导师简介:马嘉璧 副教授 博导
电子邮件: majiabi@bit.edu.cn
主要经历:
2004-2008 吉林大学 化学学院 学士
2008-2013 中国科学院化学研究所 博士
2011/9-2013/1 柏林工业大学研究方向:
团簇化学,主要利用实验和理论计算相结合的手段研究过渡金属氮、氧化物团簇结构及反应活性。CO、N2、碳氢化物等稳定分子的(催化)活化。实验主要使用原子分子簇原位反应装置(如下图)、光电子能谱等仪器手段。
气溶胶物理化学。利用团簇模型对大气中重要物理化学过程进行模拟研究,为认清我国雾霾形成机制提供重要理论依据。
承担课题:
国家重点研发计划--科技部 (青年 973)
国家自然科学基金
北京市自然科学基金
北京分子科学国家实验室开放课题基金
校基础研究基金 2 项
主要研究成果:
J. Am. Chem. Soc. 2013,135, 2991-2998. ChemPhysChem 2016, 18, 1112-1118. J. Phys. Chem. A 2019, 123, 5762-5767
代表论文: 迄今已发表通讯/第一作者SCI 论文30 篇,包含4 篇Angew. Chem. Int. Ed., 2 篇 J. Am. Chem. Soc.(附件 1),1 篇 Chem. Eur. J.,3 篇封面文章(J. Am. Chem. Soc.、 ChemPhysChem、JPCA)。
Y. Zhao, J.-T. Cui, M. Wang, D.Y. Valdivielso, A. Fielicke*, L.-R. Hu*, X. Cheng, Q.-Y. Liu, Z.-Y. Li, S.-G. He, J.-B. Ma*, “Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity”, J. Am. Chem. Soc. 2019, 141, 12592-12600.
M. Wang, C.-X. Sun, J.-T. Cui, Y. Zhang, J.-B. Ma*, “Clean and Efficient Transformation of CO2 to Isocyanic Acid: The Important Role of Triatomic Cation ScNH+”, J. Phys. Chem. A 2019, 123, 5762-5767. ( Cover Article)
M. Wang, C.-X. Sun, Y. Zhao, J.-T. Cui, J.-B. Ma*, “Efficient Liberation of Ammonia from Thermal Reaction
of ScNH+ Cations and Water”, J. Phys. Chem. A 2019. DOI: 10.1021/acs.jpca.9b05890.
J.-T. Cui, Y. Zhao, M. Wang, S.-S Wang, J.-B. Ma*, “Thermal Benzene Activation by 3d Transition Metal (Sc-Cu) Oxide Cations”, Chin. Chem. Lett. 2019. DOI:10.1016/j.cclet.2019.05.015
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J.-T. Cui, C.-X. Sun, Y. Zhao, M. Wang, J.-B. Ma*, “Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Benzene Mediated by Cu O + Cations”, Phys. Chem. Chem. Phys. 2019, 21, 1117-1122.
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Y. Zhao, J.-T. Cui, J.-C. Hu, J.-B. Ma*, “Reactivities of VO + Toward n-CmH2m+2 (m = 3, 5, 7) as Functions of Oxygen Content and Carbon Chain Length”, Acta Phys. -Chim. Sin. 2019, 35, 531-538.
J.-T. Cui, Y. Zhao, J.-C. Hu, J.-B. Ma*, “Direct Hydroxylation of Benzene to Phenol Mediated by Nanosized Vanadium Oxide Cluster Ions at Room Temperature”, J. Chem. Phys. 2018, 149, 074308.
Y. Zhao, J.-C. Hu, J.-T. Cui, L.-L. Xu, J.-B. Ma*, “Fe2O+ Cation Mediated Propane Oxidation by Dioxygen in the Gas Phase”, Chem. Eur. J. 2018, 24, 5920-5926.
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J.-C. Hu, L.-L. Xu, H.-F. Li, D.Y. Valdivielso, A. Fielicke*, S.-G. He, J.-B. Ma*, “Liberation of Three Dihydrogens from Two Ethene Molecules as Mediated by the Tantalum Nitride Anion Cluster Ta N – at Room Temperature”, Phys. Chem. Chem. Phys. 2017, 19, 3136-3142.
J.-C. Hu, L.-L. Xu, X.-Y. Hou, H.-F. Li, J.-B. Ma*, S.-G. He, “Origin of the Different Reactivity of the Triatomic Anions HMoN– and ZrNH– toward Alkane: Compositions of the Active Orbitals”, J. Phys. Chem. A 2016, 120, 7786-7791.
J.-B. Ma*, L.-L. Xu, Q.-Y. Liu, S.-G. He*, “Activation of Methane and Ethane as Mediated by the Triatomic Anion HNbN–: Electronic Structure Similarity with a Pt Atom”, Angew. Chem. Int. Ed. 2016, 55, 4947-4951.
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Q.-Y. Liu, J.-B. Ma*, Z.-Y. Li, C.-Y. Zhao, C.-G. Ning, H. Chen*, S.-G. He*, “Activation of Methane Promoted by Adsorption of CO on Mo C – Cluster Anions”, Angew. Chem. Int. Ed. 2016, 55, 5760-5764.
