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安徽师范大学化学与材料科学学院导师教师师资介绍简介-商永嘉

本站小编 Free考研考试/2021-04-24


商永嘉 教授 博士 博士生导师
邮 箱:shyj@ahnu.edu.cn
实验室:花津校区理科大楼1133-1134
办公室:花津校区理科大楼1136
ORCID:https://orcid.org/0000-0001-9873-9150




所受教育
2000 年 9 月 - 2003 年 3 月 浙江大学化学系博士研究生,获理学博士学位
1994 年 9 月 - 1997 年 7 月 南京大学化学化工学院硕士研究生,获理学硕士学位
1988 年 9 月 - 1992 年 7 月 阜阳师范大学化学系学习,获学士学位


职称职位
1.1997年7月至今 安徽师范大学助教,讲师,教授(2004年)
2. 2006年2月--2006年8月,香港大学化学系博士后研究员
3. 2010年4月,博士生导师
4. 2009年2月--2012年2月,化学与材料科学学院副院长
5. 2012年2月-2018年8月,研究生院副院长
6. 2018年8月-至今,功能分子固体教育部重点实验室常务副主任


主持项目
多反应中心卡宾中间体参与的环状化合物的高效合成反应研究,国家自然科学基金面上项目(**),64万,2018-2021,主持。
基于环状重氮-1,3-二酮的过渡金属催化的有机反应及其在复杂化合物合成中的应用,国家自然科学基金面上项目(**),80万,2014-2017,主持。
有机催化的串联反应及其在复杂化合物分子合成中的应用,国家自然科学基金面上项目(**),60万,2012-2015,主持。
教育部“新世纪优秀人才支持计划”(NCET-10-0004),50万,2011-2014,主持。
基于烯酮亚胺的多组分反应合成一些环状化合物的方法学研究,国家自然科学基金面上项目(**),35万,2009-2011,主持。
清洁化生产电子级异氰脲酸三缩水甘油酯(TGIC)及其副产物的开发研究,安徽省教育厅产学研重点项目(KJ2010A137),5万,2010-2012,主持。


主持教学项目
主持安徽省省级精品课程《有机化学》


研究领域
有机合成与药物合成
金属参与的有机合成反应
应用有机化学


讲授课程
有机化学
有机合成
综合化学实验
诺贝尔奖与科学精神


获奖与人才情况
2020年获安徽师范大学教学名师

2019年安徽省学术和技术带头人
2019年安徽省科学技术进步奖三等奖(第二完成人)
2017年安徽省科学技术奖三等奖(第一完成人)
2010年入选“教育部新世纪优秀人才支持计划”
2010年安徽优秀青年科技创新奖
2010年获安徽省高等学校省级教学成果二等奖(排名第一)
2009年安徽省学术和技术带头人后备人选
2005年获安徽省高校中青年学科带头人培养对象
2004年获安徽师范大学优秀教学二等奖
2003年获安徽省高校中青年优秀骨干教师


组内新闻
2020/12/18 祝贺课题组胡汪成同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"Construction of isoxazolone-fused phenanthridines via Rh-catalyzed cascade C-H activation/cyclization of 3-arylisoxazolones with cyclic 2-diazo-1,3-diketones".

2020/12/14 祝贺课题组左有鹏同学的文章被Adv. Synth. & Catal. 杂志接受,论文题目为""Palladium-Catalyzed 5-exo-dig Cyclization Cascade, Sequential Amination/Etherification for Stereoselective Construction of 3-Methyleneindolinones".The manuscript has been selected as a VIP.
2020/10/28 祝贺课题组洪浩然同学的文章被Adv. Synth. & Catal. 杂志接受,论文题目为"Enantioselective Michael Addition Reactions to Construct CF3S-containing Stereocenter Catalyzed by Chiral Quaternary Phosphonium Salts".

