姓名：姚子硕
个人简历
职务职称： 特别研究员/博士生导师研究团队：双稳态功能材料课题组 主页：http://www.tao-lab.cn/
电子邮箱： zishuoyao@bit.edu.cn
学习与工作经历：
2014 年 4 月~2016 年 10 月 日本九州大学 学术研究员 导师：Prof. Osamu Sato
2010 年 10 月~2014 年 3 月 日本九州大学 博士 导师：Prof. Osamu Sato
社会兼职：
中国化学会青年化学工作者委员会 委员研究领域：
基于分子结构双稳态的新型晶态功能材料
本课题组隶属于无机配位化学研究领域，致力于通过巧妙的分子结构设计，获取各种具有有趣物理性质的功能材料。通过系统的性质研究、结构分析，洞悉材料结构-性质之间的有效关系，指导新材料的进一步合成。具体研究内容包括但不仅限于下图中内容：
本课题组强调新颖的功能设计思路而非简单的长时间实验工作，欢迎有活力、喜欢动脑筋、富于想象力的研究生、博士后加盟我们 的团队。
研究成果：
目前发表 Nature Chemistry， Nature Communications， J. Am. Chem. Soc.以及 Angew. Chem. Int. Ed.等顶级期刊论文 20 余篇，担任 Nature Communications 等学术期刊独立审
稿人。
Yao, Z.-S.; Mito, M.; Kamachi, T.; Shiota, Y.; Yoshizawa, K.; Azuma, N.; Miyazaki, Y.; Takahashi, K.; Zhang, K.; Nakanishi, T.; Kang, S.; Kanegawa, S.; Sato, O*. Molecular motor-driven abrupt anisotropic shape change in a single crystal of a Ni complex. Nat. Chem. 2014, 6, 1079-1083.
Yao, Z.-S.*; Guan, H.; Shiota, Y.; He, C.-T.; Wang, X.-L.; Wu, S.-Q.; Zheng, X.; Su, S.-Q.; Yoshizawa, K.; Kong, X.; Sato, O.*; Tao, J.* Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal, Nat. Commun. 2019, 10, 4805.
Yao, Z.-S.; Wu, S.-Q.; Kitagawa, Y.; Su, S.-Q.; Huang, Y.-G.; Li, G.-L.; Ni, Z.-H.; Nojiri, H.; Shiota, Y.; Yoshizawa, K.; Kang, S.; Kanegawa, S.; Sato, O.* Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex. Angew. Chem. Int. Ed. 2017, 56, 717-721.
Yao, Z.-S.; Yamamoto, K.; Cai, H.-L.; Takahashi, K.; Sato, O*. Above Room Temperature Organic Ferroelectrics: Diprotonated 1,4-Diazabicyclo 2.2.2 octane Shifts between Two 2-Chlorobenzoates. J. Am. Chem. Soc. 2016, 138, 12005-12008.
Wang, C.-F.; Yang, G.-Y.; Yao, Z.-S.*; Tao, J.* Monitoring the Spin States of Ferrous Ions by Fluorescence Spectroscopy in Spin-Crossover-Fluorescent Hybrid Materials. Chem. Eur. J. 2018, 24, 3218-3224.
Sun, X.; Tang, Z.; Yao, Z.-S.*; Tao, J.* Homochiral 3D Framework of Mechanically Interlocked 1D Loops with Solvent-Dependent Spin-State Switching Behaviors, Chem. Commun. 2019. DOI： 10.1039/C9CC09063K
Xue, J.-P.; Wu, W.-J.; Li, Q.-S.; Yao, Z.-S.*; Tao, J.* A Two-Dimensional Spin-Crossover Coordination Polymer Exhibiting Interlayer Multiple C–Hδ+···Hδ?–B Dihydrogen Bonds, Inorg. Chem. 2019, 58, 15705-15709.
Sun, X.-P.; Wei, R.-J.; Yao, Z.-S.*; Tao, J.* Solvent effects on the structural packing and spin- crossover properties of a mononuclear iron(II) complex, Cryst. Growth Des. 2018, 18, 6853-6862.
Sun, X.-P.; Liu, T.; Yao, Z.-S.*; Tao, J.* Spin crossover and photomagnetic behaviors in one- dimensional looped coordination polymers, Dalton Trans. 2019, 48, 9243-9249.
Wang, C.-F., Yao, Z.-S.*, Yang, G.-Y. & Tao, J*. Ligand Substituent Effects on the Spin-Crossover Behaviors of Dinuclear Iron(II) Compounds. Inorg. Chem. 2019, 58, 1309-1316.