J.-B. Ma*, J.-H. Meng, S.-G. He*, “Methane Activation Mediated by a Series of Cerium-Vanadium Bimetallic Oxide Cluster Cations: Tuning Reactivity by Doping”, ChemPhysChem 2016, 17, 1112-1118. ( Cover Article)
J.-B. Ma*, L.-L. Xu, J.-H. Meng, S.-G. He*, “Dehydrogenation of Propylene Mediated by CeVO4+: An Interesting Example for the Chemistry of Binary Ce-V Transition-Metal Oxide Cluster Cations”, Int. J. Mass Spectrom. 2016, 401, 39-45.
J.-B. Ma*, J.-H. Meng, S.-G. He*, “Gas-Phase Reaction of CeVO5+ Cluster Ions with C2H4: Reactivity of Cluster Bonded Peroxides”, Dalton Trans. 2015, 44, 3128-3135.
Y. Wang, J.-B. Ma*, Q. Zhou, S.-F Pang, Y.-H. Zhang*, “Hygroscopicity of Mixed Glycerol/Mg(NO3)2/Water Droplets Affected by the Interaction between Magnesium Ions and Glycerol Molecules”, J. Phys. Chem. B 2015, 119, 5558-5566.
C. Cai, S. Tan, J.-B. Ma, H.-N. Chen; Y. Wang, J. P. Reid*, Y.-H. Zhang*, “Slow Water Transport in MgSO4 Aerosol Droplets at Gel-Forming Relative Humidities”, Phys. Chem. Chem. Phys. 2015, 17, 29753-29763.
J.-B. Ma*, Z. Yuan, J.-H. Meng, Q.-Y. Liu, S.-G. He*, “Gas-Phase Reaction of CeV2O7+ with C2H4: C?C and C?H Bonds Activation”, ChemPhysChem 2014, 15, 4117-4125.
Q. Zhou, S.-F. Pang, Y. Wang, J.-B Ma*, Y.-H. Zhang*, “Confocal Raman Studies of the Evolution of the Physical State of Mixed Phthalic Acid/Ammonium Sulfate Aerosol Droplets and the effect of Substrates. J. Phys. Chem. B 2014, 118, 6198?6205.
J.-B. Ma, Z.-C. Wang, M. Schlangen, S.-G. He*, H. Schwarz*, “On the Origin of the Surprisingly Sluggish Redox Reaction of the N2O/CO Couple Mediated by [Y2O2]+ and [YAlO2]+ Cluster Ions in the Gas Phase. Angew. Chem. Int. Ed. 2013, 52, 1226-1230.
J.-B. Ma, B. Xu, J.-H. Meng, X.-N. Wu, X.-L. Ding, S.-G. He*, “Reactivity of Atomic Oxygen Radical Anions Bound to Titania and Zirconia Nanoparticles in the Gas Phase: Low-Temperature Oxidation of Carbon Monoxidem”, J. Am. Chem. Soc. 2013, 135, 2991-2998.( Cover and Spotlights Article)
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J.-B. Ma, Z.-C. Wang, M. Schlangen, S.-G. He*, and H. Schwarz*, “Thermal Reactions of the Heteronuclear Oxide Cluster YAlO +? with Methane: Increasing the Reactivity of Y O +? and the Selectivity of Al O +? by Doping”, Angew. Chem. Int. Ed. 2012, 51, 5991-5994.
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Z.-C. Wang, N. Dietl, R. Kretschmer, J.-B. Ma, T. Weiske, M. Schlangen*, H. Schwarz*, “Direct Methane to Formaldehyde Conversion Mediated by the Al O + Cluster at Room-Temperature”, Angew. Chem. Int. Ed. 2012, 51, 3703-3707.
J.-B. Ma, Y.-X. Zhao, S.-G. He*, X.-L. Ding*, “Experimental and Theoretical Study of the Reactions between Vanadium Oxide Cluster Cations and Water”, J. Phys. Chem. A 2012, 116, 2049-2054.
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J.-B. Ma, X.-N.Wu, Y.-X. Zhao, X.-L. Ding, S.-G. He*, “Methane Activation by V3PO ?+ and V O ?+
Clusters: A Comparative Study”, Phys. Chem. Chem. Phys. 2010, 12, 12223-12228.
J.-B. Ma, X.-N. Wu, Y.-X. Zhao, X.-L. Ding, S.-G. He*, “Characterization of Mononuclear Oxygen-Centered Radical (Oˉ?) in Zr2O8ˉ Cluster”, J. Phys. Chem. A 2010, 114, 10024-10027.
J.-B. Ma, X.-N. Wu, Y.-X. Zhao, S.-G. He*, X.-L. Ding*, “Experimental and Theoretical Studies of the Reactions between Vanadium Oxide Cluster Anions and Small Hydrocarbon Molecules”, Acta Phys. -Chim. Sin. 2010, 26, 1761-1767.
J.-B. Ma, X.-N. Wu, Y.-X. Zhao, X.-L. Ding, S.-G. He*, “Experimental and Theoretical Study of Hydrogen Atom Abstraction from C2H6 and C4H10 by Zirconium Oxide Clusters Anions”, Chin. J. Chem. Phys. 2010, 2, 133-137.