2020/10/19祝贺课题组周彤彤同学的文章“Rh-catalyzed formal [3+2] cyclization for synthesis of 5-aryl-2-(quinolin-2-yl)oxazoles and its applications in metal ions probes”被Chin. J. Chem. 杂志接受。
2020/8/28 祝贺课题组洪浩然同学的文章被Chin. Chem. L. 杂志接受,论文题目为"Organophosphine bearing multiple hydrogen-bond donors for asymmetric Michael addition reaction of 1-oxoindane-2-carboxylic acid ester via dual-reagent catalysis".
2020/04/25祝贺课题组左有鹏同学的文章“Palladium-catalyzedCascade Decarboxylative Amination/6-endo-dig Benzannulation of o-Alkynylarylketones with N-Hydroxyamides to Access Diverse 1-Naphthylamine Derivatives ”被Org. Lett. 杂志接受。
2020/02/25祝贺课题组刘源同学的文章“Palladium-catalysed dearomative aryl/cycloimidoylation of indoles. ”被Chem. Commun. 杂志接受,并邀请作为做封面文章。
2020/02/23 祝贺课题组杨晨同学的文章“Rh(III)-Catalyzed Relay Double Carbenoid Insertion and Diannulation of Sulfoximine Benzamides with α?Diazo Carbonyl Compounds: Access to Furo[2,3?c]isochromenes. ”被Org. Lett. 杂志接受,并邀请作为做封面文章。
2019/03/20 祝贺课题组蔡晓婷同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"Synthesis of 4-styrylcoumarins via FeCl3-promoted cascade reactions of propargylamines with β-keto esters"。
2019/08/20 祝贺课题组刘艳飞同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"Controllable construction of isoquinolinedione and isocoumarin scaffolds via RhIII-catalyzed C–H annulation of N-tosylbenzamides with diazo compounds"。
2019/08/20 祝贺课题组左有鹏同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"Substituent-Oriented C–N Bond Formation via N–H Insertion or Wolff Rearrangement of 5-Aryl-1H-pyrazoles and Diazo Compounds"。
2019/05/21 祝贺课题组蔡盼圆同学的文章被Org. Chem. Front. 杂志接受,论文题目为"Tuneable Access to Isoquinolines via a Transition-Metal-Free C(sp3)-C(sp3) Bond Cleavage Rearrangement Reaction"。
2019/04/29 祝贺课题组宁翊同学的文章被Adv. Synth. & Catal.杂志接受,论文题目为"Rh2(OAc)4-Catalyzed Cyclization of Pyrazol-5-amines and 1,3-Diketone-2-Diazos using DMF as CH Sources: Access to Pyrazolo[3,4-b]pyridines"。
2019/02/14 祝贺课题组李欠欠同学的文章被Adv. Synth. & Catal. 杂志接受,论文题目为"Base-mediated 1,4-Conjugate Addition/Intramolecular 5-exo-digAnnulation of Propargylamines with Benzoylacetonitriles andβ-Keto Esters for Polysubstituted Furans and Furo[3,4-c]coumarins Formation"。
2018/10/21 祝贺课题组韩光同学的文章被Tetrahedron杂志接受,论文题目为"Rh(III)-catalyzed C-H activation of primary benzamides and tandem cyclization with cyclic 2-diazo-1,3-diketones for the synthesis of isocoumarins"。
2018/10/09 祝贺课题组左有鹏同学的文章被J. Org. Chem.杂志接受,论文题目为"Selective Synthesis ofAminoisoquinolinesviaRh(III)-catalyzed C-H/N-H Bond Functionalization ofN-Aryl Amidines with Cyclic 2-Diazo-1,3-diketones"。
2018/09/08 祝贺课题组王慧同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"FeCl3-promoted Tandem 1,4-Conjugate Addition/6-endo-digCyclyzation/Oxidation of Propargylamines and Benzoylacetonitriles/Malononitrile: Direct Access to Functionalized 2-Aryl-4H-chromenes"。
