徐允河
单位：化学与材料科学学院
地址：安徽省合肥市金寨路96号
邮编：230026
电话：
个人主页：
实验室介绍：


个人简历 Personal resume


2010.8--2012.2 博士后研究 新加坡南洋理工大学2006.9--2010.7 理学博士 新加坡南洋理工大学2003.9--2006.7 理学硕士 南开大学1999.9--2003.7 理学学士 青岛大学


研究方向 Research direction


1、不对称催化有机合成
2、金属催化有机合成
3、金属有机化学



招生信息 Enrollment information


具有良好的有机合成知识和研究经历。


论文专著 The monograph


1)Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)‑2-Alken-4-ynoates with Silylboronate - J. Am. Chem. Soc. - -
2)tereo- and Chemoselective Cross-Coupling between Two Electron-Deficient Acrylates: An Efficient Route to (Z, E)-Muconate Derivatives - J. Am. Chem. Soc. - -
3)Pd-Catalyzed Intramolecular C-N Bond Cleavage, 1,4-Migration, sp(3) C-H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand - J. Am. Chem. Soc. - -
4)Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp2 C-H Bond Finctionalization Reaction - Angew.Chem. Int. Ed. - -
5)Macrolide Synthesis through Intramolecular Oxidative Cross-Coupling of Alkenes - Angew.Chem. Int. Ed. - -
6)Copper-Catalyzed Silylperoxidation Reaction of α,β-Unsaturated Ketones, Esters, Amides, and Conjugated Enynes - ACS Catal. - -
7)Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of α,β-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes - ACS Catal. - -
8)Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes - ACS Catal. - -
9)Copper-Catalyzed Dehydrogenative Diels-Alder Reaction - Org. Lett. - -
10)Palladium-catalyzed silaborative carbocyclization of 1,6-diynes - Chem. Commun. - -