法，中国专利，**9.6.
2. 黄汉民*，朱其明，史登健，夏春谷，一种手性钌催化剂及其在酮不对称氢化反应中的应用， 中国专利，**6.8.
3. 黄汉民*，朱其明，史登健，夏春谷，一类苯并环状手性二胺， 中国专利，**0.4.
4. 黄汉民*，钱波，一种含氮杂环烯烃衍生物的制备方法， 中国专利，**9.7.

科研项目国家自然科学基金项目(**)
中国科学院“百人计划”项目
OSSO国家重点实验室重点方向性项目


参与会议 （1） Catalytic Selective C-H and N-H Functionalization of Nitrogen-Containing Heterocycles，第九届海峡两岸催化学术会议，2011-07，黄汉民
（2） Selective C-H and N-H Functionalization of Heterocycles，第15届全国催化大会，2010-12，黄汉民
（3） 含氮杂环的合成及应用，2010年西部有机化学论坛，2010-09，黄汉民
（4） 原子经济导向的催化基础研究，2010年中国化学会年会，2010-06，黄汉民

指导学生郭生梅 博士研究生 有机化学

史登健 硕士研究生 有机化学

周 晗 硕士研究生 有机化学

谢银君 博士研究生 有机化学
解 攀 博士研究生 有机化学

工作经历

工作简历 2008-04--今 中科院兰州化学物理研究所 百人计划研究员
2004-09--2008-03 日本名古屋大学 JSPS特别研究员

出版信息

发表著作 （1） 有机中间体制备，Preparation of Organic Intermediates，化学工业出版社，2009-07，第5作者