◎2018/07/01 祝贺2015级王慧、张兰兰两位同学通过硕士论文答辩并获得硕士学位,感谢他们为课题组所做出的贡献!祝他们前程似锦!
2017/12/11 祝贺课题组陶佳佳同学的文章被Tetrahedron杂志接受,论文题目为"Synthesis of Polysubstituted Phenyl AcetatesviaFeCl3-mediated Domino Reaction of 2-(Aryl(piperidin-1-yl)methyl)phenols and 1,3-Diketones"。
2017/11/17 祝贺课题组左有鹏同学的文章被ACS Omega杂志接受,论文题目为"Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access toN-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones andN-Arylamides"。
2017/08/14 祝贺课题组于智宇同学的文章被Org. Biomol. & Chem.杂志接受,论文题目为"Direct Carboxamidation of Cyclic 2-Diazo-1,3-diketones by Rh2(OAc)4-catalyzedIsocyanide Insertion-Hydrolysis"。
2017/07/01 祝贺2014级张家星同学通过博士论文答辩并获得博士学位,2014级杨成、陶佳佳、蔡晓婷、项立伟四位同学通过硕士论文答辩并获得硕士学位,感谢他们为课题组所做出的贡献!祝他们前程似锦!
2017/06/19 祝贺课题组时光好同学的文章被Chin. J. Chem.杂志接受,并被选为杂志封面,论文题目为"Oxidative Rearrangement of Isatins with ArylaminesUsing H2O2as Oxidant: A Facile Synthesis of Quinazoline-2,4-diones and Evaluation of Their Antibacterial Activity"。
2017/01/20 祝贺课题组杨成同学的文章被J. Org. Chem.杂志接受,论文题目为"Synthesis of Isocoumarins from Cyclic 2-Diazo-1,3-diketones and Benzoic AcidsviaRh(III)-catalyzed C?H Activation and Esterification"。
2016/12/07 祝贺课题组周尧同学的文章被ACS Omega杂志接受,论文题目为"Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-onesviaRh2(OAc)4-catalyzed [3+2] Cycloaddition Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates"。
2016/10/31 祝贺课题组张志琴同学的文章被Chem. Res. Chin. Univ.杂志接受,论文题目为"Ferrocenyl-isoxazole Derivative: A NovelElectrochemical, Colorimetric, and Fluorescent Multiple Signal Probe for Highly Selective Recognition ofCu2+Ions"。
2016/10/25 祝贺课题组张家星、陶佳佳两位同学获得国家奖学金!
2016/09/14 祝贺课题组张家星同学的文章被Org. Lett.杂志接受,论文题目为"Thiourea?Quaternary Ammonium Salt Catalyzed Asymmetric 1,3?Dipolar Cycloaddition of Imino Esters To Construct Spiro[pyrrolidin-3,3′-oxindoles]"。
2016/08/26 祝贺课题组张家星同学的文章被J. Org. Chem.杂志接受,论文题目为"Enantioselective Construction of Spirocyclic OxindolesviaTandem Michael/Michael Reactions Catalyzed by Multifunctional Quaternary Phosphonium Salt"。
2016/08/03 祝贺课题组时光好同学的文章被Chin. J. Chem.杂志接受,论文题目为"Synthesis of 3',4'-Diaryl-4'H-spiro[indoline-3,5'-[1',2',4']oxadiazol]-2-onesviaDMAP-catalyzed Domino Reactions and Their Antibacterial Activity"。
2016/07/01 祝贺2013级韩光、王婕、吴福丽三位同学通过硕士论文答辩并获得硕士学位,感谢他们为课题组所做出的贡献!祝他们前程似锦!
2016/02/15 祝贺课题组陶佳佳同学的文章被J. Org. Chem.杂志接受,论文题目为"FeCl3-mediated One-pot Domino Reactions for the Synthesis of 9-Aryl/9-Arylethynyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones from Propargylic amines/Diaryl Amines and1,3-Cyclohexanediones"。
2016/01/19 祝贺课题组时光好同学的文章被RSCAdv.杂志接受,论文题目为"Combinatorial Synthesis of Spiro[indoline-3,2'-pyrrole] Derivativesviaa Three-component Reaction under Catalyst-free Conditions