Sun, X.-P., Wei, R.-J., Yao, Z.-S.* & Tao, J*. Solvent Effects on the Structural Packing and Spin- Crossover Properties of a Mononuclear Iron(II) Complex. Cryst. Growth Des. 2018, 18, 6853-6862
Su, S.-Q.; Kamachi, T.; Yao, Z.-S.; Huang, Y.-G.; Shiota, Y.; Yoshizawa, K.; Azuma, N.; Miyazaki, Y.; Nakano, M.; Maruta, G.; Takeda, S.; Kang, S.; Kanegawa, S.; Sato, O*. Assembling an alkyl rotor to access abrupt and reversible crystalline deformation of a cobalt(II) complex. Nat. Commun. 2015, 6.
Huang, Y.-G.; Shiota, Y.; Wu, M.-Y.; Su, S.-Q.; Yao, Z.-S.; Kang, S.; Kanegawa, S.; Li, G.-L.; Wu, S.-Q.; Kamachi, T.; Yoshizawa, K.; Ariga, K.; Hong, M.-C.; Sato, O*. Superior thermoelasticity and shape-memory nanopores in a porous supramolecular organic framework. Nat. Commun. 2016, 7.
Zhang, K.; Kang, S.; Yao, Z.-S.; Nakamura, K.; Yamamoto, T.; Einaga, Y.; Azuma, N.; Miyazaki, Y.; Nakano, M.; Kanegawa, S.; Sato, O*. Charge-Transfer Phase Transition of a Cyanide-Bridged Fe-II/Fe-III Coordination Polymer. Angew. Chem. Int. Ed. 2016, 55, 6047-6050.
Huang, Y.-G.; Shiota, Y.; Su, S.-Q.; Wu, S.-Q.; Yao, Z.-S.; Li, G.-L.; Kanegawa, S.; Kang, S.; Kamachi, T.; Yoshizawa, K.; Ariga, K.; Sato, O*. Thermally Induced Intra-Carboxyl Proton Shuttle in a Molecular Rack-and-Pinion Cascade Achieving Macroscopic Crystal Deformation. Angew. Chem. Int. Ed. 2016, 55, 14628-14632.
Wu, S.-Q.; Miyazaki, Y.; Nakano, M.; Su, S.-Q.; Yao, Z.-S.; Kou, H.-Z.; Sato, O.* Slow Magnetic Relaxation in a Mononuclear Ruthenium(III) Complex. Chem. Eur. J. 2017, 23, 10028-10033.
Li, G.-L.; Wu, S.-Q.; Zhang, L.-F.; Wang, Z.; Ouyang, Z.-W.; Ni, Z.-H.; Su, S.-Q.; Yao, Z.-S.; Li, J.-Q.; Sato, O.* Field-Induced Slow Magnetic Relaxation in an Octacoordinated Fe(II) Complex
with Pseudo-D-2d Symmetry: Magnetic, HF-EPR, and Theoretical Investigations. Inorg. Chem.
2017, 56, 8018-8025.
Li, G.-L.; Kanegawa, S.; Yao, Z.-S.; Su, S.-Q.; Wu, S.-Q.; Huang, Y.-G.; Kang, S.; Sato, O*. Influence of Intermolecular Interactions on Valence Tautomeric Behaviors in Two Polymorphic Dinuclear Cobalt Complexes. Chem. Eur. J. 2016, 22, 17130-17135.
Yao, Z.-S.; Wei, X.-Y*.; Lv, J.; Liu, F.-J.; Huang, Y.-G.; Xu, J.-J.; Chen, F.-J.; Huang, Y.; Li, Y.; Lu, Y.; Zong, Z.-M. Oxidation of Shenfu Coal with RuO4 and NaOCl. Energy Fuels 2010, 24, 1801- 1808.
Huang, Y.-G.; Zong, Z.-M.; Yao, Z.-S.; Zheng, Y.-X.; Mou, J.; Liu, G.-F.; Cao, J.-P.; Ding, M.-H.; Cai, K.-Y.; Wang, F.; Zhao, W.; Xia, Z.-L.; Wu, L.; Wei, X.-Y*. Ruthenium ion-catalyzed oxidation of shenfu coal and its residues. Energy Fuels 2008, 22, 1799-1806.
Zhao, W.; Zong, Z.-M.; Lin, J.; Song, Y.-M.; Guo, X.-F.; Yao, Z.-S.; Zhang, L.-N.; He, R.-L.; Cao, J.-P.; Wei, X.-Y*. Dewaxing from stalks with petroleum ether by different methods. Energy Fuels 2007, 21, 1165-1168.