代表性论文
Zuo, Youpeng; He, Xinwei*; Tang, Qiang; Hu, Wangcheng; Zhou, Tongtong; Yongjia Shang *.Palladium-Catalyzed Cascade Decarboxylative Amination/6-endo-dig Benzannulation of o-Alkynylarylketones with N-Hydroxyamides to Access Diverse 1-Naphthylamine Derivatives.Org. Lett., 2020, 22,10, 3890-3894.




Jian Wang, * Yuan Liu, Zhuang Xiong, Ling Zhong, Shumin Ding, Lianjie Li, Haixia Zhao, Chen Chen and Yongjia Shang *. Palladium-catalysed dearomative aryl/cycloimidoylation of indoles. Chem. Commun., 2020, 56, 3249-3252. (封面文章)



Chen Yang, Chen Chen, Shunfan Li, Xinwei He, Youpeng Zuo, Wangcheng Hu, Tongtong Zhou, Jian Wang,* and Yongjia Shang*, Rh(III)-Catalyzed Relay Double Carbenoid Insertion and Diannulation of Sulfoximine Benzamides with α Diazo Carbonyl Compounds: Access to Furo[2,3 c]isochromenes. Org. Lett., 2020, 22,7, 2506-2511.(封面文章)


Jian Wang,* Panyuan Cai, Yimiao He, Yuan Liu, Ling Zhong, Shumin Ding, and Yongjia Shang*, “Tuneable Access to Isoquinolines via a Transition-Metal-Free C(sp3)-C(sp3) Bond Cleavage Rearrangement Reaction”. Org. Chem. Front., 2019, 6, 2430–2434.

Yi Ning, Xinwei He, Youpeng Zuo, Panyuan Cai, Mengqing Xie, Jian Wang,* and Yongjia Shang*, Rhodium (II) Acetate-Catalysed Cyclization of Pyrazol-5-amine and 1,3-Diketone-2-diazo Compounds using N,N-Dimethylformamide as a Carbon-Hydrogen Source: Access to Pyrazolo[3,4-b]pyridines. Adv. Synth. & Catal.,2019, 361, 3518-3524.

Li-Qin Yan, Xiaoting Cai, Xinwei He,* Hui Wang, Mengqing Xie, Youpeng Zuo, Yongjia Shang*, Synthesis of 4-styrylcoumarins via FeCl3-promoted cascade reactions of propargylamines with β-keto esters. Org. Biomol. & Chem., 2019, 17,4005-4013.
Qianqian Li, Xinwei He,* Jiajia Tao, Mengqing Xie, Hui Wang, Ruxue Li, and Yongjia Shang *, Base-mediated 1,4-Conjugate Addition/Intramolecular 5-exo-dig Annulation of Propargylamines with Benzoylacetonitriles and β-Keto Esters for Polysubstituted Furans and Furo[3,4-c]coumarins Formation. Adv. Synth. & Catal.,2019,361,1874-1886.

Xinwei He,* Guang Han, Youpeng Zuo, Yongjia Shang*, Rh(III)-catalyzed C-H Activation of Primary Benzamides and Tandem Cyclization with Cyclic 2-Diazo-1,3-diketones for the Synthesis of Isocoumarins. Tetrahedron, 2018, 74 , 7082-7088.

Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu, and Yongjia Shang*,Selective Synthesis of Aminoisoquinolines via Rh(III)-catalyzed C-H/N-H Bond Functionalization of N-Aryl Amidines with Cyclic 2-Diazo-1,3-diketones. J. Org. Chem. 2018, 83, 13463?13472.

Xinwei He,* Hui Wang, Xiaoting Cai, Qianqian Li, Jiajia Tao, andYongjia Shang.* FeCl3-promoted Tandem 1,4-Conjugate Addition/6-endo-digCyclyzation/Oxidation of Propargylamines and Benzoylacetonitriles/Malononitrile: Direct Access to Functionalized 2-Aryl-4H-chromenes.Org. Biomol. Chem.,2018,16, 7191-7202.

Youpeng Zuo, Xinwei He, Yi Ning, Lanlan Zhang, Yuhao Wu,Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and IsocoumarinsviaAdditive-controlled Chemoselective C-C or C-N Bond Cleavage.New J. Chem.,2018,42, 1673-1681.

Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu,Yongjia Shang.* Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access toN-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones andN-Arylamides.ACS Omega,2017,2, 8507-8516.

Guanghao Shi, Xinwei He,Yongjia Shang,* Cheng Yang, Liwei Xiang. Oxidative Rearrangement of Isatins with Arylamines Using H2O2as Oxidant: A Facile Synthesis of Quinazoline-2,4-diones and Evaluation of Their Antibacterial Activity.Chin. J. Chem.,2017,35, 1835-1843. (Front Cover)

Xinwei He,* Jiajia Tao, Hui Wang, Xiaoting Cai, Qianqian Li,Yongjia Shang.* Synthesis of polysubstituted phenyl acetatesviaFeCl3-mediated domino reaction of 2-(aryl(piperidin-1-yl)methyl) phenols and 1,3-diketones.Tetrahedron,2017,73, 7017-7023.

Xinwei He,* Zhiyu Yu, Youpeng Zuo, Cheng Yang,Yongjia Shang.* Direct Carboxamidation of Cyclic 2-Diazo-1,3-diketones by Rh2(OAc)4-catalyzed Isocyanide Insertion-Hydrolysis.Org. & Biomol. Chem.,2017,15, 7127-7130.

Cheng Yang, Xinwei He, Lanlan Zhang, Guang Han, Youpeng Zuo,Yongjia Shang.* Synthesis of Isocoumarins from Cyclic 2-Diazo-1,3-diketones and Benzoic AcidsviaRh(III)-catalyzed C-H Activation and Esterification.J. Org. Chem.,2017,82, 2081-2088.

Jia-Xing Zhang, Hong-Yu Wang, Qiao-Wen Jin, Chang-Wu Zheng, Gang Zhao,*Yong-Jia Shang.* Thiourea-Quaternary Ammonium Salt Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of Imino Esters To Construct Spiro[pyrrolidin-3,3′-oxindoles].Org. Lett.,2016,18, 4774-4777.

Jiaxing Zhang, Dongdong Cao, Hongyu Wang, Changwu Zheng, Gang Zhao,*Yongjia Shang.* Enantioselective Construction of Spirocyclic Oxindoles via Tandem Michael/Michael Reactions Catalyzed by Multifunctional Quaternary Phosphonium Salt.J. Org. Chem.,2016,81, 10558-10568.

Zhiqin Zhang, Xinwei He,Yongjia Shang,* Zhiyu Yu, Sufan Wang, Fuli Wu. Ferrocenyl-isoxazole Derivative: A Novel Electrochemical, Colorimetric, and Fluorescent Multiple Signal Probe for Highly Selective Recognition of Cu2+Ions.Chem. Res. Chin. Univ.,2017,33, 31-35.

Guanghao Shi, Xinwei He,Yongjia Shang,* Liwei Xiang, Cheng Yang, Guang Han, Bing Du.* Synthesisof 3',4'-Diaryl-4'H-spiro[indoline-3,5'-[1',2',4']oxadiazol]-2-onesviaDMAP-catalyzed Domino Reactions and Their Antibacterial Activity.Chin. J. Chem.,2016,34, 901-909.

Xinwei He, Yao Zhou,Yongjia Shang,* Cheng Yang, Youpeng Zuo. Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-onesviaRh2(OAc)4-catalyzed Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates.ACS Omega,2016,1, 1277-1283.

Xinwei He, Jiajia Tao, Xiaoqian Hu, Hui Wang,Yongjia Shang.* FeCl3-mediated One-pot Domino Reactions for the Synthesis of 9-Aryl/9-Arylethynyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones from Propargylic amines/Diaryl Amines and 1,3-Cyclohexanediones.J. Org. Chem.,2016,81, 2062-2069.

Guanghao Shi, Xinwei He,Yongjia Shang,* Meihua Xie.* Combinatorial Synthesis of Spiro[indoline-3,2'-pyrrole] Derivativesviaa Three-component Reaction under Catalyst-free Conditions.RSC Adv.,2016,6, 10412-10418.

Yongjia Shang,* Xiaoqian Hu, Xinwei He, Jiajia Tao, Guang Han, Fuli Wu, and Jie Wang. FeCl3-Mediated Synthesis of β-Alkynyl Ketones via Domino Nucleophilic-Substitution/Intramolecular-Cyclization/Reverse Claisen Condensation ofN-Cyclohexyl Propargylamines and 1,3-Diketones.J. Org. Chem.,2015,80, 4760-4765.

Xinwei He,Yongjia Shang,* Zhiyu Yu, Mei Fang, Yao Zhou, Guang Han, Fuli Wu. FeCl3-Catalyzed Four-component Nucleophilic Addition/Intermolecular Cyclization Yielding Polysubstituted Pyridine Derivatives.J. Org. Chem.,2014,79, 8882-8888.

Xinwei He,Yongjia Shang,* Yao Zhou, Zhiyu Yu, Guang Han, Wenjing Jin, Jiaojiao Chen. Synthesis of Coumarin-3-carboxylic EstersviaFeCl3-Catalyzed Multicomponent Reaction of Salicylaldehydes, Meldrum’s Acid and Alcohols.Tetrahedron,2015,71, 863-868.

Jiaxing Zhang, Dongdong Cao, Hongyu Wang, Gang Zhao,* and Yongjia Shang.* Enantioselective Desymmetrization of meso-Aziridines with Aaromatic Thiols Catalyzed by Chiral Bifunctional Quaternary Phosphonium Salts Derived froma-Amino Acids.Tetrahedron,2015,71, 1785-1791.

Zhiqiang Niu, Xinwei He, Yongjia Shang.* Efficient Enantioselective Synthesis of Dihydropyrans via Organocatalytic Michael Addition Reaction.Tetrahedron: Asymmetry,2014,25, 796-801.

Manman Hu, Xinwei He, Zhiqiang Niu, Zhenglei Yan, Fuyin Zhou,Yongjia Shang.* Synthesis of 3,4,5-Trisubstituted Isoxazoles by 1,3-Dipolar Cycloaddition Reaction fromα-Azidoacrylates and Aromatic Oxime.Synthesis,2014,46, 510-514.

Jianglai Cheng, Yong Wang, Chao Teng,Yongjia Shang,* Lianbing Ren, Biwang Jiang.* Preparation and Characterization of Monodisperse, Micrometer-sized, Hierarchically Porous Carbon Spheres as Catalyst Support.Chem. Eng. J.,2014,242, 285–293.

Shuyan Yu, Zhiqin Zhang, Zhiyu Yu,Yongjia Shang.* Novel Isoxazoline Ligand with Ferrocene Backbone: Preparation and Application in Heck Reaction with Water as Solvent.Appl. Organometal. Chem.,2014,28, 657–660.

Yongjia Shang,* Kaisheng Liao, Xinwei He, Jinsong Hu. One-Pot Synthesis of Disulfide-linkedN-Sulfonylazetidin-2-iminesvia a Copper-catalyzed Multicomponent Cascade Reaction.Tetrahedron,2013,69, 10134–10138.

Jiaping Wu,Yongjia Shang,* Cuie Wang, Xinwei He, Zhenglei Yan, Manman Hu, Fuyin Zhou. Synthesis of 3,4-Dihydro-2H-1,4-Benzo[b]thiazine DerivativesviaDABCO-Catalyzed One-Pot Three-Component Condensation Reactions.RSC Adv.,2013,3, 4643–4651.

Yongjia Shang,* Lifen Wang, Xinwei He, Min Zhang. Novel Syntheses of Pyrrolo[2,1-a]isoquinolines via 1,3-Dipolar Cycloaddition between N-Ylides and Alkynes.RSC Adv.,2012,2, 7681–76881.

Yongjia Shang,* Kai Ju, Xinwei He, Jinsong Hu, Shuyan Yu, Min Zhang, Kaisheng Liao, Lifen Wang, and Ping Zhang. Copper-Catalyzed Multicomponent Reaction: Synthesis of 4-Arylsulfonylimino-4, 5-dihydrofuran Derivatives.J. Org. Chem.,2010,75, 5743–5745.

Yongjia Shang,* Cuie Wang, Xinwei He, Kai Ju, Min Zhang, Shuyan Yu, Jiaping Wu. DMAP-catalyzed Cascade Reaction: One-pot Synthesis of Benzofurans in Water.Tetrahedron,2010,66, 9629–9633.

Yongjia Shang,* Xinwei He, Jinsong Hu, JianweiWu, Min Zhang, Shuyan Yu, and Qianqian Zhang. Copper-Catalyzed Efficient Multicomponent Reaction: Synthesis of Benzoxazoline-Amidine Derivatives.Adv. Synth. Catal.,2009,351, 2709–2713.

Jie Wang, Shu-Guang Chen, Bing-Feng Sun*, Guo-Qiang Lin,* and Yongjia Shang. Collective Total Synthesis of Englerin A and B, Orientalol E and F, and Oxyphyllol: Application of the Organocatalytic [4+3] Cycloaddition Reaction.Chem. Eur. J.,2013,19, 2539–2547.
Jinsong Hu,Yongjia Shang, Xiaoqiang Yao, Ling Qin, Yizhi Li, Zijian Guo, Hegen Zheng,* and Ziling Xue. Syntheses, Structures, and Photoluminescence of Five New Metal-Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids.Cryst. Growth. Des.,2010,10, 2676–2684.
Yongjia Shang,* Min Zhang, Shuyan Yu, Kai Ju, Cuie Wang, Xinwei He. New Route Synthesis of Indolizines via 1,3-Dipolar Cycloaddition of Pyridiniums and Alkynes.Tetrahedron Lett.,2009,50, 6981–6984.
Yongjia Shang,* Zhijun Feng, Lili Yuan, Shaowu Wang. Diastereoselective Cycloadditions of a Soluble Polymer-supported Substituted Allyl Alcohol Derived from Baylis–Hillman Reaction with Nitrile Oxides.Tetrahedron,2008,64, 5779–5783.



研究成果
商永嘉,顾家山,等. 氯乙酰氯的合成和研究,2000年8月通过安徽省教育厅鉴定。


会议论文
Xinwei He,* Jiajia Tao, Hui Wang,Yongjia Shang.* Synthesis of Polysubstituted Phenyl Acetates via FeCl3-mediated Domino Reaction of 2-(Aryl(piperidin-1-yl)methyl)phenols and 1,3-Diketones. 第十届全国有机化学学术会议, 中国, 深圳, 2017年12月19-21日.
Youpeng Zuo, Xinwei He,Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and Isocoumarinsvia Additive-controlled Chemoselective C-C or C-N Bond Cleavage. 第十届全国有机化学学术会议, 中国, 深圳, 2017年12月19-21日.
Xinwei He, Yao Zhou,Yongjia Shang.* Synthesis of 2-Iimino-[1,3]oxathioles via Rh2(OAc)4-catalyzed [3+2] Cycloaddition Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates. 第十九届全国金属有机化学学术讨论会, 中国, 杭州, 2016年10月28-31日.
Xinwei He, XiaoqianHu, Jiajia Tao, Hui Wang, Xiaoting Cai,Yongjia Shang.* FeCl3-catalyzed Domino Reactions of Propargylic Amines and Activated Methylene Compounds. 第十三届全国有机合成化学学术研讨会, P29, 中国, 扬州, 2016年10月13-16日.
Xiaoqian Hu, Xinwei He, Jiajia Tao,Yongjia Shang.* FeCl3-catalyzed One-pot Tandem Reactions of N-cyclohexyl Propargylamines and 1,3-Diketones. 第九届全国有机化学学术会议, P360, 中国, 长春, 2015年7月28-31日.
何心伟,商永嘉.* FeCl3催化的基于芳醛、活泼亚甲基化合物的“一锅”串联反应/多组分反应合成香豆素/吡啶衍生物的研究. 第十二届江淮有机化学论坛, 中国, 芜湖, 2014年10月31日-11月2日.
何心伟, 朱东盛, 蒋畅,商永嘉.* 室温无溶剂无催化剂下的Knoevenagel缩合反应研究. 第八届有机化学学术会议暨首届重庆有机化学国际研讨会, P794, 中国, 重庆, 2013年10月17-20日.
Xinwei He, Kaisheng Liao, Zhenglei Yan, Fuyin Zhou, Manman Hu, Yongjia Shang.* One-step Synthesis of Polysubstituted N-Sulfonylazetidin-2-imines viaCopper-catalyzed Sequential Multicomponent/S-S Coupling Reaction. 第十七届全国金属有机化学学术讨论会, P209,中国, 北京, 2012年10月19-22日.
Min Zhang, Shuyan Yu, Yongjia Shang.* General and direct synthesis of indolozines via 1,3-dipolar cycloaddition of pyridiniums and alkynes. 第六届全国有机化学会议, P340, 中国, 西安, 2009年8月17-20日.
Shuyan Yu, Min Zhang, Yongjia Shang.* Synthesis of Two Novel bisoxazoline ligands and Application to Palladium-catalyzed Heck-Sonogashira Coupling Reaction. 第六届全国有机化学会议, P153, 中国, 西安, 2009年8月17-20日.


专利
叶青青,左有鹏,何心伟,商永嘉. 1,2,3-三取代中氮茚衍生物及其制备方法.中国发明专利,专利号:4.3,公开日: 2018.09.14.
李欠欠,何心伟,陶佳佳,商永嘉. 多取代呋喃衍生物及其制备方法. 中国发明专利,专利号:7.X,公开日: 2018.08.24.
武玉豪,何心伟,左有鹏,商永嘉. 香豆素-4-磺酸酯衍生物及其制备方法. 中国发明专利,专利号:8.1,公开日: 2018.07.20.
左有鹏,何心伟,商永嘉. 异香豆素衍生物的制备方法. 中国发明专利,专利号:6.0,公开日: 2017.09.01.
何心伟,商永嘉,琚凯. 3,4,5-三取代噁唑烷酮类化合物及其制备方法. 中国发明专利,专利号: 5.X,公开日: 2015.02.04.
何心伟,靳文静,陈娇娇,商永嘉. 一种香豆素-3-羧酸酯衍生物的制备方法. 中国发明专利,专利号:0.2,公开日: 2014.03.12.
商永嘉,赵敏,何心伟,孙宇. 絮凝剂组合物,中国发明专利. 专利号: ZL 9.7.
商永嘉,琚凯,程杰,王桂蕾. 一种阿德福韦的制备工艺. 中国发明专利,专利号: ZL .7.


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